Page 1
30
1. What are the types of molecules of elements and compounds?
2. What is meant by valency of elements?
3. Chemical Reactions and Equations
Ø Chemical reactions Ø Rules of writing chemical reaction
Ø Balancing a chemical equation Ø Types of chemical reactions
3. What is the requirement for writing molecular formulae of different compounds? How
are the molecular formulae of the compounds written?
In earlier standards we have seen how compounds are formed by chemical
combination of elements. We have also learnt that the driving force behind formation of a
chemical bond is to attain an electronic configuration with a complete octet. The atoms
attain a complete octet by giving, taking or sharing of electrons with each other.
Chemical Reaction
Some of the scientists of the 18
th
and 19
th
century carried out fundamental experiments
on chemical reactions. They proved from their experiments that during chemical reactions
composition of the matter changes and that change remains permanent. On the contrary
during physical change only the state of matter changes and this change is often temporary
in nature.
Identify physical and chemical changes from the phenomena given in the following table.
3.1 Some common phenomenon
Note : Do the following activities in a group of friends. Take help of your teacher
wherever necessary.
Apparatus: Thermometer, evaporating dish, tripod stand,
funnel, Bunsen burner, etc.
Phenomenon Physical
change
Chemical
change
1. Transformation of ice into water.
2. Cooking of food.
3. Ripening of fruit.
4. Milk turned in to curd.
5. Evaporation of water.
6. Digestion of food in the stomach.
7. Size reduction of naphtha balls exposed to air.
8. Staining of Shahbad or Kadappa tile by lemon juice.
9. Breaking of a glass object on falling from a height.
Chemicals : Lime stone powder, copper sulphate, calcium chloride, potassium chromate,
zinc dust, sodium carbonate, phthalic anhydride, etc.
Procedure : Carry out the activities 1 to 5 as given below. Read and record the temperatures
in the activities 2 to 4.
Can you recall?
Try this.
Page 2
30
1. What are the types of molecules of elements and compounds?
2. What is meant by valency of elements?
3. Chemical Reactions and Equations
Ø Chemical reactions Ø Rules of writing chemical reaction
Ø Balancing a chemical equation Ø Types of chemical reactions
3. What is the requirement for writing molecular formulae of different compounds? How
are the molecular formulae of the compounds written?
In earlier standards we have seen how compounds are formed by chemical
combination of elements. We have also learnt that the driving force behind formation of a
chemical bond is to attain an electronic configuration with a complete octet. The atoms
attain a complete octet by giving, taking or sharing of electrons with each other.
Chemical Reaction
Some of the scientists of the 18
th
and 19
th
century carried out fundamental experiments
on chemical reactions. They proved from their experiments that during chemical reactions
composition of the matter changes and that change remains permanent. On the contrary
during physical change only the state of matter changes and this change is often temporary
in nature.
Identify physical and chemical changes from the phenomena given in the following table.
3.1 Some common phenomenon
Note : Do the following activities in a group of friends. Take help of your teacher
wherever necessary.
Apparatus: Thermometer, evaporating dish, tripod stand,
funnel, Bunsen burner, etc.
Phenomenon Physical
change
Chemical
change
1. Transformation of ice into water.
2. Cooking of food.
3. Ripening of fruit.
4. Milk turned in to curd.
5. Evaporation of water.
6. Digestion of food in the stomach.
7. Size reduction of naphtha balls exposed to air.
8. Staining of Shahbad or Kadappa tile by lemon juice.
9. Breaking of a glass object on falling from a height.
Chemicals : Lime stone powder, copper sulphate, calcium chloride, potassium chromate,
zinc dust, sodium carbonate, phthalic anhydride, etc.
Procedure : Carry out the activities 1 to 5 as given below. Read and record the temperatures
in the activities 2 to 4.
Can you recall?
Try this.
31
A physical change takes place due to change in the parameters such as temperature,
pressure. Often a physical change in reversible. The composition of matter remains the
same in a physical change. For example, ice is transformed into water on heating and
water is transformed into ice on cooling. On the contrary, if the composition of matter
changes during a process then it is called a chemical change. When we call a particular
process or phenomenon as a chemical change, some chemical reactions are taking place
in the concerned matter.
A chemical reaction is a process in which some substances undergo bond breaking
and are transformed into new substances by formation of new bonds. The substances
taking part in chemical reaction are called reactants, whereas the substances formed as a
result of a chemical reaction by formation of new bonds are called products. For example,
formation of carbon dioxide gas by combustion of coal in air is a chemical reaction. In
this reaction coal (carbon) and oxygen (from air) are the reactants while carbon dioxide
is the product. A chemical reaction is represented by writing a chemical equation.
Activity Colour
change
(if present)
Gas released
(yes/no)
Temperature
change
(if present)
Nature of change
(chemical /physical)
1
2
3
4
5
Find out
Observe and keep a record of the physical and chemical changes
that you experience in your daily life.
3.3 Observation table
1. Take a spoonful of lime stone powder in an
evaporating dish. Heat it strongly on a high blue
flame.
2. Add zinc (Zn) dust into the copper sulphate
(CuSO
4
) solution.
3. Add potassium chromate (K
2
CrO
4
) solution to
barium sulphate (BaSO
4
) solution.
4. Add sodium carbonate (Na
2
CO
3
) solution to the
calcium chloride (CaCl
2
) solution.
5. Take phthalic anhydride in the evaporating dish.
Close the end of the stem of a funnel with a
cotton plug. Keep this funnel inverted on the
evaporating dish. Heat the evaporating dish on
a tripod stand slowly on a low flame. What did
you observe in the funnel during heating?
Record the observation of all the activities. What did you find?
Complete the following observation table with reference to the activities 1 to 5.
3.2 To heat lime stone powder
Lime stone
powder
Bunsen
burner
Page 3
30
1. What are the types of molecules of elements and compounds?
2. What is meant by valency of elements?
3. Chemical Reactions and Equations
Ø Chemical reactions Ø Rules of writing chemical reaction
Ø Balancing a chemical equation Ø Types of chemical reactions
3. What is the requirement for writing molecular formulae of different compounds? How
are the molecular formulae of the compounds written?
In earlier standards we have seen how compounds are formed by chemical
combination of elements. We have also learnt that the driving force behind formation of a
chemical bond is to attain an electronic configuration with a complete octet. The atoms
attain a complete octet by giving, taking or sharing of electrons with each other.
Chemical Reaction
Some of the scientists of the 18
th
and 19
th
century carried out fundamental experiments
on chemical reactions. They proved from their experiments that during chemical reactions
composition of the matter changes and that change remains permanent. On the contrary
during physical change only the state of matter changes and this change is often temporary
in nature.
Identify physical and chemical changes from the phenomena given in the following table.
3.1 Some common phenomenon
Note : Do the following activities in a group of friends. Take help of your teacher
wherever necessary.
Apparatus: Thermometer, evaporating dish, tripod stand,
funnel, Bunsen burner, etc.
Phenomenon Physical
change
Chemical
change
1. Transformation of ice into water.
2. Cooking of food.
3. Ripening of fruit.
4. Milk turned in to curd.
5. Evaporation of water.
6. Digestion of food in the stomach.
7. Size reduction of naphtha balls exposed to air.
8. Staining of Shahbad or Kadappa tile by lemon juice.
9. Breaking of a glass object on falling from a height.
Chemicals : Lime stone powder, copper sulphate, calcium chloride, potassium chromate,
zinc dust, sodium carbonate, phthalic anhydride, etc.
Procedure : Carry out the activities 1 to 5 as given below. Read and record the temperatures
in the activities 2 to 4.
Can you recall?
Try this.
31
A physical change takes place due to change in the parameters such as temperature,
pressure. Often a physical change in reversible. The composition of matter remains the
same in a physical change. For example, ice is transformed into water on heating and
water is transformed into ice on cooling. On the contrary, if the composition of matter
changes during a process then it is called a chemical change. When we call a particular
process or phenomenon as a chemical change, some chemical reactions are taking place
in the concerned matter.
A chemical reaction is a process in which some substances undergo bond breaking
and are transformed into new substances by formation of new bonds. The substances
taking part in chemical reaction are called reactants, whereas the substances formed as a
result of a chemical reaction by formation of new bonds are called products. For example,
formation of carbon dioxide gas by combustion of coal in air is a chemical reaction. In
this reaction coal (carbon) and oxygen (from air) are the reactants while carbon dioxide
is the product. A chemical reaction is represented by writing a chemical equation.
Activity Colour
change
(if present)
Gas released
(yes/no)
Temperature
change
(if present)
Nature of change
(chemical /physical)
1
2
3
4
5
Find out
Observe and keep a record of the physical and chemical changes
that you experience in your daily life.
3.3 Observation table
1. Take a spoonful of lime stone powder in an
evaporating dish. Heat it strongly on a high blue
flame.
2. Add zinc (Zn) dust into the copper sulphate
(CuSO
4
) solution.
3. Add potassium chromate (K
2
CrO
4
) solution to
barium sulphate (BaSO
4
) solution.
4. Add sodium carbonate (Na
2
CO
3
) solution to the
calcium chloride (CaCl
2
) solution.
5. Take phthalic anhydride in the evaporating dish.
Close the end of the stem of a funnel with a
cotton plug. Keep this funnel inverted on the
evaporating dish. Heat the evaporating dish on
a tripod stand slowly on a low flame. What did
you observe in the funnel during heating?
Record the observation of all the activities. What did you find?
Complete the following observation table with reference to the activities 1 to 5.
3.2 To heat lime stone powder
Lime stone
powder
Bunsen
burner
32
Chemical equations
Let us first look at a chemical reaction. In the activity 2, a colourless solution of zinc
sulphate (ZnSO
4
) is formed on addition of zinc dust to the blue solution of copper sulphate
(CuSO
4
). This chemical reaction can be written in brief as follows.
Aqueous solution of copper sulphate + zinc dust Aqueous solution of zinc
sulphate + copper .......... (1)
This simple way of representing a chemical reaction in words is called a ‘Word Equation’.
A word equation can be written in a further condensed form by using chemical formulae
as follows.
CuSO
4
+ Zn ZnSO
4
+ Cu.................(2)
The representation of a chemical reaction in a condensed form using chemical formulae
is called as the chemical equation. In the above equation copper sulphate (CuSO
4
) and zinc
(Zn) are the reactants. They react with each other to form copper particles (Cu) and a
solution of the colourless zinc sulphate (ZnSO
4
) as the products having totally different
properties. The ionic bond in the reactant CuSO
4
breaks and the ionic bond in the product
ZnSO
4
is formed during the reaction.
Writing a Chemical Equation
Let us now see the conventions followed while writing a chemical equation.
1. In a chemical equation the reactants are written on the left hand side while the
products on the right hand side. An arrow heading towards the products is drawn in between
them. This arrow indicates the direction of the reaction.
2. If the reactants or products are two or more, they are linked with a plus sign (+) in
between them. For example, in the equation (2) a plus sign (+) is drawn in between the
reactants CuSO
4
and Zn. Similarly, a plus sign (+) is drawn in between the products ZnSO
4
and Cu.
3. To make the chemical equation more informative the physical states of the reactants
are indicated in the equation. Their gaseous, liquid and solid states are indicated by writing
the letters (g), (l) and (s), respectively in the brackets. Moreover, if the product is gaseous,
instead of (g) it can be indicated by an arrow pointing upwards. If the product formed is
insoluble solid, in the form of a precipitate, then instead of (s) it can be indicated by an
arrow pointing downwards. When reactants and products are in the form of solution in
water, they are said to be present in aqueous solution state. This state is indicated by putting
the letters aq in brackets after their formula. Thus, the equation (2) is rewritten as equation
(3) shown below.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) ..................... (3)
4. When heat is to be given from outside to bring about a reaction, it is indicated by the
sign rwritten above the arrow that indicates the direction of the reaction. For example, the
reaction in which slaked lime is formed on heating lime stone is written as follows.
CaCO
3
(s)
D
CaO (s) + CO
2
........................ (4)
Similarly, the fact that heat is released during the reaction between the aqueous solution
of copper sulphate and zinc dust is indicated as follows.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) + Heat ..................... (5)
5. It is necessary to fulfill certain conditions like specific temperature, pressure, catalyst,
etc. to bring about some reactions. These conditions are indicated below or above the arrow
indicating the direction of the reaction. For example, the reaction of a vegetable oil takes
place at the temperature of 60
0
C with hydrogen gas in presence of the Ni catalyst and is
written as follows.
Page 4
30
1. What are the types of molecules of elements and compounds?
2. What is meant by valency of elements?
3. Chemical Reactions and Equations
Ø Chemical reactions Ø Rules of writing chemical reaction
Ø Balancing a chemical equation Ø Types of chemical reactions
3. What is the requirement for writing molecular formulae of different compounds? How
are the molecular formulae of the compounds written?
In earlier standards we have seen how compounds are formed by chemical
combination of elements. We have also learnt that the driving force behind formation of a
chemical bond is to attain an electronic configuration with a complete octet. The atoms
attain a complete octet by giving, taking or sharing of electrons with each other.
Chemical Reaction
Some of the scientists of the 18
th
and 19
th
century carried out fundamental experiments
on chemical reactions. They proved from their experiments that during chemical reactions
composition of the matter changes and that change remains permanent. On the contrary
during physical change only the state of matter changes and this change is often temporary
in nature.
Identify physical and chemical changes from the phenomena given in the following table.
3.1 Some common phenomenon
Note : Do the following activities in a group of friends. Take help of your teacher
wherever necessary.
Apparatus: Thermometer, evaporating dish, tripod stand,
funnel, Bunsen burner, etc.
Phenomenon Physical
change
Chemical
change
1. Transformation of ice into water.
2. Cooking of food.
3. Ripening of fruit.
4. Milk turned in to curd.
5. Evaporation of water.
6. Digestion of food in the stomach.
7. Size reduction of naphtha balls exposed to air.
8. Staining of Shahbad or Kadappa tile by lemon juice.
9. Breaking of a glass object on falling from a height.
Chemicals : Lime stone powder, copper sulphate, calcium chloride, potassium chromate,
zinc dust, sodium carbonate, phthalic anhydride, etc.
Procedure : Carry out the activities 1 to 5 as given below. Read and record the temperatures
in the activities 2 to 4.
Can you recall?
Try this.
31
A physical change takes place due to change in the parameters such as temperature,
pressure. Often a physical change in reversible. The composition of matter remains the
same in a physical change. For example, ice is transformed into water on heating and
water is transformed into ice on cooling. On the contrary, if the composition of matter
changes during a process then it is called a chemical change. When we call a particular
process or phenomenon as a chemical change, some chemical reactions are taking place
in the concerned matter.
A chemical reaction is a process in which some substances undergo bond breaking
and are transformed into new substances by formation of new bonds. The substances
taking part in chemical reaction are called reactants, whereas the substances formed as a
result of a chemical reaction by formation of new bonds are called products. For example,
formation of carbon dioxide gas by combustion of coal in air is a chemical reaction. In
this reaction coal (carbon) and oxygen (from air) are the reactants while carbon dioxide
is the product. A chemical reaction is represented by writing a chemical equation.
Activity Colour
change
(if present)
Gas released
(yes/no)
Temperature
change
(if present)
Nature of change
(chemical /physical)
1
2
3
4
5
Find out
Observe and keep a record of the physical and chemical changes
that you experience in your daily life.
3.3 Observation table
1. Take a spoonful of lime stone powder in an
evaporating dish. Heat it strongly on a high blue
flame.
2. Add zinc (Zn) dust into the copper sulphate
(CuSO
4
) solution.
3. Add potassium chromate (K
2
CrO
4
) solution to
barium sulphate (BaSO
4
) solution.
4. Add sodium carbonate (Na
2
CO
3
) solution to the
calcium chloride (CaCl
2
) solution.
5. Take phthalic anhydride in the evaporating dish.
Close the end of the stem of a funnel with a
cotton plug. Keep this funnel inverted on the
evaporating dish. Heat the evaporating dish on
a tripod stand slowly on a low flame. What did
you observe in the funnel during heating?
Record the observation of all the activities. What did you find?
Complete the following observation table with reference to the activities 1 to 5.
3.2 To heat lime stone powder
Lime stone
powder
Bunsen
burner
32
Chemical equations
Let us first look at a chemical reaction. In the activity 2, a colourless solution of zinc
sulphate (ZnSO
4
) is formed on addition of zinc dust to the blue solution of copper sulphate
(CuSO
4
). This chemical reaction can be written in brief as follows.
Aqueous solution of copper sulphate + zinc dust Aqueous solution of zinc
sulphate + copper .......... (1)
This simple way of representing a chemical reaction in words is called a ‘Word Equation’.
A word equation can be written in a further condensed form by using chemical formulae
as follows.
CuSO
4
+ Zn ZnSO
4
+ Cu.................(2)
The representation of a chemical reaction in a condensed form using chemical formulae
is called as the chemical equation. In the above equation copper sulphate (CuSO
4
) and zinc
(Zn) are the reactants. They react with each other to form copper particles (Cu) and a
solution of the colourless zinc sulphate (ZnSO
4
) as the products having totally different
properties. The ionic bond in the reactant CuSO
4
breaks and the ionic bond in the product
ZnSO
4
is formed during the reaction.
Writing a Chemical Equation
Let us now see the conventions followed while writing a chemical equation.
1. In a chemical equation the reactants are written on the left hand side while the
products on the right hand side. An arrow heading towards the products is drawn in between
them. This arrow indicates the direction of the reaction.
2. If the reactants or products are two or more, they are linked with a plus sign (+) in
between them. For example, in the equation (2) a plus sign (+) is drawn in between the
reactants CuSO
4
and Zn. Similarly, a plus sign (+) is drawn in between the products ZnSO
4
and Cu.
3. To make the chemical equation more informative the physical states of the reactants
are indicated in the equation. Their gaseous, liquid and solid states are indicated by writing
the letters (g), (l) and (s), respectively in the brackets. Moreover, if the product is gaseous,
instead of (g) it can be indicated by an arrow pointing upwards. If the product formed is
insoluble solid, in the form of a precipitate, then instead of (s) it can be indicated by an
arrow pointing downwards. When reactants and products are in the form of solution in
water, they are said to be present in aqueous solution state. This state is indicated by putting
the letters aq in brackets after their formula. Thus, the equation (2) is rewritten as equation
(3) shown below.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) ..................... (3)
4. When heat is to be given from outside to bring about a reaction, it is indicated by the
sign rwritten above the arrow that indicates the direction of the reaction. For example, the
reaction in which slaked lime is formed on heating lime stone is written as follows.
CaCO
3
(s)
D
CaO (s) + CO
2
........................ (4)
Similarly, the fact that heat is released during the reaction between the aqueous solution
of copper sulphate and zinc dust is indicated as follows.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) + Heat ..................... (5)
5. It is necessary to fulfill certain conditions like specific temperature, pressure, catalyst,
etc. to bring about some reactions. These conditions are indicated below or above the arrow
indicating the direction of the reaction. For example, the reaction of a vegetable oil takes
place at the temperature of 60
0
C with hydrogen gas in presence of the Ni catalyst and is
written as follows.
33
Apparatus: Test tube, conical flask, balance, etc.
Chemicals : Sodium chloride and silver nitrate.
Silver nitrate is used in the voters-ink.
Procedure :
1. Take sodium chloride solution in a conical flask and silver nitrate solution in a test tube.
2. Tie a thread to the test tube and insert it carefully into the conical flask. Make the
conical flask air tight by fitting a rubber cork.
3. Weigh the conical flask with the help of a balance.
4. Now tilt the conical flask and mix the solution present in the test tube with the solution
in the conical flask.
5. Weigh the conical flask again.
Which changes did you find? Did any insoluble substance form? Was there any
change in the weight?
A word equation is written for the above activity as shown below.
Silver nitrate + Sodium chloride Silver chloride + Sodium nitrate
The above word equation is represented by the following chemical equation.
(Concentrated)
However, on reaction with dilute nitric acid, the product formed is nitric oxide gas.
3Cu(s) + 8HNO
3
(aq) 3Cu(NO
3
)
2
(aq) + 2NO(g) + 4H
2
O(l) ...........(8)
(dilute)
6 . Special information or names of reactants/ products are written below their
formulae. For example, copper on reaction with concentrated nitric acid gives reddish
coloured poisonous nitrogen di oxide gas.
Cu(s) + 4 HNO
3
(aq) Cu(NO
3
)
2
(aq) + 2NO
2
(g) + 2H
2
O(l) ...........(7)
What are the other uses of silver nitrate in everyday life? Find out
Vegetable oil (l) + H
2
(g) Vanaspathi ghee (s)............. (6)
Try this.
Sodium chloride
solution
Silver nitrate solution
Conical flask
Test tube
Balance
3.4 The reaction of sodium chloride with silver nitrate
Do you know ?
60
0
C
Ni Catalyst
AgNO
3
(aq)+ NaCl(aq) AgCl + NaNO
3
(aq) ........ (9)
(white)
Page 5
30
1. What are the types of molecules of elements and compounds?
2. What is meant by valency of elements?
3. Chemical Reactions and Equations
Ø Chemical reactions Ø Rules of writing chemical reaction
Ø Balancing a chemical equation Ø Types of chemical reactions
3. What is the requirement for writing molecular formulae of different compounds? How
are the molecular formulae of the compounds written?
In earlier standards we have seen how compounds are formed by chemical
combination of elements. We have also learnt that the driving force behind formation of a
chemical bond is to attain an electronic configuration with a complete octet. The atoms
attain a complete octet by giving, taking or sharing of electrons with each other.
Chemical Reaction
Some of the scientists of the 18
th
and 19
th
century carried out fundamental experiments
on chemical reactions. They proved from their experiments that during chemical reactions
composition of the matter changes and that change remains permanent. On the contrary
during physical change only the state of matter changes and this change is often temporary
in nature.
Identify physical and chemical changes from the phenomena given in the following table.
3.1 Some common phenomenon
Note : Do the following activities in a group of friends. Take help of your teacher
wherever necessary.
Apparatus: Thermometer, evaporating dish, tripod stand,
funnel, Bunsen burner, etc.
Phenomenon Physical
change
Chemical
change
1. Transformation of ice into water.
2. Cooking of food.
3. Ripening of fruit.
4. Milk turned in to curd.
5. Evaporation of water.
6. Digestion of food in the stomach.
7. Size reduction of naphtha balls exposed to air.
8. Staining of Shahbad or Kadappa tile by lemon juice.
9. Breaking of a glass object on falling from a height.
Chemicals : Lime stone powder, copper sulphate, calcium chloride, potassium chromate,
zinc dust, sodium carbonate, phthalic anhydride, etc.
Procedure : Carry out the activities 1 to 5 as given below. Read and record the temperatures
in the activities 2 to 4.
Can you recall?
Try this.
31
A physical change takes place due to change in the parameters such as temperature,
pressure. Often a physical change in reversible. The composition of matter remains the
same in a physical change. For example, ice is transformed into water on heating and
water is transformed into ice on cooling. On the contrary, if the composition of matter
changes during a process then it is called a chemical change. When we call a particular
process or phenomenon as a chemical change, some chemical reactions are taking place
in the concerned matter.
A chemical reaction is a process in which some substances undergo bond breaking
and are transformed into new substances by formation of new bonds. The substances
taking part in chemical reaction are called reactants, whereas the substances formed as a
result of a chemical reaction by formation of new bonds are called products. For example,
formation of carbon dioxide gas by combustion of coal in air is a chemical reaction. In
this reaction coal (carbon) and oxygen (from air) are the reactants while carbon dioxide
is the product. A chemical reaction is represented by writing a chemical equation.
Activity Colour
change
(if present)
Gas released
(yes/no)
Temperature
change
(if present)
Nature of change
(chemical /physical)
1
2
3
4
5
Find out
Observe and keep a record of the physical and chemical changes
that you experience in your daily life.
3.3 Observation table
1. Take a spoonful of lime stone powder in an
evaporating dish. Heat it strongly on a high blue
flame.
2. Add zinc (Zn) dust into the copper sulphate
(CuSO
4
) solution.
3. Add potassium chromate (K
2
CrO
4
) solution to
barium sulphate (BaSO
4
) solution.
4. Add sodium carbonate (Na
2
CO
3
) solution to the
calcium chloride (CaCl
2
) solution.
5. Take phthalic anhydride in the evaporating dish.
Close the end of the stem of a funnel with a
cotton plug. Keep this funnel inverted on the
evaporating dish. Heat the evaporating dish on
a tripod stand slowly on a low flame. What did
you observe in the funnel during heating?
Record the observation of all the activities. What did you find?
Complete the following observation table with reference to the activities 1 to 5.
3.2 To heat lime stone powder
Lime stone
powder
Bunsen
burner
32
Chemical equations
Let us first look at a chemical reaction. In the activity 2, a colourless solution of zinc
sulphate (ZnSO
4
) is formed on addition of zinc dust to the blue solution of copper sulphate
(CuSO
4
). This chemical reaction can be written in brief as follows.
Aqueous solution of copper sulphate + zinc dust Aqueous solution of zinc
sulphate + copper .......... (1)
This simple way of representing a chemical reaction in words is called a ‘Word Equation’.
A word equation can be written in a further condensed form by using chemical formulae
as follows.
CuSO
4
+ Zn ZnSO
4
+ Cu.................(2)
The representation of a chemical reaction in a condensed form using chemical formulae
is called as the chemical equation. In the above equation copper sulphate (CuSO
4
) and zinc
(Zn) are the reactants. They react with each other to form copper particles (Cu) and a
solution of the colourless zinc sulphate (ZnSO
4
) as the products having totally different
properties. The ionic bond in the reactant CuSO
4
breaks and the ionic bond in the product
ZnSO
4
is formed during the reaction.
Writing a Chemical Equation
Let us now see the conventions followed while writing a chemical equation.
1. In a chemical equation the reactants are written on the left hand side while the
products on the right hand side. An arrow heading towards the products is drawn in between
them. This arrow indicates the direction of the reaction.
2. If the reactants or products are two or more, they are linked with a plus sign (+) in
between them. For example, in the equation (2) a plus sign (+) is drawn in between the
reactants CuSO
4
and Zn. Similarly, a plus sign (+) is drawn in between the products ZnSO
4
and Cu.
3. To make the chemical equation more informative the physical states of the reactants
are indicated in the equation. Their gaseous, liquid and solid states are indicated by writing
the letters (g), (l) and (s), respectively in the brackets. Moreover, if the product is gaseous,
instead of (g) it can be indicated by an arrow pointing upwards. If the product formed is
insoluble solid, in the form of a precipitate, then instead of (s) it can be indicated by an
arrow pointing downwards. When reactants and products are in the form of solution in
water, they are said to be present in aqueous solution state. This state is indicated by putting
the letters aq in brackets after their formula. Thus, the equation (2) is rewritten as equation
(3) shown below.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) ..................... (3)
4. When heat is to be given from outside to bring about a reaction, it is indicated by the
sign rwritten above the arrow that indicates the direction of the reaction. For example, the
reaction in which slaked lime is formed on heating lime stone is written as follows.
CaCO
3
(s)
D
CaO (s) + CO
2
........................ (4)
Similarly, the fact that heat is released during the reaction between the aqueous solution
of copper sulphate and zinc dust is indicated as follows.
CuSO
4
(aq) + Zn (s) ZnSO
4
(aq) + Cu (s) + Heat ..................... (5)
5. It is necessary to fulfill certain conditions like specific temperature, pressure, catalyst,
etc. to bring about some reactions. These conditions are indicated below or above the arrow
indicating the direction of the reaction. For example, the reaction of a vegetable oil takes
place at the temperature of 60
0
C with hydrogen gas in presence of the Ni catalyst and is
written as follows.
33
Apparatus: Test tube, conical flask, balance, etc.
Chemicals : Sodium chloride and silver nitrate.
Silver nitrate is used in the voters-ink.
Procedure :
1. Take sodium chloride solution in a conical flask and silver nitrate solution in a test tube.
2. Tie a thread to the test tube and insert it carefully into the conical flask. Make the
conical flask air tight by fitting a rubber cork.
3. Weigh the conical flask with the help of a balance.
4. Now tilt the conical flask and mix the solution present in the test tube with the solution
in the conical flask.
5. Weigh the conical flask again.
Which changes did you find? Did any insoluble substance form? Was there any
change in the weight?
A word equation is written for the above activity as shown below.
Silver nitrate + Sodium chloride Silver chloride + Sodium nitrate
The above word equation is represented by the following chemical equation.
(Concentrated)
However, on reaction with dilute nitric acid, the product formed is nitric oxide gas.
3Cu(s) + 8HNO
3
(aq) 3Cu(NO
3
)
2
(aq) + 2NO(g) + 4H
2
O(l) ...........(8)
(dilute)
6 . Special information or names of reactants/ products are written below their
formulae. For example, copper on reaction with concentrated nitric acid gives reddish
coloured poisonous nitrogen di oxide gas.
Cu(s) + 4 HNO
3
(aq) Cu(NO
3
)
2
(aq) + 2NO
2
(g) + 2H
2
O(l) ...........(7)
What are the other uses of silver nitrate in everyday life? Find out
Vegetable oil (l) + H
2
(g) Vanaspathi ghee (s)............. (6)
Try this.
Sodium chloride
solution
Silver nitrate solution
Conical flask
Test tube
Balance
3.4 The reaction of sodium chloride with silver nitrate
Do you know ?
60
0
C
Ni Catalyst
AgNO
3
(aq)+ NaCl(aq) AgCl + NaNO
3
(aq) ........ (9)
(white)
34
Balancing a Chemical Equation
Complete the table aside on the
basis of the equation (9).
It is seen that the number of atoms
of the elements in the reactants in this
equation is same as the number of
atoms of those elements in the products.
Such an equation is called a ‘balanced
equation’. If the number of atoms of
each element is not the same on the two
sides of an equation, it is called an
‘unbalanced equation’.
Reactants
(Left side)
Products
(Right side)
Element Number of
atoms
Number of
atoms
Ag
N
O
Na
Cl
3.5 Details of equation (9)
In any reaction, the total mass of each of the elements in the
reactants is same as the total mass of each of the respective
elements in the products. This is in accordance with the law of
conservation of mass that you studied in the previous standard.
Steps in balancing a chemical reaction
A chemical equation is balanced step by step. A trial and error method is used for this
purpose. Consider the following equation as an example :
Sodium hydroxide + Sulphuric acid Sodium sulphate + water.
STEP I. Write the chemical equation from the given word equation.
NaOH + H
2
SO
4
Na
2
SO
4
+ H
2
O ..............(10)
STEP III : It is convenient to start balancing an equation from the compound which
contains the maximum number of atoms. Moreover it is convenient to first consider that
element in this compound, which has unequal number of atoms on the two sides.
Reactants
(Left side)
Products
(Right side)
Element Number of atoms Number of atoms
Na 1 2
O 5 5
H 3 2
S 1 1
Number of
sodium
atoms
In the
Reactants
(in NaOH)
In the
Products
(in Na
2
SO
4
)
Initially 1 2
To balance 1 x 2 2
Always remember
STEP II. Check whether the
equation (10) is balanced or not by
comparing the number of atoms of
the various elements present on the
two sides of the equation.
It is seen that the number of
atoms of all the elements on the two
sides are not the same. It means that
the equation (10) is not balanced.
(i) In the equation (10), there are two
components Na
2
SO
4
and H
2
SO
4
, which contain
the maximum number that is seven atoms each.
Any one of them can be selected. Select the
compound Na
2
SO
4
. Further select sodium for
balancing as the number of atoms of sodium
in this compound is unequal on the two sides. It
should be remembered that, the formula of a compound cannot be changed while balancing
the number of atoms. It means that, here to make the number of sodium atoms in the
reactants as ‘2’ the formula NaOH cannot be changed to Na
2
OH. Instead a factor of ‘2’
will have to be applied to NaOH. Write down the resulting equation (10)
/
on doing this.
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