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CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Class 12 MCQ


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21 Questions MCQ Test - CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous)

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CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 1

Direction (Q. Nos. 1 - 8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

The formula of realgar and orpiment are

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 1

Realgar and orpirffent have chemical formulae as As2S4 and As2S3 respectively.

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 2

Correct order of 2nd ionisation energy of C, N, O and F is

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 2

The correct order is O > F > N > C.

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CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 3

Which trend enthalpy is correct? 

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 3

  bond energies are more for nitrogen while others are weaker compared to phosphorus.

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 4

Boiling point of liquid nitrogen is

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 4

 Boiling point of

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 5

Oxidation of ammonia with CuO produce a gaseous chemical which can also be obtained by

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 5

Gaseous chemical formed by the oxidation of ammonia with CuO is nitrogen.


The same is obtained by reacting excess ammonia with chlorine 

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 6

Which of the molecular species has unpaired electrons?

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 6

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 7

Which is the correct order w.r.t the given property?

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 7

The electronegativity decrease down the gro up with increasing atomic size. However, amongst the heavier elements, the difference is not much pronounced.
Hence, the correct order of electronegativity is as follows:

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 8

The ratio of bond pairs and lone pairs in a P4 molecule is

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 8

P4 molecule has 6 bond pairs and 4 lone pairs, i.e. ratio is 3 :2.

*Multiple options can be correct
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 9

Direction (Q. Nos. 9-13) This section contains 5 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.

Q. 

Regarding black phosphorus correct statements are

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 9

Being good conductor of heat and electricity, black phosphorus is a most stable allotrope of phosphorus.

*Multiple options can be correct
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 10

Which are correct statements?

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 10

Maximum covalency of nitrogen and phosphorus are 4 and 6 respectively. Phosphorus have vacant d-orbitals in the outermost shell which can be used for bonding hence, expand their covalency upto 6.

*Multiple options can be correct
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 11

The correct statements regarding N and P are

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 11

White phosphorus is a translucent white waxy solid. It is poisonous, insoluble in water but soluble inCS2. Red phosphorus is insoluble in water as well as in CS2

*Multiple options can be correct
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 12

The correct statements among the given are

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 12

Minimum and maximum oxidation number of phosphorus is -3 and +5 respectively.
The electron gain enthalpy of P < N < S < O.

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 13

Which of the following statements is/are correct?

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 13

A molecule of N2 has the pπ-pπ bonding with each other respectively and the abundance in the earth's crest follows

P > N > As > Sb

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 14

Direction (Q. Nos. 14 and 15) This section contains a paragraph, describing theory, experiments, data, etc. Two questions related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage

Phosphorus was discovered by Brand (1669), Scheele isolated from bone ash and Lavoisier proved its elemental nature (1777). The principal minerals are phosphate rock, fluoroapatite and chloroapatite. Phosphorus is prepared by the direct reduction of phosphorite by carbon in the presence of silica. It exists in different allotropic forms such as yellow or white, red, α-black, β-black, etc. White P is most reactive, poisonous, glows in dark and readily catches fire due to unstable discrete P4 molecules. Red P is inert, non-poisonous, does not glow etc., due to its polymeric structure, α-black, β -black allotropes are also chemically inert, do not ignite at normal temperature. It has layer structure like graphite and acts as conductor.

Q. 

The allotrope of phosphorus with low ignition temperature is

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 14

White P is an allotrope of phosphorus with low ignition temperature.

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 15

Phosphorus was discovered by Brand (1669), Scheele isolated from bone ash and Lavoisier proved its elemental nature (1777). The principal minerals are phosphate rock, fluoroapatite and chloroapatite. Phosphorus is prepared by the direct reduction of phosphorite by carbon in the presence of silica. It exists in different allotropic forms such as yellow or white, red, α-black, β-black, etc. White P is most reactive, poisonous, glows in dark and readily catches fire due to unstable discrete P4 molecules. Red P is inert, non-poisonous, does not glow etc., due to its polymeric structure, α-black, β -black allotropes are also chemically inert, do not ignite at normal temperature. It has layer structure like graphite and acts as conductor.

Q. 

The allotrope of phosphorus that has layer lattice like graphite is

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 15

Black P has layer lattice like graphite.

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 16

Direction (Q. Nos. 16 and 17) Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct.

Match the Column I with Column li and mark the correct option from the codes given below. 

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 16

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 17

Match the Column I with Column II and mark the correct option from the codes given below.

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 17

*Answer can only contain numeric values
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 18

Direction (Q. Nos. 18-20) This section contains 3 questions. When worked out wilt result in an integer from 0 to 9 (both inclusive).

Q. 

How many of the given chemicals liberate dinitrogen on heating?


Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 18

 4 chemicals liberate dinitrogen on heating. 

*Answer can only contain numeric values
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 19

Number of chemical species having negative oxidation state for nitrogen among


Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 19

Except in NF3, N2O and NO-2, in all others N has negative oxidation states.

*Answer can only contain numeric values
CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 20

According to moiecular orbital theory, number of electrons present in the antibonding orbitals of dinitrogen.


Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 20

CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 21

Direction (Q. No. 21) This section is based on Statement I and Statement II. Select the correct answer from the codes given below.

Q. 

Satement I : N2 is less reactive than P4.

Statement II : Nitrogen has more electron gain enthalpy than phosphorus.

Detailed Solution for CPU 1 - General Properties Of 15Th Group (Nitrogen & Phosphorous) - Question 21

P— P single bo nd in P4 molecule is much weaker
(213 kJ mol-1) than triple bond (941.4 kJ mol-1) in N2.

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