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Organic Chemistry PPT Chemistry Class 12

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Organic Chemistry
Page 2


Organic Chemistry
Introductions 
1. Organic chemicals compounds appear in materials 
like clothing, fuels, polymers dyes and medicines.
2. F. Wohler synthesised an organic compound, urea 
from an inorganic compound, ammonium cyanate.
Page 3


Organic Chemistry
Introductions 
1. Organic chemicals compounds appear in materials 
like clothing, fuels, polymers dyes and medicines.
2. F. Wohler synthesised an organic compound, urea 
from an inorganic compound, ammonium cyanate.
STRUCTURAL  REPRESENTATION OF
ORGANIC COMPOUNDS
Complete, condensed and bond line 
structural formulas
?Organic compounds structures are represented 
in several ways.
1. The Lewis structure or dot structure, dash structure, 
condensed    structure and bond line structural 
formulas are some of the specific types.    
2. The Lewis structures, however, can be simplified
by representing the two-electron covalent
bond by a dash (–).
Page 4


Organic Chemistry
Introductions 
1. Organic chemicals compounds appear in materials 
like clothing, fuels, polymers dyes and medicines.
2. F. Wohler synthesised an organic compound, urea 
from an inorganic compound, ammonium cyanate.
STRUCTURAL  REPRESENTATION OF
ORGANIC COMPOUNDS
Complete, condensed and bond line 
structural formulas
?Organic compounds structures are represented 
in several ways.
1. The Lewis structure or dot structure, dash structure, 
condensed    structure and bond line structural 
formulas are some of the specific types.    
2. The Lewis structures, however, can be simplified
by representing the two-electron covalent
bond by a dash (–).
Thus, ethane (C2H6),  ethene (C2H4),  ethyne (C2H2)
Such structural representations are called 
complete structural formula
H       H                            
H       C        C         H  
H        H
Ethane
H                         H
C           C
H                         H
Ethene
H        C          C H
Ethyne
Page 5


Organic Chemistry
Introductions 
1. Organic chemicals compounds appear in materials 
like clothing, fuels, polymers dyes and medicines.
2. F. Wohler synthesised an organic compound, urea 
from an inorganic compound, ammonium cyanate.
STRUCTURAL  REPRESENTATION OF
ORGANIC COMPOUNDS
Complete, condensed and bond line 
structural formulas
?Organic compounds structures are represented 
in several ways.
1. The Lewis structure or dot structure, dash structure, 
condensed    structure and bond line structural 
formulas are some of the specific types.    
2. The Lewis structures, however, can be simplified
by representing the two-electron covalent
bond by a dash (–).
Thus, ethane (C2H6),  ethene (C2H4),  ethyne (C2H2)
Such structural representations are called 
complete structural formula
H       H                            
H       C        C         H  
H        H
Ethane
H                         H
C           C
H                         H
Ethene
H        C          C H
Ethyne
These structures can also be represented by the following 
ways 
CH3 CH3 H2C       H2C HC       HC
Ethane               Ethene                  Ethyne
organic chemists use another way of representing the 
structures, in which only lines are used. In this bond-line 
structural representation of organic compounds, carbon and 
hydrogen atoms are not shown and the lines representing 
carbon-carbon bonds are drawn in a zig-zag fashion.
For example
i)  CH3CH2CHCH2CH2CH2CH2CH3
|
CH3
3-Methyloctane can be represented in various 
forms as:
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FAQs on PPT: Organic Chemistry – Some Basic Principles and Techniques

1. What's the difference between homolytic and heterolytic cleavage in organic reactions?
Ans. Homolytic cleavage breaks a bond equally, producing two free radicals with unpaired electrons, while heterolytic cleavage breaks it unequally, forming a carbocation and carbanion. Homolytic cleavage requires high energy (heat/light); heterolytic cleavage occurs in polar solvents. Understanding bond fission mechanisms is crucial for predicting organic reaction pathways and NEET exam success in chemical transformations.
2. How do I identify functional groups quickly in complex organic molecules for CBSE Class 12?
Ans. Functional groups are specific atom arrangements determining molecular properties and reactivity. Look for C=C (alkene), C≡C (alkyne), -OH (alcohol), -CHO (aldehyde), C=O (ketone), -COOH (carboxylic acid), and -CN (nitrile). Recognising these characteristic groups immediately helps predict chemical behaviour and reaction types. Flashcards and mind maps on functional group identification streamline exam preparation.
3. What's the difference between nucleophiles and electrophiles, and why does it matter?
Ans. Nucleophiles are electron-rich species (negative or lone-pair donors) attacking electron-deficient sites; electrophiles are electron-deficient species (positive or electron-acceptors). This distinction determines reaction mechanisms-SN1, SN2, elimination pathways-and predicts which molecules will react together. Grasping nucleophilic and electrophilic character is fundamental to understanding organic reaction mechanisms tested extensively in NEET.
4. Why do some carbocations rearrange, and how can I predict when it happens?
Ans. Carbocations rearrange via hydride or methyl shifts to form more stable, lower-energy structures. Primary carbocations rearrange to secondary; secondary to tertiary (increasing alkyl group substitution stabilises positive charge). Rearrangement occurs when stability increases substantially. Recognising hyperconjugation and inductive effects helps predict rearrangement likelihood-critical for solving reaction mechanism questions in competitive exams.
5. How do I know whether a reaction will follow SN1 or SN2 mechanism in organic chemistry?
Ans. SN1 dominates with tertiary alkyl halides, weak nucleophiles, and polar aprotic solvents; SN2 favours primary alkyl halides, strong nucleophiles, and polar protic solvents. Temperature, substrate structure, and leaving group ability influence mechanism selection. Mastering these factors determines reaction outcomes and stereochemistry predictions-essential for CBSE board exams and competitive entrance tests covering bimolecular and unimolecular substitution pathways.
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