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UP PGT Chemistry Mock Test - 10 - UPTET MCQ


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30 Questions MCQ Test UP PGT Mock Test Series 2024 - UP PGT Chemistry Mock Test - 10

UP PGT Chemistry Mock Test - 10 for UPTET 2024 is part of UP PGT Mock Test Series 2024 preparation. The UP PGT Chemistry Mock Test - 10 questions and answers have been prepared according to the UPTET exam syllabus.The UP PGT Chemistry Mock Test - 10 MCQs are made for UPTET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for UP PGT Chemistry Mock Test - 10 below.
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UP PGT Chemistry Mock Test - 10 - Question 1

The density (in g mL-1) of a 3.60 M sulphuric acid solution that is 29% H2SO4(Molar mass = 98 g mol-1) by mass will be -    

[AIEEE 2007]

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 1

The correct answer is Option C.

Mass % of H2SO4=29%
Therefore 100g solution contains 29g H2SO4

Let the density of solution (in g/ml) is d
Molarity of solution :

Hence the answer is 1.22g/ml.
 

UP PGT Chemistry Mock Test - 10 - Question 2

Electron gain enthalpy values of noble gases are positive because:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 2

Electron gain enthalpy values of noble gases are positive because they have stable electronic configuration and thus have no tendency to take additionalelectron.

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UP PGT Chemistry Mock Test - 10 - Question 3

amongst the following compounds, the optically active alkane having lowest molar mass is 

[AIEEE 2004]

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 3

Here all compounds except in option c are achiral. So automatically option c is correct.

UP PGT Chemistry Mock Test - 10 - Question 4

Which of the following is not a secondary pollutant

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 4

CO2 is not secondary pollutant.

UP PGT Chemistry Mock Test - 10 - Question 5

Why are enzymes highly specific?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 5

The correct answer is Option B.

Enzymes are highly selective catalysts, meaning that each enzyme only speeds up a specific reaction. The molecules that an enzyme works with are called substrates. The substrates bind to a region on the enzyme called the active site. There are two theories explaining the enzyme-substrate interaction.
 

UP PGT Chemistry Mock Test - 10 - Question 6

An element with atomic number will form a basic oxide________        

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 6

Sodium forms a basic oxide because it is a metal. Metals generally form basic oxides because they tend to donate electrons to oxygen atoms. In the case of sodium, when it reacts with oxygen, it forms sodium oxide, in which each sodium atom donates one electron to oxygen. This results in the formation of sodium ions (Na+) and oxide ions (O2-), which can combine to form the ionic compound sodium oxide. Sodium oxide is basic because it can react with water to form a solution of sodium hydroxide, a strong base.

 

UP PGT Chemistry Mock Test - 10 - Question 7

A photon of 4000  is used to break the iodine molecule, then the % of energy converted to the K.E. of iodine atoms if bond dissociation energy of I2 molecule is 246.5 kJ/mol is:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 7

Energy of one photon
Energy supplied by one mole photon in KJ/mole = 3.11×6×10−19×6×1023×10−3=297KJ/mole
% of energy converted to K.E.= 

UP PGT Chemistry Mock Test - 10 - Question 8

The pair of compounds, which cannot exist together in a solution is-

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 8

NaHCO3 + NaOH   Na2CO3 + H2O


Acidic  Base hydrogen

UP PGT Chemistry Mock Test - 10 - Question 9

A red solid is insoluble in water. However, it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is  

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 9

UP PGT Chemistry Mock Test - 10 - Question 10

In a first order reaction, the concentration of the reactant, decreases from 0.8 M to 0.4 M in 15 minutes. The time taken for the concentration to change from 0.1 M to 0.025 M is - 

[AIEEE-2004]

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 10

The correct answer is  Option A.
The concentration of the reactant decreases from 0.8M to 0.4M in 15 minutes, i.e. t1/2 = 15 minutes. Therefore, the concentration of the reactant will fall from 0.1M to 0.025M in two half lives. i.e.    2t1/2 = 2 × 15 = 30 minutes.

UP PGT Chemistry Mock Test - 10 - Question 11

Direction (Q. Nos. 13 and 14) This section contains a paragraph, describing theory, experiments, data, etc. Two questions related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage

In the all oxyacids of phosphorus, each phosphorus atom is in sp3-hybridised state. All these acids contain P—OH bonds, the hydrogen atom of which are ionisable imparting acidic nature to the compound. The ‘ous’ acids (oxidation state of P is + 1 or + 3) also have P—H bonds in which hydrogens are not ionisable.
The presence of P—H bonds in these acids imparts reducing properties. The structure of some oxyacids are drawn below:


 

 

Q. 

Although metaphosphoric acid is written as a monomer, it exists as a polymer (HPO3)n. The number of P—O—P bonds in cyclic trimetaphosphoric acid is

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 11


UP PGT Chemistry Mock Test - 10 - Question 12

Assuming (2s-2p) mixing is not operative, the paramagnetic species among the following is

[JEE Advanced 2014]

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 12

If (2s-2p) mixing is not operative, then

UP PGT Chemistry Mock Test - 10 - Question 13

Among the following elements, which one was initially placed in the 'rare earths' group in Mendeleev's Periodic Table?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 13

Cerium, a rare earth metal, was initially placed in the 'rare earths' group in Mendeleev's Periodic Table. Mendeleev organized elements into groups based on their similar chemical properties, and cerium was grouped with other rare earth elements due to its similar behavior.

UP PGT Chemistry Mock Test - 10 - Question 14

Prussian blue is represented by KFex[Fe(CN)6]. Value of x is

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 14

UP PGT Chemistry Mock Test - 10 - Question 15

Hardness of a water sample is 200 ppm CaCO3, Thus, molarity of CaCO3 is

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 15

Hard water has hardness = 200 ppm Thus, 106 mL(= 103 L)water has CaC03 =200 g =2 mol

UP PGT Chemistry Mock Test - 10 - Question 16

A 20.0 litre vessel initially contains 0.50 mole each of H2 and I2 gases. These substances react and finally reach an equilibrium condition. Calculate the equilibrium concentration of HI if Keq = 49 for the reaction H2 + I2  2HI.

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 16




UP PGT Chemistry Mock Test - 10 - Question 17

For noble gases radius is measured as:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 17

It is believed that Noble gases don't form (or rather don't easily form bonds). This way only Van der Waals radius is measured.

The rationale here is based on the fact that noble gases have very low chemical reactivity and their atomic radii are non bonded.

UP PGT Chemistry Mock Test - 10 - Question 18

What is the increasing order of reactivity of the following in an E2 reaction with ethanolic KOH solution?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 18

(III) is most reactive as it has most acidic β-H as well as it gives resonance stabilised alkene.Next to (III) is (IV) as it is tertiary. (I) is less reactive than (II) because (I) gives less substituted alkene.

UP PGT Chemistry Mock Test - 10 - Question 19

Approximately what percent of matter in the universe is believed to consist of hydrogen?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 19

Hydrogen is the most abundant element in the universe, accounting for about 75 percent of its normal matter, and was created in the Big Bang.

UP PGT Chemistry Mock Test - 10 - Question 20

Comprehension Type

Direction (Q. Nos. 14-16) This section contains a paragraph, describing theory, experiments, data, etc. Three questions related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage

An organic compound A (C7H16O) shows both enantiomerism and diastereomerism. Treatment of a pure enantiomer of A with Na2CrO4 /Dil. H2SO4 gives B (C7H14O) - Also A on dehydration with concentrated H2SO4 gives a single alkene C (C7H14). Ozonolysis of C followed by work-up with Zn-H2O gives D (C5H10O) as one of the product which gives racemic mixture on reduction with NaBH4.

Q. 

The structure of A satisfying the above criteria is

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 20

Since, A is completely saturated, it must contain more than one chiral carbon atoms in order to show both enantiomerism and diastereomerism. Also, C on ozonolysis gives D (C5H10O) as one product, other product must be CH3SHO. Hence, C must be 

UP PGT Chemistry Mock Test - 10 - Question 21

Product (B) will be : 

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 21

UP PGT Chemistry Mock Test - 10 - Question 22

Group 2 elements are:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 22

The Group II elements are powerful reducing agents. A reducing agent is the compound that gets oxidised in the reaction and, therefore, loses electrons.

M = Mg, Ca, Sr,Ba --> I will be using 'M' as the general symbol for a Group II element in this topic. 

UP PGT Chemistry Mock Test - 10 - Question 23

Choose the correct statement:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 23

The non metallic character decreases down the group.And we know the oxides of non-metal r acidic in genral.Hence acidic character of oxides decreases down d group. Down the group the size of the element increases, electronegativity decreases ,metallic character increases and hence the acidic character decrease.

UP PGT Chemistry Mock Test - 10 - Question 24

Water has a maximum density at _____ degree centigrade.

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 24

Water has a maximum density at 4-degree centigrade, this is because at 4-degree centigrade, as opposite forces are in balance that is like the formation of Ice and maintaining of the liquid phase of water. Any less than 4-degree centigrade or greater than 4-degree centigrade, the water density is lesser than that of 4-degree centigrade.

UP PGT Chemistry Mock Test - 10 - Question 25

What is the dominant intermolecular force or bond that must be overcome in converting liquid CH3CH2OH to vapours?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 25

CH3CH2OH is in liquid state due to association as a result of intermolecular H-bonding.

UP PGT Chemistry Mock Test - 10 - Question 26

When Al2O3 is electrolysed ,cation and anions are discharged. For a given quantity of electricity,ratio of number of moles of Al and O2 gas is 

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 26

When same quantity of electricity is passed, elements/gases are formed in the ratio of their equivalents
.

UP PGT Chemistry Mock Test - 10 - Question 27

What is wrong about enantiomers of 2-chloropropanoic acid?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 27

The correct answer is option D.
Pair of enantiomers react differently with pure enantiomers of other compounds.
 

UP PGT Chemistry Mock Test - 10 - Question 28

As you move from top to bottom down the periodic table:

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 28

As you move down a periodic table group, electronegativity decreases because the distance between the atomic nucleus and the valence electrons increases.

UP PGT Chemistry Mock Test - 10 - Question 29

A 5.2 molal aqueous solution of methyl alcohol (CH3OH) is supplied. What is the mole fraction of methyl alcohol in the solution?

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 29

UP PGT Chemistry Mock Test - 10 - Question 30

Direction (Q. Nos. 1-16) This section contains 16 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q. The correct statement for the molecule Csl-3 is

Detailed Solution for UP PGT Chemistry Mock Test - 10 - Question 30



Cs is electropositive element hence, it forms Cs+ ion. Hence, no covalent bonding.

Cs+ has stable inert gas configuration thus, Cs3+ is not formed.

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