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PYQ Test: Thermodynamics(26 Feb) - JEE MCQ


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10 Questions MCQ Test Daily Test for JEE Preparation - PYQ Test: Thermodynamics(26 Feb)

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PYQ Test: Thermodynamics(26 Feb) - Question 1

The heat required to raise the temperature of body by 1 K is called [2002]

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 1

The heat required to raise the temperature of body by 1K is called thermal capacity or heat capacity.

PYQ Test: Thermodynamics(26 Feb) - Question 2

The internal energy change when a system goes from state A to B is 40 kJ/mole. If the system goes from A to B by a reversible path and returns to state A by an irreversible path what would be the net change in internal energy ? [2003]

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 2

For a cyclic process then net change in the internal energy is zero because the change in internal energy does not depend on the path.

PYQ Test: Thermodynamics(26 Feb) - Question 3

If at 298 K the bond energies of C — H, C — C, C = C and H — H bonds are respectively 414, 347, 615 and 435 kJ mol–1, the value of enthalpy change for the reaction H2C = CH2(g) + H2(g) → H3C — CH3(g) at 298 K will be [2003] 

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 3

CH2 = CH2(g) + H2(g) → CH3 - CH3
Enthalpy change = Bond energy of reactants – Bond energy of products.
ΔH = 1(C = C) + 4 (C – H) + 1 (H - H) - 1 (C - C) - 6 (C - H)
         = 1 (C = C) + 1 ( H – H) – 1 (C – C) – 2 (C– H)
        = 615 + 435 – 347 – 2 × 414  = 1050 – 1175 = –125 kJ.

PYQ Test: Thermodynamics(26 Feb) - Question 4

In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (ΔG) and  change in entropy (dS), satisfy the criteria [2003]  

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 4

For spontaneous reaction, dS > 0 and ΔG should be negative i.e. < 0.

PYQ Test: Thermodynamics(26 Feb) - Question 5

The correct relationship between free energy change in a reaction and the corresponding equilibrium constant Kc is [2003] 

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 5

ΔGº = – RT lnKc or – ΔGº = RT lnKc

PYQ Test: Thermodynamics(26 Feb) - Question 6

The enthalpy change for a reaction does not depend upon [2003]

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 6

Enthalpy change for a reaction does not depend upon the nature of intermediate reaction steps.

PYQ Test: Thermodynamics(26 Feb) - Question 7

An ideal gas expands in volume from 1×10–3 to 1 × 10–2 m3 at 300 K against a constant pressure of 1×105 Nm–2. The work done is [2004] 

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 7

 w = -PΔV = -10-5 (1x10 -2 - 1x10 -3) = -900J

PYQ Test: Thermodynamics(26 Feb) - Question 8

The enthalpies of combustion of carbon and carbon monoxide are – 393.5 and – 283 kJ mol–1 respectively. The enthalpy of formation of carbon monoxide per mole is  

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 8

ΔH = –283.0 kJmol–1

Operating (i) - (ii), we have

 ΔH = -110.5 kJmol–1

PYQ Test: Thermodynamics(26 Feb) - Question 9

Consider an endothermic reaction X → Y with the activation en er gies Eb and Ef  for the backward and forward reactions, respectively. In general [2005]  

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 9

Enthalpy of reaction for an endothermic reaction ΔH = +ve hence for ΔH to be negative

PYQ Test: Thermodynamics(26 Feb) - Question 10

Consider the reaction : N2 + 3H2 → 2 NH3 carried out at constant temperature and pressure. If ΔH and ΔU are the enthalpy and internal energy changes for the reaction, which of the following expressions is true ? [2005]  

Detailed Solution for PYQ Test: Thermodynamics(26 Feb) - Question 10

ΔH = ΔU + ΔnRT for N2 + 3H2 —​→ 2 NH3
Δng = 2 – 4 = – 2
∴ΔH =ΔU-2RT or ΔU = ΔH+2RT ∴ΔU >ΔH

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