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All questions of p-Block Elements (Only in NEET) for NEET Exam

Which of the following is a polar molecule ? [NEET 2013]
  • a)
    SF4
  • b)
    SiF4
  • c)
    XeF4
  • d)
    BF3
Correct answer is option 'A'. Can you explain this answer?

Rajesh Datta answered
SF4 has 4 bond pairs and 1 lone pair of electrons, sp3d hybridisation leads to irregular shapeand resultant
μ ≠ 0.

In the MOT of F2 molecule, number of electrons occupying antibonding orbitals are
    Correct answer is '8'. Can you explain this answer?

    Nandita Ahuja answered
    Fluorine atom have 2+7 electrons so an F2 molecule contain 18 electrons.

    Hence, 8 electrons occupy the antibonding orbitals.

    The correct statements among the following are
    • a)
      Bond lengths in O2 , are 121 , 134, 149 pm
    • b)
      Ozone is stronger oxidising agent than dioxygen
    • c)
      O2 acts as reducing agent when it reacts with powerful oxidising agents like PtF6
    • d)
      Ozone is much more stable than oxygen
    Correct answer is option 'A,B,C'. Can you explain this answer?

    Srishti Kaur answered
    The correct option is Option A, B and C.
    Bond length is inversely proportional to bond order. O2+ has the highest bond order among these three, so it should have the shortest bond length.
    Ozone is a powerful oxidizing agent as compared to oxygen. This is due to the unstable nature of ozone and the nascent oxygen that is released during the reaction.
    O2 when gas makes others like H2 gas to lose electrons, therefore, O2 gas is an oxidizing agent and H2 when gas loses electrons in redox reaction, therefore H2 gas is a reducing agent.
    Oxygen is more stable than ozone. On heating, ozone readily dissociates and forms oxygen and free radicals of oxygen known as nascent oxygen which take part in reaction, thus ozone is more reactive than oxygen

    When chlorine reacts with hot, cone. NaOH, the products formed are
    • a)
      NaCI
    • b)
      NaOCI
    • c)
      NaCIO3
    • d)
      HCI
    Correct answer is option 'A,C'. Can you explain this answer?

    Anupama Nair answered
    When Cl2 reacts with hot and concentrated NaOH, then....6NaOH+3Cl2→5NaCl +NaClO3+3H2O...When Cl2 reacts with cold and dilute NaOH then ...2NaOH+Cl2→NaCl+NaOCl+H2O

    The total number of positive oxidation states shown by fluorine is
      Correct answer is '1'. Can you explain this answer?

      Puja Gupta answered
      Fluorine is an element that belongs to the halogen group in the periodic table. It has an atomic number of 9, and its electron configuration is 1s^2 2s^2 2p^5. Fluorine is highly electronegative, meaning it has a strong tendency to attract electrons towards itself when it forms chemical bonds. This property is due to its relatively small atomic size and high effective nuclear charge.

      Fluorine has a total of 7 valence electrons, which are electrons in its outermost energy level (2s^2 2p^5). In order to achieve a stable electron configuration, fluorine tends to gain one electron to complete its octet. By gaining one electron, fluorine achieves a stable electron configuration similar to the nearest noble gas, neon (1s^2 2s^2 2p^6).

      Fluorine's strong electronegativity and its tendency to gain electrons result in it having only one common oxidation state, which is -1. In this oxidation state, fluorine gains one electron to achieve a stable configuration of 1s^2 2s^2 2p^6. This oxidation state is commonly observed in compounds where fluorine acts as an anion, such as in the compound sodium fluoride (NaF). In NaF, fluorine gains an electron from sodium to form the F- ion.

      It is important to note that although fluorine is highly electronegative and tends to gain electrons, it does not have the capability to lose electrons easily and form positive oxidation states. This is because fluorine's valence shell is almost full, and losing electrons would require a significant amount of energy.

      In conclusion, fluorine has only one common oxidation state, which is -1. This is due to its strong electronegativity and its tendency to gain one electron to achieve a stable electron configuration.

      Which of the following is the strongest Lewis base?
      • a)
        NBr3
      • b)
        NF3
      • c)
        NCl3
      • d)
        NI3
      Correct answer is option 'D'. Can you explain this answer?

      Correct Answer :- D
      • Lewis bases need to be able to donate electrons. Fluorine is the most electronegative element in the halogens followed by chlorine, bromine and iodine. 
      • Due to fluorine being strongly electronegative, it draws the electron density towards itself which makes it difficult for nitrogen atom to donate its lone pair of electrons. So, NF is the least basic. This trend follows the strength of electronegativity of the halides. 
      • Since iodine is least electronegative, it is the most basic trihalide of nitrogen.
      So, we have the trend, in decreasing order of basic strength:
      NF3 < NCl3 < NBr3 < NI3

      Among the following which is the strongest oxidising agent? [2009]
      • a)
        Br2
      • b)
        I2
      • c)
        Cl2
      • d)
        F2
      Correct answer is option 'D'. Can you explain this answer?

      Rajesh Datta answered
      Standard reduction potential of halogens are positive and decreases from fluorine to iodine. Therefore halogens act as strong oxidising agent and their oxidising power decreases from fluorine to iodine.

      Which has lowest bond energy (single bond)?
      • a)
        O—H
      • b)
        O—O
      • c)
        S—H
      • d)
        S—S
      Correct answer is option 'B'. Can you explain this answer?

      Rahul Bansal answered
      Sulfur atoms are larger than oxygen atoms.

      Pi bonds are formed by overlapping of two parallel p orbitals. The further the distance between atoms, the lesser the overlapping and weaker the bond.

      But sigma bonds in case of Oxygen and Nitrogen are not strong enough because you are bringing two very small atoms (with large no. of electrons in the outer shell) too close which makes the sigma bond comparatively unstable than that of S-S bond where sigma bond is more stable due to lesser electro static repulsion of non-bonding electrons.

      At what temperature white phosphorous changes to red phosphorous?
      • a)
        300° C
      • b)
        450° C
      • c)
        50° C
      • d)
        400° C
      Correct answer is option 'A'. Can you explain this answer?

      Ananya Singh answered
      According to NCERT, red phosphorus is obtained by heating white phosphorus at 573 K in an inert atmosphere for several days. In degree celius, temperature = 300⁰ C (573K - 273).

      Which of the following is the most basic oxide?
      • a)
        Sb2O3
      • b)
        Bi2O3 [2006]
      • c)
        SeO2
      • d)
        Al2O3
      Correct answer is option 'B'. Can you explain this answer?

      Nilotpal Gupta answered
      More the oxidation state of the central atom (metal) more is its acidity. Hence SeO2 (O. S. of Se = +4) is acidic. Further for a given O.S., the basic character of the oxides increases with the increasing size of the central atom.
      Thus Al2O3 and Sb2O3 are amphoteric and Bi2O3 is basic.

      Which of the following is not a use of noble gases?
      • a)
        Argon is widely used for filling incandescent electric bulbs
      • b)
        Neon is used in safety devices for protecting electrical instruments
      • c)
        Radon is used in radiotherapy of cancer
      • d)
        Helium is filled in tubes of cycles and scooters tyres
      Correct answer is option 'D'. Can you explain this answer?

      Helium is filled in tubes of cycles and scooters tyres
      Helium is not used for filling tubes of cycles and scooters tyres. It is primarily used in other applications such as:

      Argon:
      - Widely used for filling incandescent electric bulbs to prevent the filament from oxidizing.
      - Used in welding and metal fabrication to shield the weld area from atmospheric gases.

      Neon:
      - Used in safety devices for protecting electrical instruments due to its ability to produce a bright light when an electric current passes through it.
      - Also commonly used in neon signs for advertising.

      Radon:
      - Used in radiotherapy of cancer as a radiation source to destroy cancer cells.
      - It can also be used in some geological research applications to trace the movement of underground gases.
      In contrast, helium is typically used in applications such as:
      - Cryogenics to achieve low temperatures
      - In filling balloons for various purposes
      - In cooling nuclear reactors and MRI machines
      Therefore, while noble gases have a variety of important uses, filling tubes of cycles and scooters tyres with helium is not one of them.

        is the structure of
      • a)
        Phosphorous acid
      • b)
        Hypophosphorus Acid
      • c)
        Phosphoric acid
      • d)
        Pyrophosphoric acid
      Correct answer is option 'B'. Can you explain this answer?

      Baby Ghosh answered
      Of course..this is a structure of hypo phosphorus acid. It is a mineral acid with formula H4P2O6.In hypophosphorus acid,the phosphorus bonds are identical and joined with p-p bond .there is also joined oxygen and hydrogen bonds as the structure follows.

      Most metal oxides are
      • a)
        Covalent in nature
      • b)
        Acidic in nature
      • c)
        Basic in nature
      • d)
        None of these
      Correct answer is option 'C'. Can you explain this answer?

      Rashi Bose answered
      Most metal oxides are ionic crystals with high melting and boiling points. They are compounds that contain at least one metal and one oxygen atom, and are generally basic in nature. Metal oxides are basic because they react with acids to form salt and water, neutralizing the acids. 

      Which is the correct order of basic strength ?
      • a)
         NH2OH < N2H4 < NH3
      • b)
         N2H4 <  NH2OH < NH3
      • c)
         NH3 < N2H4 < NH2OH
      • d)
         NH2OH < NH3 < N2H4
      Correct answer is option 'A'. Can you explain this answer?

      Ashish Nambiar answered
      NH2OH and NH2—NH2 may be considered as NH3 derivatives in which H is replaced but — OH and NH2 respectively. Due to their electron withdrawing nature, these groups decreases electron density over nitrogen making them less basic. The effect of — OH group is stronger than —NH2

      The formula for calcium chlorite is [1994]
      • a)
        Ca(ClO4)2
      • b)
        Ca(ClO3)2
      • c)
        CaClO2
      • d)
        Ca(ClO2)2
      Correct answer is option 'D'. Can you explain this answer?

      The formula for calcium chlorite is Ca(ClO2)2. Let's break down the components of this compound to understand why this is the correct formula.

      Calcium:
      - Calcium is a metal with a +2 charge. It is represented by the symbol Ca in the periodic table.

      Chlorite:
      - Chlorite is a polyatomic ion with the formula ClO2-. It consists of one chlorine atom (Cl) bonded to two oxygen atoms (O), and it carries a -1 charge.

      Formation of calcium chlorite:
      - When calcium reacts with chlorite, the calcium ion (Ca2+) combines with two chlorite ions (ClO2-) to form calcium chlorite (Ca(ClO2)2).
      - The calcium ion has a +2 charge, while each chlorite ion has a -1 charge. To balance the charges, two chlorite ions are needed for every calcium ion.

      Explanation of options:

      a) Ca(ClO4)2:
      - This formula represents calcium perchlorate, not calcium chlorite. Perchlorate is a different polyatomic ion that consists of one chlorine atom and four oxygen atoms.

      b) Ca(ClO3)2:
      - This formula represents calcium chlorate, not calcium chlorite. Chlorate is another polyatomic ion that consists of one chlorine atom and three oxygen atoms.

      c) CaClO2:
      - This formula represents calcium hypochlorite, not calcium chlorite. Hypochlorite is a different polyatomic ion that consists of one chlorine atom and two oxygen atoms.

      d) Ca(ClO2)2:
      - This formula represents calcium chlorite, which is the correct compound. It consists of one calcium ion (Ca2+) bonded to two chlorite ions (ClO2-).

      In summary, the correct formula for calcium chlorite is Ca(ClO2)2, as it consists of one calcium ion bonded to two chlorite ions.

      Noble gases do not react with other elements because [1994]
      • a)
        They are mono atomic
      • b)
        They are found in abundance
      • c)
        The size of their atoms is very small
      • d)
        They are completely paired up and stable electron shells
      Correct answer is option 'D'. Can you explain this answer?

      Abhishek Desai answered
      On account of highly stable ns2 np6 configuration in the valence shell. These elements have no tendency either to lose gain or share electrons with atoms of other elements i.e., their combining capacity or valency is zero. Further all the orbitals in the atoms of these elements are doubly occupied i.e electrons are not available for sharing.

      Which one of the following  arrangements does not give the correct picture of the trends indicated against it ? [2008]
      • a)
        F2 > Cl2 > Br2 > I2 : Oxidizing power
      • b)
        F2 > Cl2 > Br2 > I2 : Electron gain enthalpy
      • c)
        F2 > Cl2 > Br2 > I2 : Bond dissociation energy
      • d)
        F2 > Cl2 > Br2 > I2 : Electronegativity.
      Correct answer is option 'B,C'. Can you explain this answer?

      Nisha Pillai answered
      From the given options we find option (a) is correct. The oxidising power of halogens follow the order F2 > Cl2 > Br2 > I2 . Option (b) is incorrect because it in not the correct order of electron gain enthalpy of halogens. The correct order is Cl2 > F2 > Br2 > I2 . The low value of F2 than Cl2 is due to its small size. Option (c) is incorrect. The correct order of bond dissociation energies of halogens is Cl2 > Br2 > F2 > I2 . Option (d) is correct. It is the correct order of electronegativity values of halogens. Thus option (b) and (c) are incorrect.

      Which of the following statements is not correct?
      • a)
        Helium has the lowest boiling point among the noble gases
      • b)
        Argon is used in electric bulbs
      • c)
        Krypton is obtained during radioactive disintegration
      • d)
        Xe forms XeF6
      Correct answer is option 'C'. Can you explain this answer?

      Swati Bose answered
      Explanation:

      The correct statement is option 'C': Krypton is obtained during radioactive disintegration.

      Explanation:

      - Statement a: Helium has the lowest boiling point among the noble gases.
      - This statement is correct. Helium has the lowest boiling point (-268.93°C) among all the noble gases. It is a colorless and odorless gas that remains in a gaseous state at room temperature and pressure.

      - Statement b: Argon is used in electric bulbs.
      - This statement is correct. Argon is commonly used in electric bulbs to maintain an inert atmosphere and prevent oxidation of the filament. It is an abundant noble gas and is chemically inert.

      - Statement c: Krypton is obtained during radioactive disintegration.
      - This statement is incorrect. Krypton is not obtained during radioactive disintegration. Krypton (Kr) is a noble gas that is chemically unreactive and does not undergo radioactive disintegration. It is obtained through the fractional distillation of liquid air.

      - Statement d: Xe forms XeF6.
      - This statement is correct. Xenon (Xe) can form compounds, and one of them is xenon hexafluoride (XeF6). XeF6 is a strong oxidizing agent and is used in chemical reactions and synthesis.

      Therefore, the correct statement is option 'C': Krypton is obtained during radioactive disintegration. Krypton is not obtained through radioactive disintegration, but rather through fractional distillation of liquid air.

      When carnallite is dissolved in water the number of ions formed are
        Correct answer is '5'. Can you explain this answer?

        Carnallite is a double salt. It will dissociate into simple substances or ions completely when dissolved in water.

        Hence, 5 ions are produced.

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