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NEET Chemistry: Topic-wise Test- 5 Free Online Test 2026


MCQ Practice Test & Solutions: Chemistry: Topic-wise Test- 5 (45 Questions)

You can prepare effectively for NEET NEET Mock Test Series - Updated 2026 Pattern with this dedicated MCQ Practice Test (available with solutions) on the important topic of "Chemistry: Topic-wise Test- 5". These 45 questions have been designed by the experts with the latest curriculum of NEET 2026, to help you master the concept.

Test Highlights:

  • - Format: Multiple Choice Questions (MCQ)
  • - Duration: 45 minutes
  • - Number of Questions: 45

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Chemistry: Topic-wise Test- 5 - Question 1

Which is incorrectly matched ?

Detailed Solution: Question 1


It is strictly covalent does not shows cationic & anionic form.

Chemistry: Topic-wise Test- 5 - Question 2

Which of the following species is not a pseudohalide ?

Detailed Solution: Question 2

Pseudo halides are
CN, NC, OCN, SCN, SeCN
NCS, N3, NCO

Chemistry: Topic-wise Test- 5 - Question 3

An orange solid (X) on heating , gives a colourless gas (Y) and a only green residue (Z). Gas (Y) treatment with Mg, produces a white solid substance...............

Detailed Solution: Question 3

(NH4)2Cr2O7 → Cr2O3 + H2O + N2

Chemistry: Topic-wise Test- 5 - Question 4

Conc. HNO3 is yellow coloured liquid due to

Detailed Solution: Question 4


Dissolved NO2 makes it yellow

Chemistry: Topic-wise Test- 5 - Question 5

Only One Option Correct Type

Direction (Q, Nos. 1-9) This section contains 9 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

Which of the following will give a racemic mixture on reduction with NaBH4 followed by acid work-up?

Detailed Solution: Question 5

NaBH4 brings about reduction of carbonyls by hydrid e transfer mechanism at planar sp2 carbon. Hence, if a chiral carbon is generated, racemic mixture is always produced.

Chemistry: Topic-wise Test- 5 - Question 6

Which of the following on reaction with excess of NaHSO3 in aqueous solution will give mixture of salts which can be separated into two fractions by fractional crystallisation?

Detailed Solution: Question 6

In the above reaction, four stereoisomers, two pairs of enantiomers are formed. Each member of a pair of enantiomer is diastereomer of each member of other pair of enantiomer. Hence, fractional crystallisation would give two fractions, each containing racemic mixture.

Chemistry: Topic-wise Test- 5 - Question 7

Which is the most suitable reagent for the following transformation?

 

Detailed Solution: Question 7

Wolff-Kishner reduction is suitable for reduction of carbonyls containing olefinic bonds. If Clemmensen reduction is done, HCI also attacks olefinic bonds.

Chemistry: Topic-wise Test- 5 - Question 8

What is the final major product Y in the following reaction?

Detailed Solution: Question 8

Chemistry: Topic-wise Test- 5 - Question 9

What is the final major product in the following reaction?

Detailed Solution: Question 9

Chemistry: Topic-wise Test- 5 - Question 10

Consider the following reaction,

Q. 

Which of the labeiled C—C bond formation is not possible in the above reaction? 

Detailed Solution: Question 10

Chemistry: Topic-wise Test- 5 - Question 11

In a mixed aldoi condensation with ethanal as one aidehyde, which other from the following is expected to give maximum yield of cross condensation product?

Detailed Solution: Question 11

Nucleophilic addition at carbonyl carbon of cyclopropane releases angle strain.

Chemistry: Topic-wise Test- 5 - Question 12

Consider the following aldol condensation reaction,

Q.

The nucleophile is

Detailed Solution: Question 12

In acid catalysed aldo! condensation, enol acts as a nucleophile.

Chemistry: Topic-wise Test- 5 - Question 13

Only One Option Correct Type

Direction (Q. Nos. 1-10) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

The major organic product in the following reaction is

Detailed Solution: Question 13

Chemistry: Topic-wise Test- 5 - Question 14

Which is the best hydride (H-) donor in the key step of Cannizaro reaction? 

Detailed Solution: Question 14

Dianion is better hydride donor. Also the electron donating group (CH3O) increases hydride (H-) donating a bility .

Chemistry: Topic-wise Test- 5 - Question 15

Only One Option Correct Type

Direction (Q. Nos. 1-7) This section contains 7 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

Which gives more than one amides on treatment with NH2OH followed by PCI5?

Detailed Solution: Question 15

Unsymmetrical carbonyls give more than one oximes with hydroxylamine, hence more than one amides in the subsequent Beckmann rearrangement.

Chemistry: Topic-wise Test- 5 - Question 16

Which oximes on treatment with concentrated H2SO4 undergo rearrangement to give single amide?

Detailed Solution: Question 16

Symmetrical oximes give single amide in Beckmann rearrangement.

Chemistry: Topic-wise Test- 5 - Question 17

What would be the major organic product in the following oxidation reaction?

Detailed Solution: Question 17

In BV oxidation, tertiary alkyl group has greater migrating aptitude than primary and secondary alkyl group.

Chemistry: Topic-wise Test- 5 - Question 18

Only One Option Correct Type

Direction (Q, Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

What is the major product of the following reaction?

Detailed Solution: Question 18

Free radical coupling reaction of aldehydes and ketones.

Chemistry: Topic-wise Test- 5 - Question 19

Predict the major product of the following reaction
 

Detailed Solution: Question 19

This reaction involves the treatment of a methyl ketone (CH₃COCH₃) with nitrous acid (HNO₂) in the presence of ethyl nitrite (C₂H₅ONO) and HCl.

This is a Nef reaction, which converts a methyl ketone into an oxime derivative in the presence of nitrous acid. The mechanism involves the formation of an intermediate diazonium salt, followed by its rearrangement and hydrolysis, leading to the formation of an oxime.

Let's break down the product options:

  • Option 1: This structure shows an imine with a hydroxyl group attached directly to nitrogen. However, this is not the expected structure from a Nef reaction.

  • Option 2: This shows an oxime (CH₃COCH=NOH), which is the expected major product of the reaction.

  • Option 3: This shows an ester-like product (CH₃COCH=NOEt), which is not the expected result of the Nef reaction.

  • Option 4: This shows an imine derivative (CH₃COCH=NH), which is not the expected major product in this case.

Conclusion:

The major product of the reaction is the oxime, as shown in Option 2.

The correct answer is:

Option 2.

Chemistry: Topic-wise Test- 5 - Question 20

Which of the following polymer is stored in the liver of animals?

Detailed Solution: Question 20

If blood glucose levels become too low, glucagon (pancreatic hormone) is released, which causes the liver to convert the stored glycogen back into glucose, and release it into the bloodstream.

Chemistry: Topic-wise Test- 5 - Question 21

Sucrose (cane sugar) is a disaccharide. One molecule of sucrose on hydrolysis gives _________.

Detailed Solution: Question 21

Explanation:

  • Sucrose (cane sugar) is a disaccharide: This means it is composed of two monosaccharides bonded together.

  • Hydrolysis of sucrose: When sucrose is hydrolyzed, it breaks down into its two monosaccharide components.

  • Components of sucrose: Sucrose is made up of one molecule of glucose and one molecule of fructose.

  • Result of hydrolysis: Therefore, when sucrose is hydrolyzed, it gives one molecule of glucose and one molecule of fructose.

Chemistry: Topic-wise Test- 5 - Question 22

Proteins are found to have two different types of secondary structures viz. α-helix and β-pleated sheet structure. α-helix structure of protein is stabilised by :

Detailed Solution: Question 22

In α-helix, hydrogen bonds are present between –NH group of one amino acid residue to the >C= O group of another aminoacid residue.

Chemistry: Topic-wise Test- 5 - Question 23

The commonest disaccharide have the molecular formula:​

Detailed Solution: Question 23

Sucrose or cane sugar is the commonest of the disaccharides. It has the molecular formula C12H22O11. It does not form a phenylhydrazone or exhibit carbonyl properties. On hydrolysis with dilute acids, it yields one molecule of D-(+)-glucose and one molecule of D-(—)-fructose. It is not a reducing sugar. 

Chemistry: Topic-wise Test- 5 - Question 24

Glucose and fructose are:

Detailed Solution: Question 24

Glucose and fructose are functional isomers of each other Because they have same molecular formula that is C6H12O6 But different functional group in their chemical formula. Glucose has aldehyde group while fructose has ketone as functional group.

Chemistry: Topic-wise Test- 5 - Question 25

Which of the following carbohydrates is called milk sugar?

Detailed Solution: Question 25

Lactose: The sugar found naturally in milk, it is a disaccharide composed of one galactose unit and one glucose unit; sometimes called milk sugar.

Chemistry: Topic-wise Test- 5 - Question 26

Which of the following is a test for proteins?

Detailed Solution: Question 26

Biuret solution is used to identify the presence of protein. Biuret reagent is a blue solution that, when it reacts with protein, will change color to pink-purple.

Chemistry: Topic-wise Test- 5 - Question 27

Haemoglobin is an example of:

Detailed Solution: Question 27

The correct answer is A
Haemoglobin is a Quaternary protein because it has 4 polypeptide structures - 2alpha and 2 beta.

Chemistry: Topic-wise Test- 5 - Question 28

N20→ 2NO2 + O2

When N205 decompose, its t12 does not change with its changing pressure during the reaction, so which one is the correct representation for "pressure of 2NO2" vs lime° during the reaction when initial N205 is equals to Po

Detailed Solution: Question 28

The correct sentence is option C
Since the half-life period is independent of the changing pressure, the reaction is of the first order.
The integrated rate law is (PN2​O5​​)t​=(P​oN2​O5​)0e−kt
Thus the partial pressure of N2​O5​ decreases exponentially with time and the partial pressure of NO2​ increases exponentially with time.
Hence, the correct graph is represented by option C.
 

Chemistry: Topic-wise Test- 5 - Question 29

In a hypothetical reaction

A(aq)  2B(aq) + C(aq)    (Ist order decomposition)

'A' is optically active (dextro-rototory) while 'B' and 'C' are optically inactive but 'B' takes part in a titration reaction (fast reaction) with H202. Hence the progress of reaction can be monitored by measuring rotation of plane of plane polarised light or by measuring volume of H202 consumed in titration.

 In an experiment the optical rotation was found to be 0 = 30° at t = 20 min and 8 =15° at t= 50 min. from start of the reaction. If the progress would have been monitored by titration method, volume of H202 consumed at t = 30 min. (from start) is 30 ml then volume of H202 consumed at t = 90 min will be:

Detailed Solution: Question 29

(B) As only A is optically active. So conc. of A at t =20min ∝ 30° 

While concentration of A at t= 50min ∝ mc 15° 

So conc. has deceased to half oils value in 30 min, so t1/2=30 min.

So volume consumed of H202 at t =30 min =t1/2 ,is according to 50% production of B at t= 90 min. production of B=87.5%(Threehalflives)

So volume consumed =

Chemistry: Topic-wise Test- 5 - Question 30

 At a certain temperature, the first order rate constant k1 is found to be smaller than the second order rate constant k2. If the energy of activation E1 of the first order reaction is greater than energy of activation E2 of the second order reaction, then with increase in temperature.

Detailed Solution: Question 30

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