Chemistry Model Test - 2017 - IIT JAM


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60 Questions MCQ Test IIT JAM Past Year Papers and Model Test Paper (All Branches) - Chemistry Model Test - 2017

Chemistry Model Test - 2017 for IIT JAM 2023 is part of IIT JAM Past Year Papers and Model Test Paper (All Branches) preparation. The Chemistry Model Test - 2017 questions and answers have been prepared according to the IIT JAM exam syllabus.The Chemistry Model Test - 2017 MCQs are made for IIT JAM 2023 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Chemistry Model Test - 2017 below.
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Chemistry Model Test - 2017 - Question 1

Silver article turns black when kept in the open for a few days due to formation of     

Chemistry Model Test - 2017 - Question 2

The decreasing order of the first ionization energy of the following elements is

Chemistry Model Test - 2017 - Question 3

Which of these compounds are not aromatic in character ?

Chemistry Model Test - 2017 - Question 4

R- alanine is represented by______

Chemistry Model Test - 2017 - Question 5

Toluene when refluxed with bromine in the Presence of light gives mainly______

Chemistry Model Test - 2017 - Question 6

An element X on exposure to moist air turns reddish-brown and a new compound Y is formed. The substance X and Y are

Chemistry Model Test - 2017 - Question 7

If a Particle has linear momentum then its angular momentum is ________

Detailed Solution for Chemistry Model Test - 2017 - Question 7

Angular momentum
J = r × p

= (3i - j + k) × (2i + j + k)

= i(-1-1) +j(3-2) +k(3+2)

= -2i + j + 5k 

Chemistry Model Test - 2017 - Question 8

The chemical formula of lead sulphate is

Chemistry Model Test - 2017 - Question 9

An electron is found in an orbital with one radial node and two angular nodes. Which orbital electron is it ?

Detailed Solution for Chemistry Model Test - 2017 - Question 9

For 4d orbital, n = 4 and l = 2
Number of radial nodes = n - l -1 = 4 - 2 - 1 = 1
Number of angular nodes =  l = 2
The number of angular and radial nodes of 4d orbital are 2 and 1 respectively.

Chemistry Model Test - 2017 - Question 10

n- simple molecule of solute A associate in solution as The degree of association is x. what is the number of particles at equilibrium ?

Chemistry Model Test - 2017 - Question 11

The final product of the reaction is:

Chemistry Model Test - 2017 - Question 12

In the given reaction - 

reagent may be:

Chemistry Model Test - 2017 - Question 13

In the given reaction sequence

(B) is _______

Detailed Solution for Chemistry Model Test - 2017 - Question 13

Chloroform when react with hv Phosgene (CCl2O).

and when phosgene react with alcohol dialkyl carbonate is produced.

Chemistry Model Test - 2017 - Question 14

Chemistry Model Test - 2017 - Question 15

In the given reaction

Chemistry Model Test - 2017 - Question 16

In the given reaction

Detailed Solution for Chemistry Model Test - 2017 - Question 16

Correct Answer :- d

Explanation : A mixture of concentrated sulphuric acid and concentrated nitric acid introduces nitro group into benzene ring in an electrophilic aromatic substitution reaction.

When phenol is treated separately with a mixture of concentrated sulphuric acid and concentrated nitric acid, 2,4,6-trinitrophenol ( also known as picric acid) is acid is obtained. Hydroxyl group is activating and ortho, para directing.

When nitrobenzene is treated separately with a mixture of concentrated sulphuric acid and concentrated nitric acid, m-dinitrobenzene is acid is obtained. Nitro group is deactivating and meta directing.

Chemistry Model Test - 2017 - Question 17

When sulphanilic acid is treated with excess of bromine water, it gives _____

Chemistry Model Test - 2017 - Question 18

Which of the following will be more reactive for E1 reaction?

Chemistry Model Test - 2017 - Question 19

The shape of which one of the orbitals corresponds to the angular wave function in the figure given above ?

Chemistry Model Test - 2017 - Question 20

The ground stable energy of hydrogen atom is - 13.6 ev what is the ground state energy of atom?

Detailed Solution for Chemistry Model Test - 2017 - Question 20

 

For n=1 me -13.6ev and n=2 me -3.4ev then excitation energy = final - initial energy then 10.2ev. 

Chemistry Model Test - 2017 - Question 21

Taking into account the isoelectronic Principle and VSEPR Theory, predict in which one of the following pairs, both molecular species have Pyramidal geometry ?

Chemistry Model Test - 2017 - Question 22

XeF3+ belongs to which one of the following AXnEm nomenclature (A = Central, X = singly bonded liquid and E = an unshared electron pair) ?

Chemistry Model Test - 2017 - Question 23

Consider the 0.1N aqueous solutions of the following electrolytes:

1. NaOH
2. NH4OH
3. CH3COOH
4. HCl

The correct sequence of their increasing ph is

Chemistry Model Test - 2017 - Question 24

The molecule N (Sime3)3 has a

Chemistry Model Test - 2017 - Question 25

Haemoglobin a complex containing iron is a constituent of blood. The oxidation state of iron of the complex is ________

Chemistry Model Test - 2017 - Question 26

Match list- I (The metallozymes) with list- II (The metal present in the enzyme) and select the correct answer using the codes given below the lists:



Chemistry Model Test - 2017 - Question 27

The isomerism that are possible in the w(III) complexes [Co(NH3)3 (NO2/3)] and [Co(NH3)3 NO2]Cl2 respectively, are _______

Chemistry Model Test - 2017 - Question 28

For the reaction :

2Cl(g) → Cl (g)

the thermodynamic properties

Chemistry Model Test - 2017 - Question 29

For an enzyme catalysed reaction

Where the symbol have their usual meaning, using the steady state approximation for [ES]. The overall rate equation workout to be

Chemistry Model Test - 2017 - Question 30

The standard oxidation potential of copper and silver electrodes are - 

and 

Respectively, an electrochemical cell containing a copper electrode dipping in a 0.1m CuSO4 solution and a silver electrode dipping in a 0.1m AgNO3 solution is formed using a salt bridge when current is drawn from the cell.

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 31

Which of the following are aromatic ?

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 32

Which of the following compounds has (L) configuration ?

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 33

Which among these can exist tautomerism ?

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 34

Lysione is not used as :

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 35

Which of the following is correct about ΔG ?

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 36

The angular momentum of electron can have the value (s) ___

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 37

The correct starting material and product of different disintegration series are______

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 38

In which of the following set, both the species are isoelectronic and and isostructural?

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 39

Which of the following statement is/are correct

*Multiple options can be correct
Chemistry Model Test - 2017 - Question 40

In which of these compounds does the carbon atom (underlined) nor use Sp3 hybridization for bond formation.

*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 41

How many d- electrons in Cu+ (At. No. = 29) can have the spin quantum number


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 42

One gram of 226Rq has an activity of nearly 1 Ci. The half life of 226Ra is ____ years.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 43

The non- compressive volume of a gas is ____ times than the actual volume of gas molecules.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 44

Calculate the enthalpy of the following reaction :

H2C = CH2(g) + H2(g) → CH3 – CH3(g)

The bond energies of C- H, C- C, C=C and H- H are 99, 83, 147 and 104 kcal respectively.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 45

For a reaction A+B → C+D. If the concentration of A is doubled without altering the concentration of B, the rate gets doubled, if the concentration of B is increased by nine times without altering the concentration of A, the rate gets tripled. The order of reaction is _____


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 46

For the hopothetical reactions, the equilibrium constant (k) values are given below:

The equilibrium constant (k) for the reaction 


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 47

What current strength in ampere will be required to liberate 10g of chlorine from sodium chloride solution in one hour?


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 48

How many stereoisomers exist with the following basic connectivity?

Br CH2 CH (CH3). CH2 CH3


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 49

Use the following data to answer the question below:

The resonance energy of anthracene is _____


Detailed Solution for Chemistry Model Test - 2017 - Question 49

From first reaction we see that for hydrogenation of one double bond we need -28.6 kcal energy.And we know that anthracene contain 7 double bond .So calculated value of hydrogenation of anthracene is (7*-28.6=-200.2).

Resonance energy =Experimental -Calculated

                               =-116.2-(-200.2)

                               =84.

*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 50

Density of lithium atom is 0.53 g/cm3. The edge length of Li is 3.5 A°. Find out the number of lithium atoms is a unit cell. (N0 = 6.022 x1023/mol& M = 6.94)


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 51

What value of n in Huckel's rule applies to the aromatic compound shown above?


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 52

When methyl glucopyranoside reacts with periodic acid, how many moles of the oxidising agent are consumed per mole of sugar ?


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 53

How many isomeric aldehydes are possible with formula C5H10O ?


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 54

The ionic radius of the fluoride ion is ____ using only the following interionic distance and the radius of the iodide ion 2.19A°.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 55

How many nearest, neighbours are there in an atom or ions for an octahedral hole of a closed packed structure ?


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 56

In hydrogen atom, energy of first excited state is - 3.4ev, then the K.E. of same orbital of hydrogen atom is ____ev


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 57

The molecular MLx is planar with 7 pairs of electrons around M in the valence shell, the value of x is ______.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 58

In the electronic structure of H2SO4, the total number of unshared electrons is ____.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 59

The dissociation constant of a substituted benzoic acid at 25°C is 1.0 × 10–4. The pH of a 0.01 M solution of its sodium salt is _______.


*Answer can only contain numeric values
Chemistry Model Test - 2017 - Question 60

An excess of AgNO3 is added to 100 mL of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of AgCl precipitate would be


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