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QUESTION: 1

Br^{–} ion forms a closed packed structure. If the radius of it is 195 pm. Which of the following is true?

Solution:

QUESTION: 2

In fcc crystal lattice, edge length is 400 pm. Find the diameter of greatest sphere which can be fitted into the interstitial vo id without distortion of lattice:

Solution:

QUESTION: 3

For a Ag-Zn button cell, net reaction is, Zn(s) + Ag_{2}O(s) → ZnO(s) + 2Ag(s) ΔGf(Ag_{2}O) = -11.21 kJ mol^{-1}, ΔG_{f}(ZnO) = -318.3 kJ mol^{-1}, 1 Faraday = 96500C Hence, E°cell of the button cell is:

Solution:

QUESTION: 4

Sn^{2+} + 2e^{–} → Sn, E^{0} = – 0.14 V

Sn^{4+} + 2e^{- }→ Sn^{2+}, E^{0} = + 0.13 V

Which of the following is true?

Solution:

QUESTION: 5

Each Rubidium halide crystallizing in the NaCl type lattice has a unit cell length 30 pm greater than for corresponding potassium salt (R_{K}^{+} = 133 pm) of the same halogen. What is ionic radius of Rb^{+}?

Solution:

QUESTION: 6

At what glancing angle would the first order diffraction occur, when copper radiation (wavelength = 154 pm) interacts with lattice planes that are 154 pm apart?

Solution:

QUESTION: 7

% of free space in ccp and bcc structure are, respectively:

Solution:

QUESTION: 8

In fcc lattice, atom A occupies the corner position and B occupies the face center positions. If one atom of B is missing from one of the Face centered positions, the formula of compound is?

Solution:

QUESTION: 9

The distance between two successive (110) planes in a simple cubic lattice with lattice parameter ‘a’ is:

Solution:

QUESTION: 10

CsBr crystal has a bcc structure. It has an edge length of 4.3 Å. The shortest interionic distance between cation and anion is

Solution:

QUESTION: 11

Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m^{3} and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.2^{0}. Identify the crystal plane which caused this diffraction. (N_{A} = 6.023 × 10^{23})

Solution:

QUESTION: 12

If unit cell of a material has ccp array of Oxygen atoms with ‘m’ fraction of Octahedral holes occupied by Aluminium ions and ‘n’ fraction of Tetrahedral holes occupied by Magnesium ions. Then ‘m’ and ‘n’ are respectively:

Solution:

QUESTION: 13

Silver has a density of 10.5 g/cm^{3}. The number of Silver atoms on a surface of area 10^{–12} m^{2} can be expressed in scientific notation as y × 10^{x}. The value of ‘x’ is? (Given. At.Wt of silver = 108g/mol)

Solution:

QUESTION: 14

Match axial parameters given in List-I with crystal systems given in List-II and select the correct answer using the codes given below the lists:

Solution:

QUESTION: 15

Consider the following equations for a cell reaction:

A+B → C+D E^{0} = x; K_{eq} = k_{1}

2A+2B → 2C +2D E^{0} = y; K_{eq} = k_{2}

Solution:

QUESTION: 16

Match the following:

Solution:

QUESTION: 17

For the reactions,

Then, for the reaction,

Solution:

QUESTION: 18

A compound M_{p}X_{q} has cubic close packing (ccp) arrangement of X. Its unit cell structure is shown below. The empirical formula of the compound is:

Solution:

QUESTION: 19

CH_{3}COOH is titrated with NaOH solution. Which is true statement:

Solution:

QUESTION: 20

The conductivity of the saturated solution of some bivalent salt XY is 3.06 × 10^{–6} ohm^{–1} cm^{–1} and its equivalent conductivity is 1.53 ohm^{–1} cm^{2} equiv^{–1}. The value of K_{sp} of XY is:

Solution:

QUESTION: 21

In the following electrochemical cell: Zn|Zn^{+2}||H^{+}|H_{2}(Pt) and E^{0}_{cell} = E_{cell}

This is possible when:

Solution:

QUESTION: 22

The X at 1 atm is bubbled through a solution containing a mixture of 1 MY^{–} and 1 MZ^{–} at 25°C. If the order of reduction potential is Z < Y > X, then:

Solution:

QUESTION: 23

The ionization constant of a weak electrolyte is 25 × 10^{–6} while the equivalent conductance of its 0.01 M solution is 19.6 s cm^{2 }eq^{–1}. The equivalent conductance of the electrolyte at infinite dilution (in 5 cm^{2} eq^{–1}) will be:

Solution:

QUESTION: 24

The standard reduction potential at 298 K for the following half cells are given:

Which is the strongest reducing agent:

Solution:

QUESTION: 25

Which of the following solutions of KCl has the lowest value of specific conductance?

Solution:

QUESTION: 26

Consider the given data:

E° for the reaction,

Solution:

QUESTION: 27

For the electrochemical cell,

= V and M° _{X / X}- = 0.33 V.

= From this data we can deduce that:

Solution:

QUESTION: 28

The specific conductivity of solution depends upon:

Solution:

QUESTION: 29

In a solution, cations H^{+}, Li^{+}, Na^{+} and K^{+} are present. The one with highest ionic mobility and another with lowest ionic mobility respectively are:

Solution:

QUESTION: 30

An aqueous solution containing 0.01 M FeCl_{3} and 0.06 M HClO_{4} has the same ionic strength as a solution of:

Solution:

*Multiple options can be correct

QUESTION: 31

Which of the following statements are correct:

Solution:

*Multiple options can be correct

QUESTION: 32

For the cell prepared from electrode A and B; Electrode A: Cr_{2}O_{7}^{2–}| Cr^{3+}, E°_{red }= + 1.33 V and electrode B; Fe^{3+}|Fe^{2+}, E°_{red} = 0.77 V.

Which of the following statements are correct:

Solution:

*Multiple options can be correct

QUESTION: 33

Select the correct statements about solid crystals:

Solution:

*Multiple options can be correct

QUESTION: 34

p-type semiconductors are produced when:

Solution:

*Multiple options can be correct

QUESTION: 35

If the radius of Na^{+} ion is 95 pm and that of Cl^{–} ion is 181 pm. Then:

Solution:

*Multiple options can be correct

QUESTION: 36

Which is the incorrect statement:

Solution:

*Multiple options can be correct

QUESTION: 37

In which of the following structures, the coordination number of both the ions are same:

Solution:

*Multiple options can be correct

QUESTION: 38

Which of the following are concentration cells?

Solution:

*Multiple options can be correct

QUESTION: 39

Which is/are correct match about coductometric titration:

Solution:

*Multiple options can be correct

QUESTION: 40

Which of the following statements is correct for ionic mobility?

Solution:

*Answer can only contain numeric values

QUESTION: 41

A 0.05 N solution of a salt occupying a volume between two platinum electrodes separated by a distance of 1.72 cm and having an area of 4.5 cm^{2 }has a resistance of 250 ohm. Calculate the equivalent conductance (in s^{–1} cm^{2} eq^{–1}) of the solution [rounded up to two decimal places]:

Solution:

*Answer can only contain numeric values

QUESTION: 42

An electric current of 100 ampere is passed through a molten liquid of sodium chloride for 5 hours. Calculate the volume (in L) of chlorine gas liberated at the electrode at NTP. (Consider volume at NTP = 22.4L, 1F = 96500C & calculate the answer up to two decimal places):

Solution:

*Answer can only contain numeric values

QUESTION: 43

For the following reaction,

Given: and

Calculate –log10 K_{sp}(AgCl) at 298 K [rounded up to two decimal places].

Solution:

*Answer can only contain numeric values

QUESTION: 44

In silicates, the Oxygen atom form a tetrahedral void and the limiting ratio for tetrahedral void is 0.22. The radius of oxide is 1.4Å. Find out the radius of cation [rounded up to three decimal places]:

Solution:

*Answer can only contain numeric values

QUESTION: 45

A compound form hexagonal close packed. What is the total number of voids (up to two decimal places & in the multiple of 10^{23}) in 0.5 mol of it? [rounded up to three decimal places]

Solution:

*Answer can only contain numeric values

QUESTION: 46

Li forms bcc structure. The length of side of its unit cell is 351 pm. Atomic radius (in pm & up to first decimal places) of Lithium will be?

Solution:

*Answer can only contain numeric values

QUESTION: 47

X-ray of wavelength 0.154 nm striking an Aluminium crystal, get reflected at an angle of 25.5^{0} showing first order diffraction. Calculate the spacing between plane of aluminium atoms (in pm, rounded up to first decimal places):

Solution:

*Answer can only contain numeric values

QUESTION: 48

Given the E° values for the following react ion sequence,

The computed value of E° for (rounded up to two decimal place)

Solution:

*Answer can only contain numeric values

QUESTION: 49

If 0.01 M solution of an electrolyte has a resistance of 40 ohm in a cell having a cell constant of 0.4 cm^{–1}, then, its molar conductance in ohm^{–1} cm^{2} mol^{–1} will be:

Solution:

*Answer can only contain numeric values

QUESTION: 50

Calculate the pH (rounded up to two decimal places) of the following half-cell solution at 298K.

Pt(H_{2}, 1atm) | H^{+}(HCl); E = 0.25 volt

Solution:

*Answer can only contain numeric values

QUESTION: 51

Radius of Be^{+2} is 59 pm and that of S^{–2} is 170 pm. Find out the coordination number:

Solution:

*Answer can only contain numeric values

QUESTION: 52

In a diffraction experiment with X-rays of wavelength 1.54 Å, a diffraction line corresponding to 2q = 20.8° is observed. The inter-planar separation in Å is _________: (rounded up to two decimal place)

Solution:

*Answer can only contain numeric values

QUESTION: 53

To find the standard potential of M^{3+}/M electrode, the following cell is constituted. Pt|M|M^{3+} (0.0018 mol^{–1}L) || Ag^{+} (0.01 mol^{–1}L)|Ag The emf of this cell is found to be 0.42 volt. Calculate the standard potential of the anode half (up to two decimal places). Given E^{0}_{Ag+|Ag} = 0.80 Volt.

Solution:

*Answer can only contain numeric values

QUESTION: 54

A metal crystallizes in two cubic phases, fcc and bcc whose unit cell lengths are 3.5Å and 3.0Å resp. Calculate the ratio (up to two decimal places) of densities of fcc to bcc.

Solution:

*Answer can only contain numeric values

QUESTION: 55

The specific conductivity of 0.02 M KCl solution at 25°C is 2.768 × 10^{–3} ohm^{–1 }cm^{–1}. The resistance of this solution at 25°C when measured with a particular cell was 250.2 ohms. The resistance of 0.01 M CuSO_{4} solution at 25°C measured with the same cell was 8331 ohms. Calculate the molar conductivity (in s^{–1} cm^{2 }mol^{–1}& rounded up to three decimal places) of the copper sulfate solution:

Solution:

*Answer can only contain numeric values

QUESTION: 56

What is the value of pK_{b} (CH_{3}COO^{–}) if λ°_{m} 390 & λ_{m }= 7.8 for 0.04 M CH_{3}COOH at 25°C?

(rounded up to two decimal place):

Solution:

*Answer can only contain numeric values

QUESTION: 57

Calculate the percentage of unoccupied volume in case of metal crystal of primitive cubic: [rounded up to two decimal places]

Solution:

*Answer can only contain numeric values

QUESTION: 58

The edge length of unit cell of a metal having molecular weight 75g/mol is 5Å which crystallizes in cubic lattice. If the density is 2g/cm^{3}, then, find the radius (in pm, rounded up to first decimal places) of metal atom:

Solution:

*Answer can only contain numeric values

QUESTION: 59

Consider the cell Cd|CdCl_{2}.2H_{2}O|AgCl_{(s)}| Hg

The emf of the cell at 15°C is 0.67531 V and temperature coefficient of emf is 0.00065 V deg^{–1}. Calculate the value of heat flow (in Joules/mol) if the process is carried reversibly: [rounded up to first decimal places]

Solution:

*Answer can only contain numeric values

QUESTION: 60

The angle at which the first order Bragg reflection is observed from (110) plane in a simple cubic unit cell of side 3.238 Å when chromium Kα radiation of wavelength 2.29 Å is used, is (rounded up to first decimal place):

Solution:

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