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(18-01-2018) Major Test - 1 - IIT JAM MCQ


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30 Questions MCQ Test - (18-01-2018) Major Test - 1

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(18-01-2018) Major Test - 1 - Question 1

Correct order of bond length of p, q, r, x and y given in following compound is:

                                                  

(18-01-2018) Major Test - 1 - Question 2

Which of the following reaction profile represent the following energy diagram:

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(18-01-2018) Major Test - 1 - Question 3

For (CH3)2S correct sequence of Lewis acidic strength:

(18-01-2018) Major Test - 1 - Question 4

The major product of the following reaction is:

(18-01-2018) Major Test - 1 - Question 5

The major product of the following reaction is:

(18-01-2018) Major Test - 1 - Question 6

According to VSEPR theory, the molecule/ion having ideal tetrahedral shape is:

(18-01-2018) Major Test - 1 - Question 7

The pH of the blood is maintained by the balance between H2CO3 and NaHCO3. If the amount of CO2 in the blood is increased how will it affect the pH of blood?

(18-01-2018) Major Test - 1 - Question 8

The change in the hybrid state of BeCl2 in the solid state from vapour state is:

(18-01-2018) Major Test - 1 - Question 9

A mixture of two amino acids having pH 9.60 and 5.40 can be separated:

(18-01-2018) Major Test - 1 - Question 10

An aqueous solution of hydrated aluminium chloride contains the following set of ions:

(18-01-2018) Major Test - 1 - Question 11

Which sequence of steps describes the best synthesis of 2-methyl-3-pentanone?

(18-01-2018) Major Test - 1 - Question 12

The major product C of the following reaction:

(18-01-2018) Major Test - 1 - Question 13

If   then the value of a for which A2 = B is:

(18-01-2018) Major Test - 1 - Question 14

If y(t) is a solution of     then y(1) is equal to:

(18-01-2018) Major Test - 1 - Question 15

The angular part of the wave function for the electron in a hydrogen atom is proportional to . The values of the azimuthal quantum number (l) and the magnetic quantum number (m) are, respectively

(18-01-2018) Major Test - 1 - Question 16

 What can be the maximum pressure to be given to a plastic for blow molding process?

(18-01-2018) Major Test - 1 - Question 17

A molecule having formula PQ2H8 has the following structural features (H is hydrogen atom):

(I) P and Q both belong to period 2 of periodic table.

(II) P and Q have two and three balance electrons respectively.

(III) There are four (2c—2e) bonds and four (3c—2e) bonds in the molecule.

(IV) In P and Q both form atleast one (2c—2e) bond.

Based on above structural information which one of the following structures is most appropriate for PQ2H8?

(18-01-2018) Major Test - 1 - Question 18

In the thermite process, iron oxide is reduced to molten iron by aluminium powder because:

(18-01-2018) Major Test - 1 - Question 19

A solution containing a group-IV cation gives precipitate on passing, H2S. A solution of this precipitate in dil. HCl produces a white precipitate with NaOH solution and bluish-white precipitate with basic potassium ferrocyanide. The cation is:

(18-01-2018) Major Test - 1 - Question 20

A metal ‘M’ reacts with nitrogen gas to afford ‘M3N’. ‘M3N’ on heating at high temperature gives back ‘M’ and on reaction with water produces a gas ‘B’. Gas ‘B’ reacts with aqueous solution of CuSO­4 to form a deep blue compound. ‘M’ and ‘B’ respectively are:

(18-01-2018) Major Test - 1 - Question 21

Select the correct statement:

(18-01-2018) Major Test - 1 - Question 22

The major product formed in the following reaction is:

(18-01-2018) Major Test - 1 - Question 23

The n factor of K4[Fe(CN)6] in the given reaction would be:

Zn2++ K4[Fe(CN)6]→ K2Zn3[Fe(CN)6]2+ KΘ

(18-01-2018) Major Test - 1 - Question 24

For a given nuclear fission reaction of 235U

The amount of energy (in kJ/mol) released during this process is (given 235U = 235.0439 amu,
142Ba = 141.9164 amu, 91Kr = 90.9234 amu, neutron = 1.00866 amu):

(18-01-2018) Major Test - 1 - Question 25

An organic compound A(C8H16O2) on treatment with an excess of methylmagnesium chloride generated two alcohols B and C, whereas reaction of A with lithium aluminium hydride generated only a single alcohol C. Compound B on treatment with an acid yielded an olefin ?(C6H12), which exhibited only a singlet at ppm in the 1H NMR spectrum. The compound A is:

(18-01-2018) Major Test - 1 - Question 26

The major product formed in the following reaction is:

(18-01-2018) Major Test - 1 - Question 27

The major product formed in the following reaction is:

(18-01-2018) Major Test - 1 - Question 28

The species with highest magnetic moment (spin only value) is:

(18-01-2018) Major Test - 1 - Question 29

The molal freezing point depression constant of benzene (C6H6) is 4.90 K kg mol–1. Selenium exists as a polymer of the type Sex. When 3.26 g of selenium is dissolved in 0.112 °C lower than pure benzene. The correct molecular formula of selenium is:

(18-01-2018) Major Test - 1 - Question 30

Equivalent conductance of BaCl2, H2SO4 and HCl are x1, x2 and x3 S cm2 equiv–1 at infinite dilution. If specific conductance of saturated BaSO4 solution is y S cm–1 then Ksp of BaSO4 is:

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