Assertion & Reason Test: Acids, Bases & Salts - 1 - Class 10 MCQ

• Assertion (A): After white washing the walls, a shiny white finish on walls is obtained after two to three days.

  • This statement is true. After applying whitewash (which typically contains calcium hydroxide, not calcium oxide directly), the walls initially appear wet and chalky. Over time, as the whitewash dries and carbon dioxide from the air reacts with calcium hydroxide, a shiny white finish develops.

• Reason (R): Calcium Oxide reacts with Carbon dioxide to form Calcium Hydrogen Carbonate which gives shiny white finish.

  • This statement is partly incorrect:
    Calcium oxide (CaO) reacts with carbon dioxide (CO2) to form calcium carbonate (CaCO3), not calcium hydrogen carbonate. Calcium carbonate can contribute to the shiny white appearance after whitewashing, but it does not form calcium hydrogen carbonate as stated.

• Assertion (A): When zinc is added to dilute hydrochloric acid, hydrogen is given off.

  • This statement is true. When zinc metal reacts with dilute hydrochloric acid (HCl), it produces zinc chloride (ZnCl2) and hydrogen gas (H2).

• Reason (R): Hydrogen chloride molecules contain hydrochloric acid and hydrogen atoms.

  • This statement is misleading:
    Hydrogen chloride (HCl) is a gas composed of hydrogen and chlorine atoms, not hydrogen atoms alone. It dissociates in water to form hydrochloric acid (HCl). However, this does not directly relate to the reaction of zinc with hydrochloric acid where hydrogen gas is produced due to the displacement reaction between zinc and the hydrogen ions in the acid.

• Assertion (A): Gas bubbles are observed when sodium carbonate is added to dilute hydrochloric acid.

  • This statement is true. When sodium carbonate (Na2CO3) reacts with dilute hydrochloric acid (HCl), carbon dioxide gas (CO2) is produced. The evolution of gas bubbles is observed as a result of this reaction.

• Reason (R): Carbon dioxide is given off in the reaction.

  • This statement is true and correctly explains why gas bubbles are observed. The reaction between sodium carbonate and hydrochloric acid produces carbon dioxide gas, which escapes as bubbles in the solution.

• Assertion (A): Ammonia solution is an alkali.

  • This statement is true. Ammonia solution (NH3 dissolved in water) is a weak alkali because it produces hydroxide ions (OH-) in aqueous solution, which can neutralize acids and turn red litmus paper blue.

• Reason (R): Ammonia solution turns blue litmus paper red.

  • This statement is false. Ammonia solution actually turns red litmus paper blue, not the other way around. Ammonia solution is basic (alkaline), so it turns red litmus paper blue and does not affect blue litmus paper (which remains blue).

Magnesium chloride present in common salt is a deliquescent substance i.e. it absorbs moisture from the air when kept in open.

• Assertion (A): Baking soda creates acidity in the stomach.

  • This statement is false. Baking soda (sodium bicarbonate, NaHCO3) is alkaline in nature, not acidic. It acts as a base and can neutralize acids in the stomach, helping to alleviate symptoms of acid reflux or indigestion by raising the pH level.

• Reason (R): Baking soda is alkaline.

  • This statement is true. Baking soda is indeed alkaline. When ingested, it reacts with stomach acid (hydrochloric acid, HCl) to form carbon dioxide gas, water, and salt, which can help to neutralize excess stomach acid.

• Assertion (A): Plaster of Paris is used by doctors for setting fractured bones.

  • This statement is true. Plaster of Paris (calcium sulfate hemihydrate, CaSO4·0.5H2O) is commonly used in medicine for immobilizing broken bones. It is mixed with water to form a paste that sets into a hard mass, providing support and stability to the fractured limb.

• Reason (R): When Plaster of Paris is mixed with water and applied around the fractured limbs, it sets into a hard mass.

  • This statement is true and correctly explains why plaster of Paris is effective in setting fractured bones. When mixed with water, plaster of Paris undergoes an exothermic reaction, forming gypsum (calcium sulfate dihydrate, CaSO4·2H2O), which hardens rapidly into a solid mass.

• Assertion (A): While dissolving an acid or base in water, the acids must always be added slowly to water with constant stirring.

  • This statement is true. When dissolving acids or bases in water, especially concentrated solutions, adding them slowly to water with stirring helps to control the reaction and prevents splashing or excessive heat generation.

• Reason (R): Dissolving an acid or base in water is a highly exothermic reaction.

  • This statement is true. The process of dissolving strong acids or bases in water is exothermic, meaning it releases heat.

• Assertion (A): On adding H2SO4 to water, the resulting aqueous solution gets corrosive.

  • This statement is true. Sulfuric acid (H2SO4) is a strong acid that dissociates completely in water to form hydronium ions (H3O+) and sulfate ions (SO4^2-). The resulting solution is highly acidic and corrosive to many materials.

• Reason (R): Hydronium ions are responsible for corrosive action.

  • This statement is true and correctly explains why the solution becomes corrosive. Hydronium ions (H3O+) in acidic solutions have a high affinity for reacting with materials, causing corrosion or damage to surfaces they come into contact with.

• Assertion (A): Phenolphthalein gives a pink color in basic solution.

  • This statement is true. Phenolphthalein is an indicator that turns pink in basic or alkaline solutions with a pH greater than 8.2.

• Reason (R): Phenolphthalein is a natural indicator.

  • This statement is false. Phenolphthalein is a synthetic indicator, not a natural one. It is synthesized in the laboratory and is widely used in acid-base titrations and as a pH indicator.

Assertion:

"HCl gas does not change the colour of dry blue litmus paper."

• This statement is true. Dry HCl gas cannot release hydrogen ions (H⁺) because it needs to be dissolved in water to form hydronium ions (H3O+H_3O^+H3​O+), which cause the acidic effect. Therefore, HCl gas will not change the colour of dry blue litmus paper.

Reason:

"HCl gas dissolves in the water present in wet litmus paper to form H⁺ ions."

• This statement is also true. When HCl gas dissolves in the water present on wet litmus paper, it dissociates to form H⁺ ions, which can then change the colour of blue litmus to red, indicating an acidic environment.

Conclusion:

Both the assertion and reason are true, and the reason correctly explains the assertion.

Thus, the correct answer is:

Option 1: Both assertion (A) and reason (R) are true and reason (R) is the correct explanation of assertion (A).

• Assertion (A): HCl produces hydronium ions (H3O+) and chloride ions (Cl-) in aqueous solution.

  • This statement is true. When hydrogen chloride (HCl) dissolves in water, it dissociates completely into hydronium ions (H3O+) and chloride ions (Cl-). The reaction can be represented as: 

• Reason (R): In presence of water, bases give H+ ions.

  • This statement is false. Bases do not give H+ ions in water; they give OH- ions instead. The presence of OH- ions characterizes a basic solution, not H+ ions.

Assertion (A): Sodium hydroxide reacts with zinc to produce hydrogen gas.

• This statement is true. When sodium hydroxide (NaOH) reacts with zinc (Zn), it produces hydrogen gas (H2).

Zn (s) + 2NaOH (aq) → Na₂ZmO₂ (aq)+ H₂ (g)

Reason (R): Acids react with active metals to produce hydrogen gas.

• This statement is also true. Acids such as hydrochloric acid (HCl) or sulfuric acid (H2SO4) react with active metals like zinc (Zn) to produce hydrogen gas.

• Assertion (A): Ammonia solution is an alkali.

  • This statement is true. Ammonia solution (NH3 dissolved in water) is considered an alkali because it produces hydroxide ions (OH-) when dissolved in water. It can neutralize acids and turn red litmus paper blue.

• Reason (R): Ammonia solution turns blue litmus paper red.

  • This statement is false. Ammonia solution actually turns red litmus paper blue, not red. This color change occurs because ammonia solution is basic (alkaline) and reacts with the red litmus paper to turn it blue.

Reason (R) : A lot of heat energy will be given out in the dilution of concentrated sulphuric acid. Ans. Correct option : (d) Explanation: Water is never added to concentrated sulphuric acid as it is an exothermic reaction and releases a large amount of heat energy.

- Assertion (A): True. Acid should be added to water with stirring to prevent exothermic reactions from causing splashes or eruptions.
- Reason (R): True. Adding acid to water decreases the concentration of H⁺ ions per unit volume as the solution becomes more diluted.
- The reason (R) correctly explains the safety aspect of dilution rather than the procedural necessity of adding acid to water.
- Correct choice: B. Both A and R are true, but R is not the correct explanation of A.