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MCQ Practice Test & Solutions: Chemistry: Topic-wise Test- 7 (45 Questions)

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Test Highlights:

  • - Format: Multiple Choice Questions (MCQ)
  • - Duration: 45 minutes
  • - Number of Questions: 45

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Chemistry: Topic-wise Test- 7 - Question 1

If the kinetic energy of an electron is increased four times, the wavelength of the de-Broglie wave associated with it would become

Detailed Solution: Question 1

The wavelength λ is inversely proportional to the square root of kinetic energy. So if KE is increased 4 times, the wavelength becomes half.

λ∝1/√KE

Hence Option A is the answer.

Chemistry: Topic-wise Test- 7 - Question 2

The frequency of light emitted for the transition n = 4 to n = 2 of He+ is equal to the transition in H atom corresponding to which of the following

Detailed Solution: Question 2

Correct Answer is A.

Chemistry: Topic-wise Test- 7 - Question 3

The maximum number of atomic orbitals associated with a principal quantum number 5 is

Detailed Solution: Question 3

Number of orbitals in a shell = n2 = (5)= 25

Chemistry: Topic-wise Test- 7 - Question 4

The radius of the second Bohr orbit for the hydrogen atom is :
(Planck’s constant, h = 6.262×10-34Js: Mass of electron = 9.1091×10-31kg; Charge of electron e = 1.60210×10-19C; permittivity of vacuum ε0 = 8.854185×10-12kg-1m-3A2)

Detailed Solution: Question 4

Chemistry: Topic-wise Test- 7 - Question 5

Which model describes that there is no change in the energy of electrons as long as they keep revolving in the same energy level and atoms remains stable?

Detailed Solution: Question 5

Bohr Model of atom:

  • An atom is made up of three particles: Electrons, neutrons and protons.
  • The protons and neutrons are located in a small nucleus at the centre of the atom.
  • The electrons revolve rapidly around the nucleus at the centre of the atom.
  • There is a limit to the number of electrons that each energy level can hold.
  • Each energy level is associated with a fixed amount of energy.
  • There is no change in the energy of electrons as long as they keep revolving in the same energy level.

Bohr explained the stability through the concept of revolution of electrons in different energy levels.


The change in the energy of an electron occurs when it jumps from lower to higher energy levels. When it gains energy, it excites from lower to higher and vice versa.
Thus energy is not lost and the atom remains stable.

Chemistry: Topic-wise Test- 7 - Question 6

The number of radial nodes for 3p orbital is:

Detailed Solution: Question 6

  • Number of radial nodes = n - l – 1

where n = principal quantum number, l = azimuthal quantum number

  • For 3p orbital, n = 3 – 1 – 1 = 1
  • Number of radial nodes = 3 – 1 – 1 = 1. 

Chemistry: Topic-wise Test- 7 - Question 7

A sub-shell with n = 6 , l = 2 can accommodate a maximum of

Detailed Solution: Question 7

n = 6, l = 2 means 6d → will have 5 orbitals. 

∴ max 10 electrons can be accommodate as each orbital can have maximum of 2 electrons. 

Chemistry: Topic-wise Test- 7 - Question 8

Thomson’s plum pudding model explained:

Detailed Solution: Question 8

  • An atom consists of a positively charged sphere with electrons filled into it. The negative and positive charges present inside an atom are equal and as a whole, an atom is electrically neutral.
  • Thomson’s model of the atom as compared to plum pudding and watermelon.
  • He compared the red edible part of the watermelon to a positively charged sphere whereas the seeds of watermelon to negatively charged particles.

electrical world

Chemistry: Topic-wise Test- 7 - Question 9

Which of the following conclusions could not be derived from Rutherford’s α -particle scattering experiment?

Detailed Solution: Question 9

  • Concept of electrons moving in a circular path of fixed energy called orbits was put forward by Bohr and not derived from Rutherford's scattering experiment.
  • Out of a large number of circular orbits theoretically possible around the nucleus.
  • The electron revolves only in those orbits which have a tired value of energy Hence, these orbits are called energy level or stationary states.

Chemistry: Topic-wise Test- 7 - Question 10

Passage II

For the following,

Q.

pH of the solution in the half-cell containing 0.02 HA is(HA is a weak monobasic acid)   

Detailed Solution: Question 10

Anodic

Cathodic

Reaction quotient (Q) 





Chemistry: Topic-wise Test- 7 - Question 11

Passage II

For the following,

Q.

pKa of the weak monobasic acid is  

Detailed Solution: Question 11

Anodic

Cathodic

Reaction quotient (Q) 



*Answer can only contain numeric values
Chemistry: Topic-wise Test- 7 - Question 12

One Integer Value Correct Type

This section contains 3 questions, when worked out will result in an integer value from 0 to 9 (both inclusive)

Q.

For the following cell with metal X electrodes, 

Ecell = -0.028 V at 298 K, if there is no liquid juncton potential,valency of X is.......  


Detailed Solution: Question 12




Chemistry: Topic-wise Test- 7 - Question 13

Passage II

Given molar conductance of 0.001 M NH4OH solution at 298K = 3.0 x 10-3Sm2mol-1.
Limiting molar conductance of

aq. NH4CI = 1.50 x 10-2Sm2mol-1

aq. NaCl = 1.26 x 10-2Sm2 mol-1

and aq. NaOH = 2.48 x 10-2 Sm2 mol-1

Q.

Degree of dissociation of NH4OH at 298 K is 

Detailed Solution: Question 13

By Kohlrausch’s law,

= 1.50 x 10-2 + 2.48 x 10-2 - 1.26 x 10-2
= 2.72 x 10-2 Sm2mol-1
 


Chemistry: Topic-wise Test- 7 - Question 14

Passage II

Given molar conductance of 0.001 M NH4OH solution at 298K = 3.0 x 10-3Sm2mol-1.
Limiting molar conductance of

aq. NH4CI = 1.50 x 10-2Sm2mol-1

aq. NaCl = 1.26 x 10-2Sm2 mol-1

and aq. NaOH = 2.48 x 10-2 Sm2 mol-1

Q.

pKb of NH4OH  is

Detailed Solution: Question 14

By Kohlrausch’s law,

= 1.50 x 10-2 + 2.48 x 10-2 - 1.26 x 10-2
= 2.72 x 10-2 Sm2mol-1
 


*Answer can only contain numeric values
Chemistry: Topic-wise Test- 7 - Question 15

One Integer Value Correct Type

This section contains 2 questions, when worked out will result in an integer value from 0 to 9 (both inclusive)

Q.

0.01 M aqueous solution of a dibasic acid is diluted to 0.004N such that equivalent conductance is x times.What is the value of x?


Detailed Solution: Question 15

Dibasic acid is H2 2H+ + A2- 
∴ 0.01M = 0.02N
Equivalent conductance at 0.02 N

Equivalent conductance at 0.004 N 

Chemistry: Topic-wise Test- 7 - Question 16

The internationally recommended unit for conductance is

Detailed Solution: Question 16

The internationally recommended unit for conductance is Siemens (S). 1 siemen = 1 ohm-1

Chemistry: Topic-wise Test- 7 - Question 17

Matching List Type

Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct

Q.

The standard reduction potential data at 298 K is given below:

Match E° of a redox pair in Column I with the values given in Column II and select the corect answer using the codes given below:

Detailed Solution: Question 17

In all cases, we use





Equal number of electrons are involved. 



Chemistry: Topic-wise Test- 7 - Question 18

Passage II 

Given,

ΔG0f(AgCl) = -109kJmol-1, ΔG0f(Cl-) = -129kJmol-1

ΔG0f(Ag+) = 77kJmol-1,

Thus E°cell of the cell reaction is  

Ag+(aq) + Cl-(aq) → AgCl(s) is  

Detailed Solution: Question 18




Chemistry: Topic-wise Test- 7 - Question 19

Passage II 

Given,

ΔG0f(AgCl) = -109kJmol-1, ΔG0f(Cl-) = -129kJmol-1

ΔG0f(Ag+) = 77kJmol-1,

Q.

Ksp of AgCl is thus,

Detailed Solution: Question 19


For equilibrium, AgCl(s)  Ag+  + Cl-    E0 = -0.59V


-0.59 = 0.0591logKsp

∴   log Ksp = -10

∴ Ksp = 10-10

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 7 - Question 20

Using Cr2O72- aqueous, solution  
E0red = 1.33V and ΔG0 = -770.07 kJmol-1

What is the valency of the ion formed after reduction?  


Detailed Solution: Question 20


Chemistry: Topic-wise Test- 7 - Question 21

Direction (Q. Nos. 1-18) This section contains 18 multiple choice questions. Each question has four
 choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q. 

How many diffrent alkenes exist for C5H10 which are structural isomeres ?

Detailed Solution: Question 21

CH10

 Two times double bond can’t appear as it has asked alkene and not alkadiene. So, these are the only types of alkenes that can be formed which are structural isomers.

Chemistry: Topic-wise Test- 7 - Question 22

Direction (Q. Nos. 1-18) This section contains 18 multiple choice questions. Each question has four

 choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.
 

Q.

The correct statement regarding a chiral compound is

Detailed Solution: Question 22

According to option A chiral compound at least have one chiral carbon but compounds other than carbon and also chiral like NCl Br I is chiral. According to option b a compound containing only one ka kalakaron is always is always correct that is statement is true it is the minimum requirement for a carbon atom to become chiral. Efficiency is not necessary to be true all the time compound will not be superimposable on its Mirror image. And for option d a plane of symmetry is sufficient but not a mandatory to give achiral compound.

Chemistry: Topic-wise Test- 7 - Question 23

The correct statement regarding elements of symmetry and chirality of a compound is

Detailed Solution: Question 23

Correct answer: Option C.

A molecule that has a plane of symmetry (σ) or a centre of symmetry (i) is achiral because the optical activity of one part of the molecule is exactly cancelled by the mirror-related part; a classical example is meso-tartaric acid.

The presence of a proper rotation axis (Cn) does not necessarily destroy chirality; many chiral molecules possess a Cn axis. By contrast, an improper rotation axis (Sn) - a rotation followed by reflection - renders a molecule achiral; in particular S1 ≡ σ and S2 ≡ i.

Therefore, only statement 3 is correct. Statements 1, 2 and 4 are incorrect: statement 1 is false because a Cn axis alone need not destroy chirality; statement 2 is false because a centre of symmetry (i) does make a molecule achiral; statement 4 is false because an axis of symmetry does not imply the existence of a centre of symmetry.

Chemistry: Topic-wise Test- 7 - Question 24

What is true regarding a meso form of a compound?

Detailed Solution: Question 24

The given compound is superimposable on its mirror image, so it is achiral. Achiral molecules which have chirality centers are called meso compounds. Meso compounds are possible if two (or more) chirality centers in a molecule have the same set of four substituents.

Chemistry: Topic-wise Test- 7 - Question 25

The number of optically active optical isomers of the compound is:

Detailed Solution: Question 25

The compound shown is glyceraldehyde, which contains 3 chiral centers (n = 3). The general formula to calculate the number of stereoisomers is 2n = 23 = 8. However, due to the presence of a meso form (an internal plane of symmetry), some stereoisomers are optically inactive.

The number of optically active isomers = 2n-1 = 23-1 = 4. But since one of these is a meso compound (optically inactive), the total number of optically active isomers = 4 - 2 = 2.

Alternatively, using the formula: Number of optically active isomers = 2n-1 - 2(n-1)/2 = 22 - 21 = 4 - 2 = 2.

Thus, the compound has 2 optically active isomers.

Chemistry: Topic-wise Test- 7 - Question 26

Find the number of stereoisomers for CH3 – CHOH – CH = CH – CH3.

Detailed Solution: Question 26

The number of stereoisomers for CH3 – CHOH – CH = CH – CH3 is four. This is calculated by the formula 2n+1. where n is number of chiral centres, which is 1 in this case. So, 21+1 = 22= 4

Chemistry: Topic-wise Test- 7 - Question 27

Direction (Q. Nos. 1-13) This section contains 13 multiple choice questions. Each question has four
 choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q.
Which among the following defines Meso forms of isomers
 

Detailed Solution: Question 27

The correct option is D Molecule in meso form have a plane of symmetry
Meso forms of isomers are single compound and their molecules are achiral and hence they cannot be separated into optically active enantiometric pairs.
Molecule in meso form have a plane of symmetry due to which the optical rotations of upper and lower parts are equal and in the opposite direction which balanced internally and compound become optically inactive. this property is called internal compensation.

Chemistry: Topic-wise Test- 7 - Question 28

Direction (Q. Nos. 1 - 6) This section contains 6 multiple choice questions. Each question has four
choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

 

Q.

A pure enantiomer with molecular formula C6H13OBr, when reacted with PBr3, an achiral product C6H12Br2 is obtained that has no chiral carbon. The compound which satisfy this condition could be (no bond to chiral carbon is broken during the reaction)

Detailed Solution: Question 28

 2-bromomethyl-2-methyl-1-butanol: The bromine substitution occurs at the carbon bonded to oxygen but not at a chiral carbon. Thus option b satisfies the condition.

Chemistry: Topic-wise Test- 7 - Question 29

Optical rotation of a newly synthesised chiral compound is found to be +60°. Which of the following experiment can be performed to establish that optical rotation is not actually -300°?

Detailed Solution: Question 29

Option b: Decrease concentration of sample four times and measure the optical rotation. Explanation:

  • Optical rotation is directly proportional to concentration (specific rotation = observed rotation/concentration).
  • If you decrease the concentration of the chiral compound in the sample, the observed optical rotation will decrease proportionally.
  • If the initial observed rotation is indeed +60° and not -300°, decreasing the concentration will still result in a positive rotation, but it will be lower.

The other options are less likely to provide useful information in this context.

*Multiple options can be correct
Chemistry: Topic-wise Test- 7 - Question 30

Direction (Q. Nos. 10-14) This section contains 5 multiple choice questions. Each question has four
choices (a), (b), (c), and (d), out of which ONE or  MORE THAN ONE  is correct.

Q.Consider the following molecule

The correct statement concerning the above molecule is/are 

Detailed Solution: Question 30

  •  The given compound has a total of six stereoisomers 
  • It's meso form upon ozonolysis followed by Zn-hydrolysis gives racemic mixture 

  • It's optically active isomers, each upon ozonolysis followed by Zn-hydrolysis gives a single enantiomer. 

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