(T) imparts violet colour (V) Red gas (W) Red ppt.
(W) Red ppt. white ppt.
(U) gas (gives white fumes with HCl)
sublimes on heating Identify (T) to (Z).
The number of moles of acidified KMnO4 required to convert one mole of sulphite ion into sulphate ion is-
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N2(g) + 3H2 (g) 2NH3(g) ; Haber's process, Mo is used as -
Potash alum is a double salt, its aqueous solution shows the characteristics of-
The structure of the product formed in the reaction given below is -
Vapour pressure of pure water at 298 K is 23.8 torr. Thus, vapour pressure of a solution containing 6 g urea and 68.4 g sucrose in 10 moles of water is
Vapour pressure of nitrobenzene (molar mass = 123 g mol-1) is 3.6 kNm-2 and that of water (molar mass = 18 g mol-1) is 977 kNm-2. They form immiscible mixture at the given temperature. Thus, percentage of nitrobenzene in the vapour phase is
The vapour pressure of n-hexane at 350 K is 840 torr and that of cyclohexane is 600 torr. Mole fraction of hexane in the mixture that boils at 350 K and 1 atm pressure assuming ideal behaviour is
At 298 K, the vapour pressure of pure water is 23.76 mm Hg and that of an aqueous solution is 22.98 mm Hg. Thus, molality of solution is (assume dilute solution)
Elevation in boiling point of a molar (1 M) glucose solution (d = 1.2 g mL-1) is
Relative lowering of vapour pressure of a non-volatile solute X in water is 0.05. If Kb(H20) = 0.52° mol-1 kg-1.
(ΔTb) = elevation in boiling point assuming a dilute solution
(ATb)' = elevation in boiling point assuming a solution of moderate concentration then, {ΔTb) - {ΔTb)' =
Osmotic pressure of insulin solution at 298 K is found to be 0.0072 atm at 298 K. Hence, height of water column due to this pressure is (density of mercury = 13.6 g mL-1)
Which has maximum osmotic pressure at temperature T K?
There is formation of Prussian blue when Fe3+ reacts with [Fe(CN)6]4-. Two solutions as shown are separated by a semipermeable membrane AB. Due to osmosis, there is
Three solutions of following in water are isothermal conditions as given:
Thus,
Only One Option Correct Type
This section contains 7 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct
Q.
The degree of dissociation (α ) o f weak electrolyte AxBy is related to van’t Hoff factor (i) by the expression
[AIEEE 2011]
0.004 M Na2S04 aqueous solution is isotonic with 0.01 M glucose solution at 300 K. Thus, degree of dissociation of Na2S04 is
When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene, a freezing point depression of 2 K is observed. [Kf (benzene) = 1.72Kmol-1 kg]. The van’t Hoff factor (i) is
[IIT - JEE 2007]
An aqueous solution of a solute AB has boiling point of 101.08° C and freezes at -1 .80 °C . AB is found to be 100% ionised at boiling point. If Kb /Kf = 0.3, then AB
What is the correct increasing order of acidity of the following?
Which of the following can be used for the distinction of ethanol from phenol?
Consider the following reaction,
The above reaction can best be brought about by
Passage III
When suspected drunk drivers are tested with a breathalyser, the alcohol (ethanol) in the exhaled breath is oxidised to ethanoic acid with an acidic solution of potassium dichromate.
Q.
Under standard state, E°cell of the breathalyser would be
Passage III
When suspected drunk drivers are tested with a breathalyser, the alcohol (ethanol) in the exhaled breath is oxidised to ethanoic acid with an acidic solution of potassium dichromate.
Q.
Under the condition of unit activity of each species,emf recorded in the breathalyser at pH 4 would be
E° values of Mn+ + ne- → M are given below
Fe2+/Fe -0.44 V, Mg2+/Mg -2.37 V, Pt(H2)/H+ 0.00 V,
AI3+/AI -1.66 V , Zn2+/Zn - 0.76 V, Cu2+/Cu +0.34 V,
Ag+/Ag + 0.80 V, Ni2+/Ni -0.26 V
How many of the metals can be used to prevent corrosion of Ni to Ni2+?
A hydrogen-oxygen fuel cell opeartes on the simple reaction:
If the cell is designed to produce 1.46A of current and if the H2 is contained in a 1.0 L tank at 2.00 atm pressure at 298K, how long can the fuel cell operate(in hour) before the H2 runs out.(Assume unlimited supply of oxygen)
1 videos|26 docs|121 tests
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1 videos|26 docs|121 tests
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