Pressure and the simple mercury barometer - Chemistry Video Lecture - IIT JAM

We typically consider matter to exist
in three distinct states.
We've got solids, we've got
liquids and we've got gases.
And of those three, probably
the least often considered are gases.
And maybe that's because we can't often
see or hold gases too well,
but it doesn't mean that
gases aren't important.
In fact, the very air
that you're breathing
right now is a gas.
So the macroscopic, kind
of big picture level,
the gas phase refers a system in which
the molecules don't have a
definite shape or volume.
So, I've got kind of a cloud of gas here
and it doesn't have a
shape or volume to it.
And at the nitty-gritty,
microscopic level,
we're talking about a substance
with molecules that are
freely moving through space.
So these particles are
moving freely through space.
And this means that the
energy of their motion,
which is their kinectic energy,
is greater than the potential energy
of the intermolecular
forces that might hold
these molecules together as a solid.
Now, one of the more
intuitive properties of a gas
is that it exerts pressure
on its surroundings.
So gas exerts pressure
on the surroundings.
And for example, when
you inflate a balloon
the gas inside exerts a
pressure on the elastic sides,
making them grow taut and then
eventually causing them to expand.
So what is this pressure that's causing
the gas in the balloon to expand?
Well, pressure is actually a
measure of force per unit area.
So what's actually going on here
is that the little particles in here
are moving around the container.
So they have a velocity.
They're moving around the container.
And when they collide
against the container
they exert a force on
the area of collision.
And while one little particle collision
might not have a huge amount of pressure,
when you think about the
huge amount of particles
and the huge number of collisions,
we pretty easily get enough
pressure to fill the balloon.
And the neat thing about balloons is
we typically don't just
fill them up a little bit,
we can fill them up a lot.
And the more we fill them
up the tauter the sides get,
indicating that they have more pressure.
So what might cause the
pressure to increase?
Well, according to our
little pressure formula here,
pressure is directly
proportional to the force.
So let's think about what would
cause the force to increase.
We know that force is equal to
the mass times acceleration.
So if we increase the
magnitude of the acceleration,
we can increase the force.
Because force and acceleration
are also directly proportional.
That means if we have a
greater change in velocity-
because that's what acceleration is,
it's a change in velocity.
So if we have a greater change in velocity
during the collision, we
can increase the force.
And that means that the faster
our little particles are moving,
the greater the force.
And thus the greater the pressure.
And if you remember from our last video,
we said that temperature was a measure
of the average kinetic
energy of the particles.
So really what we're saying,
is that when we increase the temperature,
we're increasing the
pressure that the gas exerts.
So what else might cause
the pressure to increase?
Well, if the total pressure is the sum
of those little individual collisions,
more collisions would mean more pressure.
But how do we increase
the number of collisions?
One method might be to add more particles,
because more particles
means more collisions.
So more moles of gas-
remember that moles is simply
referring to the number of particles.
More moles of gas means more pressure.
Now we could also increase the
frequency of these collisions
by making the container smaller.
Because the particles would
have less space to move around,
and would therefore hit the sides
of the container more frequently.
So if we decrease the volume-
If we decrease the space of the container,
we're going to increase the pressure.
So we can change the pressure of a gas.
But how do we measure those changes?
Well, a long time ago in 1643
a former student of Galileo
named Evangelista Torricelli
asked the same question while
he was trying to measure
the changing pressure of
the gas in our atmosphere.
And he solved the problem by inventing
the Torricellian Barometer.
A barometer is a device
that measures pressure.
And so he took a glass tube,
and he filled it up with mercury.
So he took a glass tube
and he filled it up with mercury.
And he quickly flipped the tube over,
and he stuck the open end
into an open dish of mercury.
So he stuck the tube into
an open dish of mercury,
open end down, and interestingly enough,
most of the mercury stayed in the tube.
And the mercury stayed in the tube,
even though it was trying to flow out,
because as it tries to flow out
it exerts a pressure on
the mercury in the dish,
which then causes the mercury in the dish
to push upward against the air.
And when the pressure
of the rising mercury
meets the pressure of the atmosphere
pushing down on the liquid's surface,
the mercury that's in the
tube, it can't flow anymore.
So the pressure in the atmosphere traps
some of the mercury inside the tube.
And we see that at sea level
the height of the mercury
that's left in the column
is about 760 millimeters.
Now if we were to measure
the height of the column
on top of a giant mountain,
the column would be shorter.
Because there isn't as much air
pushing down on the open liquid.
So more mercury from
the column can escape.
In fact on the ski slopes
of Breckinridge, Colorado,
the height of the column
would only be about 520 millimeters.
So with less weight of the atmosphere
pushing down on the surface
of the mercury in the dish,
more can escape so that
the amount in the column is shorter.
And in order to get a
baseline for comparison,
we say that the pressure of the atmosphere
at sea level is one standard
atmosphere or one ATM
And because of a lot of manometers,
which are kind of generic devices
that measure pressure using mercury,
pressure is often measured
in millimeters of mercury.
Which we know that one atmosphere,
because it's at sea level,
would equal 760 millimeters of mercury.
And in honor of Torricelli,
this millimeters of mercury
unit is often called a tor.
So one atmosphere equals
760 millimeters of mercury,
which equals 760 tor.
Now because pressure is a
measure of force-per-area,
and the SI unit for force is the newton,
and the SI unit for area
is the square meter,
we have another unit of pressure
which is the newton-per-square-meter.
And we call that the pascal.
But if we measure the
pressure of the atmosphere
at sea level in pascal,
we get one atmosphere is
equal to 101,325 pascals.
And so it's worth quickly
mentioning pascals,
because it might be a unit
of pressure that allows
us to translate into other standard units,
but mostly, because this
number is annoyingly large,
we typically measure pressure
in atmosphere or tor.
Especially when we're dealing
with the pressure of gases.