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Organic Analysis - Chemistry MCQ


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30 Questions MCQ Test Mock Test Series for IIT JAM Chemistry - Organic Analysis

Organic Analysis for Chemistry 2024 is part of Mock Test Series for IIT JAM Chemistry preparation. The Organic Analysis questions and answers have been prepared according to the Chemistry exam syllabus.The Organic Analysis MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Organic Analysis below.
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Organic Analysis - Question 1

Which of the following compound is expected to show a sharp singlet for one of its protons at δ ≥ 8 ppm in 1H NMR spectrum, given that this signal remains unaffected on shaking the solution thoroughly with D2O?           

Organic Analysis - Question 2

Sometimes, the color observed in Lassaigne’s test for nitrogen is green. It is because of:           

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Organic Analysis - Question 3

Arrange the following molecules, in their chemical shift value(s) of ortho hydrogen in 1H NMR:

Organic Analysis - Question 4

Consider the following:
 

Order of C-H stretching frequency in IR-spectroscopy would be:

Organic Analysis - Question 5

The major product B is:

Organic Analysis - Question 6

The complementary strand of DNA for the following single stranded DNA sequence:   is:   
 

Organic Analysis - Question 7

The correct sequence of the amino acids present in the tripeptide given below is:

Organic Analysis - Question 8

One amongst the following is an alcoholic amino acid?           

Organic Analysis - Question 9

Consider the following:
   
Order of stretching frequency in IR-spectroscopy would be:

Organic Analysis - Question 10

For the detection of sulfur in an organic compound, Lassaigne’s extract is acidified with acetic acid. Lead acetate solution is then added to it. The black precipitate formed is due to the formation of ?           

Organic Analysis - Question 11

Which of the following compound show only two signals in 1H NMR and a strong IR bond at 
~1690 cm–1:
 

Organic Analysis - Question 12

A compound with molecular formula C5H10O does not form, 2, 4-DNP derivative. It responds positively to Iodoform test and on ozonolysis gives one mole formaldehyde. It could be:

Organic Analysis - Question 13

The correct match of the 1H NMR chemical shift d of the following species/compound is:
 

Organic Analysis - Question 14

In the Lassaigne’s test for the detection of nitrogen in an organic compound, the Prussian blue colour is due to the formation of _______________:           

Organic Analysis - Question 15

The correct order of 1H NMR chemical shift (δ) values for the labeled methyl groups in the following compound is:

Organic Analysis - Question 16

The Beckmann rearrangement of a bromo-acetophenone oxime (C8H8BrNO) gives a major product having the following 1H NMR – 9.85 (S, 1H), 7.88 (S, 1H), 7.45 (d, 1H, J=7.2), 7.17 (m, 1H, 7.12 (d, 1H, J=7.0 Hz), 2.06 (S, 3H). The structure of the product is:

Organic Analysis - Question 17

The absorption at lmax 279 nm (ε = 15) in the UV spectrum of acetone is due to:

Organic Analysis - Question 18

Match the following compounds with their respective classes:
  

 

Organic Analysis - Question 19

The structure of D-(+)-glucose is:

The structure of L-(–)-glucose is:

Organic Analysis - Question 20

Which of the following compounds will behave as a reducing sugar in an aqueous KOH solution?

Organic Analysis - Question 21

Consider the following: 


Order of their stretching frequency in IR-spectroscopy would be:

           

Organic Analysis - Question 22

In the UV-visible absorption spectrum of an α, β-unsaturated carbonyl compound, with increasing solvent polarity:

Organic Analysis - Question 23

Among the following, the compound that displays an IR band at 2150 cm–1 is:

Organic Analysis - Question 24

The compound which shows IR frequencies at both 3314 and 2126 cm–1 is:

Organic Analysis - Question 25

 

Organic Analysis - Question 26

Compound I gives a strong infrared absorption at 1730 cm–1. 1H NMR spectrum indicates that it has two types of hydrogen atoms; one H atom appearing as singlet at δ = 9.7 ppm and 9H atoms appearing as a singlet at δ = 1.2 ppm. The structure of I is:

Organic Analysis - Question 27

Major product would be

Organic Analysis - Question 28

The major product of the following is:

Organic Analysis - Question 29

Consider the following:

Order of C-O stretching frequency in IR-spectroscopy would be:

            

Organic Analysis - Question 30

During the detection of sulfur in an organic compound, the violet color formed by the addition of Sodium nitroprusside to Lassaigne’s extract is due to _____________:           

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