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Chemistry Exam > Chemistry Tests > Organic Chemistry > Test: Pericyclic Level - 2 - Chemistry MCQ

Test: Pericyclic Level - 2 - Chemistry MCQ

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30 Questions MCQ Test Organic Chemistry - Test: Pericyclic Level - 2

Test: Pericyclic Level - 2 for Chemistry 2024 is part of Organic Chemistry preparation. The Test: Pericyclic Level - 2 questions and answers have been prepared according to the Chemistry exam syllabus.The Test: Pericyclic Level - 2 MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Pericyclic Level - 2 below.

Solutions of Test: Pericyclic Level - 2 questions in English are available as part of our Organic Chemistry for Chemistry & Test: Pericyclic Level - 2 solutions in Hindi for Organic Chemistry course. Download more important topics, notes, lectures and mock test series for Chemistry Exam by signing up for free. Attempt Test: Pericyclic Level - 2 | 30 questions in 90 minutes | Mock test for Chemistry preparation | Free important questions MCQ to study Organic Chemistry for Chemistry Exam | Download free PDF with solutions

Test: Pericyclic Level - 2 - Question 1

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 2

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The major product of the following reaction is:

A.
B.
C.
D.
None of these.

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Test: Pericyclic Level - 2 - Question 3

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The product of the following reaction is:

Detailed Solution for Test: Pericyclic Level - 2 - Question 3

[4+2] cycloaddition, COOMe remains as it is and stereochemistry of 2 Hydrogen remains cis.

Test: Pericyclic Level - 2 - Question 4

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 5

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The product of the following reaction is:

Test: Pericyclic Level - 2 - Question 6

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The product of the following reaction is:

Test: Pericyclic Level - 2 - Question 7

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The product of the following reaction is:

Test: Pericyclic Level - 2 - Question 8

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The product of the following reaction is:

A.
B.
C.
D.
None of these.

Test: Pericyclic Level - 2 - Question 9

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 10

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The product of the following reaction is:

Test: Pericyclic Level - 2 - Question 11

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 12

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 13

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 14

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 15

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 16

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The major product of the following is:

Detailed Solution for Test: Pericyclic Level - 2 - Question 16

Six membered transition state of chair form will give option A.

Test: Pericyclic Level - 2 - Question 17

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 18

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The reactivity of compound I-IV with maleic anhydride (V) follows the order:

A.
I < II < III < IV
B.
II < IV < III < I
C.
II < I < III < IV
D.
II < I < IV < III

Test: Pericyclic Level - 2 - Question 19

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Order of reactivity of the following dienes X, Y and Z in Diels-Alder reaction is:

A.
X > Z > Y
B.
Y > X > Z
C.
Y > Z > X
D.
X > Y > Z

Test: Pericyclic Level - 2 - Question 20

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Give the major product and the mechanism involved in the following reaction.

A.
2−bromohexane
B.
1−bromo1ethylcyclobutane
C.
none of these
D.
1−bromo1methylcyclopentane

Detailed Solution for Test: Pericyclic Level - 2 - Question 20

Test: Pericyclic Level - 2 - Question 21

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Amongst the following the compound that does not act as a diene in Diels-Alder reaction is:

Test: Pericyclic Level - 2 - Question 22

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In the reaction of Cyclopentadiene with acrylate ester giving diels-Alder reaction products, the interacting frontier orbitals are:

A.
HOMO of a diene and LUMO of a dienophile.
B.
HOMO of a dienophile and LUMO of a diene.
C.
HOMO of a diene and HOMO of a dienophile.
D.
LUMO of a diene and LUMO of a dienophile.

Test: Pericyclic Level - 2 - Question 23

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Diels-Alder reaction normally yields endo-adduct as a major product. This is due to:

A.
Higher stability of the product.
B.
Faster rate of formation of the endo product.
C.
Steric hindrance.
D.
Secondary orbital interactions between a diene and a dienophile.

Test: Pericyclic Level - 2 - Question 24

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Diels-Alder reaction is a:

A.
[2 + 2] Thermal cyclisation.
B.
[4 + 2] Photoaddition.
C.
[4 + 2] Cycloaddition.
D.
[3 + 3] Cycloaddition.

Test: Pericyclic Level - 2 - Question 25

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In the [4 + 2] cycloaddition of 1, 3-butadiene and ethylene:

A.
Overlap of the HOMO of butadiene with the LUMO of ethylene.
B.
Overlap of the HOMO of ethylene with the LUMO of butadiene.
C.
Both (a) and (b)
D.
None of these.

Test: Pericyclic Level - 2 - Question 26

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The major product of the reaction is:

Test: Pericyclic Level - 2 - Question 27

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The major product of the following reaction is:

Test: Pericyclic Level - 2 - Question 28

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The reaction of 1-bromo-2-fluorobenzene with furan in the presence of one equivalent to Mg gives

Test: Pericyclic Level - 2 - Question 29

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The diene which undergoes Diels–Alder reaction with maleic anhydride is:

Test: Pericyclic Level - 2 - Question 30

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In a Diels–Alder reaction, the most reactive diene amongst the following is:

A.
(4E)–1, 4–hexadiene.
B.
(4Z)–1, 4–hexadiene.
C.
(2E, 4E)–2, 4–hexadiene.
D.
(2Z, 4Z)–2, 4–hexadiene.

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