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Assertion & Reason Test: Redox Reactions - NEET MCQ


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Assertion & Reason Test: Redox Reactions - Question 1

In the following questions a statement of assertion (A) followed by a statement of reason (R) is given. Choose the correct option out of the choices given below each question. 
Assertion(A): Among halogens fluorine is the best oxidant.
Reason(R): Fluorine is the most electronegative atom.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 1

Assertion: Among halogens fluorine is the best oxidant
Oxidants - Oxidants are also known as oxidising agents.
These are those species which oxidise others and get reduced by tjemselves .
Thus, more is the tendency of species to get reduced, stronger will be its oxidising power.

Reason: Fluorine is the most electronegative atom.
Fluorine belongs to 17th group, Electronic configuration of Fluorine is −1s2 2s2 2p5
Thus, fluorine needs only one electron to achieve stable inert gas configuration and has very small size. Hence, fluorine is the most electronegative atom.
The given assertion is correct and given reason is also correct. But reason is not the correct explanation of assertion.

Assertion & Reason Test: Redox Reactions - Question 2

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : Among halogens fluorine is the best oxidant.

Reason (R) : Fluorine is the most electronegative atom.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 2
Fluorine (F2) has the maximum E0 value (+2.87 V) among the halogens, hence, it reduces first than other halogens and acts as the best oxidant. Fluorine is the most electronegative atom due to its small size.

Hence, both assertion and reason are correct but reason is not the correct explanation for assertion.

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Assertion & Reason Test: Redox Reactions - Question 3

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent.

Reason (R) : Oxidation state of manganese changes from +2 to +7 during the reaction.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 3
In the reaction given in assertion, the oxidation number changes from +7 to +4.
Assertion & Reason Test: Redox Reactions - Question 4

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent.

Reason (R) : Oxidation state of manganese changes from +2 to +7 during

the reaction.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 4
2KMnO4 +2KI⟶2MnO2 +I2 ​+4KO

Oxidation state of Mn in 2KMnO4 is −2+2x−16=0

x=9

Oxidation state of Mn in 2MnO2 is 2x−8=0

x=4

The decrease of oxidation state indicates that Mn is oxidising agent

Assertion & Reason Test: Redox Reactions - Question 5

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.

Reason (R) : The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in O2 and – 2 oxidation state in H2O.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 5
Disproportionation is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states.

2H2O2(ag)→2H2O(l)+O2(g) Here the oxygen of peroxide, which is present in −1 state, is converted to zero oxidation state in O2 undergoing oxidation and decreases to −2 oxidation state in H2O undergoing reduction. So, it is an example of disproportionation reaction.

Hence, both assertion and reason are correct and reason is the correct explanation for assertion.

Assertion & Reason Test: Redox Reactions - Question 6

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.

Reason (R) : The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in O2 and –2 oxidation state in H2O.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 6
Disproportionation is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states.

2H2O2(ag)→2H2O(l)+O2(g) Here the oxygen of peroxide, which is present in −1 state, is converted to zero oxidation state in O2 undergoing oxidation and decreases to −2 oxidation state in H2O undergoing reduction. So, it is an example of disproportionation reaction.

So, it is an example of disproportionation reaction.Hence, both assertion and reason are correct and reason is the correct explanation for assertion.

Assertion & Reason Test: Redox Reactions - Question 7

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R) : In the representation and and are redox couples.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 7
In the reaction of an electrolytic cell both the reduced and oxidized forms of the same species are present. These are represented in the reduction and oxidation half reactions separately or combined form i.e., redox couple.
Assertion & Reason Test: Redox Reactions - Question 8

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A): Structure I is more accurate than II

Reason (R): More electronegative oxygen atom carries negative charge in I.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 8
Atoms are electrically neutral. They do not have net electrical charge.Number of protons and electrons are equal. Hence, total positive charges are balanced with total negative charges.
Assertion & Reason Test: Redox Reactions - Question 9

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R) : In the representation EOFe3+ /Fe2+ and EO Cu2+/Cu, Fe3+/ Fe2+ and Cu2+ / Cu are redox couples.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 9
A redox couple is defined as pair of compounds or elements having together the oxidised and reduced forms of it and taking part in an oxidation or reduction half-reaction. So, Fe3+/Fe2+and Cu2+/Cu are redox couples.

Both assertion and reason are true reason is the correct explanation of assertion.

Assertion & Reason Test: Redox Reactions - Question 10

Direction: In the following questions, a statement of assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Assertion (A) : In a reaction Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s) Zn is a reductant but itself get oxidized.

Reason (R) : In a redox reaction, oxidant is reduced by accepting electrons and reductant is oxidized by losing electrons.

Detailed Solution for Assertion & Reason Test: Redox Reactions - Question 10

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