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Page 1 Disclaimer: The information on this page has not been checked by an independent person. Use this information at your own risk. ROYMECH Home Thermos Index Thermodynamics Cycles Introduction Various internal combustion engine types have been devised and represented by various idealised cycles (otto cycle for four stroke, diesel cycle etc.. These idealised cycles are useful for determining the practical limitations and efficiencies possible. They do not however provide the answer to the question.. "What is the greatest fraction of the heat transfer from a energy source is it possible to convert into work ? i.e. what is the limiting efficiency of conversion ?" Carnot introduced a theoretical gas cycle based on ideal reversible process which provides this information Carnot Cycle Carnot in 1824 arrived at the "carnot cycle" which is an idealised gas cycle that obtains the maximum amount of work from an engine working in a thermodynamically reversible manner. This cycle provides a maximum efficiency for any thermodynamic heat engine The Carnot cycle for perfect gases is an idealised cycle composed of four reversible processes 1. an isothermal expansion of fixed mass of gas (say in a cylinder- causing a piston to move out) 2. an adiabetic expansion the gas (say in a cylinder- causing a piston to move out) 3. an isothermal contraction of the gas (say in a cylinder- causing a piston to move in) 4. an adiabetic contraction of the gas (say in a cylinder- causing a piston to move in) This imaginary working fluid is contained in the (cylinder)closed system and simply receives and rejects energy to a source and sink using perfect heat transfer (with no temperature difference ). As a result of receiving and rejecting energy it expands and contracts during four ideal reversible "no-flow" processes. The fluid is an ideal gas following the ideal gas laws. Page 2 Disclaimer: The information on this page has not been checked by an independent person. Use this information at your own risk. ROYMECH Home Thermos Index Thermodynamics Cycles Introduction Various internal combustion engine types have been devised and represented by various idealised cycles (otto cycle for four stroke, diesel cycle etc.. These idealised cycles are useful for determining the practical limitations and efficiencies possible. They do not however provide the answer to the question.. "What is the greatest fraction of the heat transfer from a energy source is it possible to convert into work ? i.e. what is the limiting efficiency of conversion ?" Carnot introduced a theoretical gas cycle based on ideal reversible process which provides this information Carnot Cycle Carnot in 1824 arrived at the "carnot cycle" which is an idealised gas cycle that obtains the maximum amount of work from an engine working in a thermodynamically reversible manner. This cycle provides a maximum efficiency for any thermodynamic heat engine The Carnot cycle for perfect gases is an idealised cycle composed of four reversible processes 1. an isothermal expansion of fixed mass of gas (say in a cylinder- causing a piston to move out) 2. an adiabetic expansion the gas (say in a cylinder- causing a piston to move out) 3. an isothermal contraction of the gas (say in a cylinder- causing a piston to move in) 4. an adiabetic contraction of the gas (say in a cylinder- causing a piston to move in) This imaginary working fluid is contained in the (cylinder)closed system and simply receives and rejects energy to a source and sink using perfect heat transfer (with no temperature difference ). As a result of receiving and rejecting energy it expands and contracts during four ideal reversible "no-flow" processes. The fluid is an ideal gas following the ideal gas laws. The work done through during a complete cycle is determined using the relationships identified on webpage Polytropic processes.... From the general relationship for adiabatic polytropic processes the following relationship is identified. Relationships Reversible Process Heat Transfer at T1 to Working Fluid From Hot Source Heat Rejected at T2 from Working Fluid From Sink Work done by working fluid Change in Internal Energy of Fluid Isothermal Expansion RmT 1log er 0 RmT 1log er 0 Adiabatic Expansion 0 0 Rm(T 1 - T 2 )/ (1- ? ) -Rm(T 1 - T 2 )/ (1- ? ) Isothermal Compression 0 RmT 2log er -RmT 2log er 0 Adiabatic Compression 0 0 -Rm(T 1 - T 2 )/ (1- ? ) Rm(T 1 - T 2 )/ (1- ? ) Totals RmT 1log er = Q 1 RmT 2log er = Q 2 Rm(T 1- T 2 )log er= W 0 From the table it can clearly be seen that the total work done by the carnot cycle is Rm(T1 - T1 )loge r = Q1 - Q2. Page 3 Disclaimer: The information on this page has not been checked by an independent person. Use this information at your own risk. ROYMECH Home Thermos Index Thermodynamics Cycles Introduction Various internal combustion engine types have been devised and represented by various idealised cycles (otto cycle for four stroke, diesel cycle etc.. These idealised cycles are useful for determining the practical limitations and efficiencies possible. They do not however provide the answer to the question.. "What is the greatest fraction of the heat transfer from a energy source is it possible to convert into work ? i.e. what is the limiting efficiency of conversion ?" Carnot introduced a theoretical gas cycle based on ideal reversible process which provides this information Carnot Cycle Carnot in 1824 arrived at the "carnot cycle" which is an idealised gas cycle that obtains the maximum amount of work from an engine working in a thermodynamically reversible manner. This cycle provides a maximum efficiency for any thermodynamic heat engine The Carnot cycle for perfect gases is an idealised cycle composed of four reversible processes 1. an isothermal expansion of fixed mass of gas (say in a cylinder- causing a piston to move out) 2. an adiabetic expansion the gas (say in a cylinder- causing a piston to move out) 3. an isothermal contraction of the gas (say in a cylinder- causing a piston to move in) 4. an adiabetic contraction of the gas (say in a cylinder- causing a piston to move in) This imaginary working fluid is contained in the (cylinder)closed system and simply receives and rejects energy to a source and sink using perfect heat transfer (with no temperature difference ). As a result of receiving and rejecting energy it expands and contracts during four ideal reversible "no-flow" processes. The fluid is an ideal gas following the ideal gas laws. The work done through during a complete cycle is determined using the relationships identified on webpage Polytropic processes.... From the general relationship for adiabatic polytropic processes the following relationship is identified. Relationships Reversible Process Heat Transfer at T1 to Working Fluid From Hot Source Heat Rejected at T2 from Working Fluid From Sink Work done by working fluid Change in Internal Energy of Fluid Isothermal Expansion RmT 1log er 0 RmT 1log er 0 Adiabatic Expansion 0 0 Rm(T 1 - T 2 )/ (1- ? ) -Rm(T 1 - T 2 )/ (1- ? ) Isothermal Compression 0 RmT 2log er -RmT 2log er 0 Adiabatic Compression 0 0 -Rm(T 1 - T 2 )/ (1- ? ) Rm(T 1 - T 2 )/ (1- ? ) Totals RmT 1log er = Q 1 RmT 2log er = Q 2 Rm(T 1- T 2 )log er= W 0 From the table it can clearly be seen that the total work done by the carnot cycle is Rm(T1 - T1 )loge r = Q1 - Q2. The energy supplied = RmT1 loge r = Q1. Therefore This is the maximum efficiency achievable by an reversible thermodynamic cycle working with a ideal perfect gas. The following relationship results from the above.... Air Standard cycles Although the Carnot cycle is theoretically the most efficient it is in no way a practical device. Also the energy transfers would be far too slow for any real benefits to be realised. Internal combustion engines work on non cyclic processes because the fuel-air mix enters the system and products of combustion exit the system. . However theoretical cycles based on the hypothesis that air is the working fluid in a closed system receiving an rejecting energy to external sinks allows provide very crude estimations on the theoretical efficiencies possible internal combustion engines. For the purpose of the air standard cycles the suction and exhaust strokes are not considered.T The Otto Cycle or constant volume cycle has been proposed to provide an approximation of the 4 stroke Internal combustion cycle designed by Otto. The diesel cycle is used to approximate a cycle with heat being added at constant pressure.. Otto Cycle The Otto cycle is comprised of four reversible processes of air in a closed system: ? a -> c adiabatic compression, Page 4 Disclaimer: The information on this page has not been checked by an independent person. Use this information at your own risk. ROYMECH Home Thermos Index Thermodynamics Cycles Introduction Various internal combustion engine types have been devised and represented by various idealised cycles (otto cycle for four stroke, diesel cycle etc.. These idealised cycles are useful for determining the practical limitations and efficiencies possible. They do not however provide the answer to the question.. "What is the greatest fraction of the heat transfer from a energy source is it possible to convert into work ? i.e. what is the limiting efficiency of conversion ?" Carnot introduced a theoretical gas cycle based on ideal reversible process which provides this information Carnot Cycle Carnot in 1824 arrived at the "carnot cycle" which is an idealised gas cycle that obtains the maximum amount of work from an engine working in a thermodynamically reversible manner. This cycle provides a maximum efficiency for any thermodynamic heat engine The Carnot cycle for perfect gases is an idealised cycle composed of four reversible processes 1. an isothermal expansion of fixed mass of gas (say in a cylinder- causing a piston to move out) 2. an adiabetic expansion the gas (say in a cylinder- causing a piston to move out) 3. an isothermal contraction of the gas (say in a cylinder- causing a piston to move in) 4. an adiabetic contraction of the gas (say in a cylinder- causing a piston to move in) This imaginary working fluid is contained in the (cylinder)closed system and simply receives and rejects energy to a source and sink using perfect heat transfer (with no temperature difference ). As a result of receiving and rejecting energy it expands and contracts during four ideal reversible "no-flow" processes. The fluid is an ideal gas following the ideal gas laws. The work done through during a complete cycle is determined using the relationships identified on webpage Polytropic processes.... From the general relationship for adiabatic polytropic processes the following relationship is identified. Relationships Reversible Process Heat Transfer at T1 to Working Fluid From Hot Source Heat Rejected at T2 from Working Fluid From Sink Work done by working fluid Change in Internal Energy of Fluid Isothermal Expansion RmT 1log er 0 RmT 1log er 0 Adiabatic Expansion 0 0 Rm(T 1 - T 2 )/ (1- ? ) -Rm(T 1 - T 2 )/ (1- ? ) Isothermal Compression 0 RmT 2log er -RmT 2log er 0 Adiabatic Compression 0 0 -Rm(T 1 - T 2 )/ (1- ? ) Rm(T 1 - T 2 )/ (1- ? ) Totals RmT 1log er = Q 1 RmT 2log er = Q 2 Rm(T 1- T 2 )log er= W 0 From the table it can clearly be seen that the total work done by the carnot cycle is Rm(T1 - T1 )loge r = Q1 - Q2. The energy supplied = RmT1 loge r = Q1. Therefore This is the maximum efficiency achievable by an reversible thermodynamic cycle working with a ideal perfect gas. The following relationship results from the above.... Air Standard cycles Although the Carnot cycle is theoretically the most efficient it is in no way a practical device. Also the energy transfers would be far too slow for any real benefits to be realised. Internal combustion engines work on non cyclic processes because the fuel-air mix enters the system and products of combustion exit the system. . However theoretical cycles based on the hypothesis that air is the working fluid in a closed system receiving an rejecting energy to external sinks allows provide very crude estimations on the theoretical efficiencies possible internal combustion engines. For the purpose of the air standard cycles the suction and exhaust strokes are not considered.T The Otto Cycle or constant volume cycle has been proposed to provide an approximation of the 4 stroke Internal combustion cycle designed by Otto. The diesel cycle is used to approximate a cycle with heat being added at constant pressure.. Otto Cycle The Otto cycle is comprised of four reversible processes of air in a closed system: ? a -> c adiabatic compression, THERMODYNAMICS - THEORY Reversible and Irreversible Process Examples of Reversible and Irreversible Processes Click to View Movie (52 kB) A process is reversible if, after it has been carried out, it is possible to restore both the system and its entire surroundings to exactly the same states they were in before the process. If the system and its surroundings cannot return to their initial states at the end of the reversed process, this process is an irreversible process. A system can be restored to its initial state following a process, regardless if the process is reversible or not. If the surroundings can also be restored to its initial state, the process is reversible. Otherwise, the process is irreversible. Reversible process does not occur in nature. It is the idealization of actual process and serves as an idealized model to which actual process can be compared. The factors that cause a process to be irreversible are called irreversibilities. They include: ? heat transfers through a finite temperature difference ? unrestrained expansion of a gas ? mixing of two gases ? friction ? electric current flow through a resistance ? inelastic deformation ? chemical reactions The process is irreversible if any of these effects present. Internally and Externally Reversible Processes When a process is carried out, irreversibilities can be found within the system as well as in the system's surroundings. A process is called internally reversible if the system can be restored through exactly the same equilibrium states which the system goes through. No irreversibilities occur within the boundaries of the system as it goes through the process. If no irreversibilities occur outside the system boundaries during the process, the process is called Page 5 Disclaimer: The information on this page has not been checked by an independent person. Use this information at your own risk. ROYMECH Home Thermos Index Thermodynamics Cycles Introduction Various internal combustion engine types have been devised and represented by various idealised cycles (otto cycle for four stroke, diesel cycle etc.. These idealised cycles are useful for determining the practical limitations and efficiencies possible. They do not however provide the answer to the question.. "What is the greatest fraction of the heat transfer from a energy source is it possible to convert into work ? i.e. what is the limiting efficiency of conversion ?" Carnot introduced a theoretical gas cycle based on ideal reversible process which provides this information Carnot Cycle Carnot in 1824 arrived at the "carnot cycle" which is an idealised gas cycle that obtains the maximum amount of work from an engine working in a thermodynamically reversible manner. This cycle provides a maximum efficiency for any thermodynamic heat engine The Carnot cycle for perfect gases is an idealised cycle composed of four reversible processes 1. an isothermal expansion of fixed mass of gas (say in a cylinder- causing a piston to move out) 2. an adiabetic expansion the gas (say in a cylinder- causing a piston to move out) 3. an isothermal contraction of the gas (say in a cylinder- causing a piston to move in) 4. an adiabetic contraction of the gas (say in a cylinder- causing a piston to move in) This imaginary working fluid is contained in the (cylinder)closed system and simply receives and rejects energy to a source and sink using perfect heat transfer (with no temperature difference ). As a result of receiving and rejecting energy it expands and contracts during four ideal reversible "no-flow" processes. The fluid is an ideal gas following the ideal gas laws. The work done through during a complete cycle is determined using the relationships identified on webpage Polytropic processes.... From the general relationship for adiabatic polytropic processes the following relationship is identified. Relationships Reversible Process Heat Transfer at T1 to Working Fluid From Hot Source Heat Rejected at T2 from Working Fluid From Sink Work done by working fluid Change in Internal Energy of Fluid Isothermal Expansion RmT 1log er 0 RmT 1log er 0 Adiabatic Expansion 0 0 Rm(T 1 - T 2 )/ (1- ? ) -Rm(T 1 - T 2 )/ (1- ? ) Isothermal Compression 0 RmT 2log er -RmT 2log er 0 Adiabatic Compression 0 0 -Rm(T 1 - T 2 )/ (1- ? ) Rm(T 1 - T 2 )/ (1- ? ) Totals RmT 1log er = Q 1 RmT 2log er = Q 2 Rm(T 1- T 2 )log er= W 0 From the table it can clearly be seen that the total work done by the carnot cycle is Rm(T1 - T1 )loge r = Q1 - Q2. The energy supplied = RmT1 loge r = Q1. Therefore This is the maximum efficiency achievable by an reversible thermodynamic cycle working with a ideal perfect gas. The following relationship results from the above.... Air Standard cycles Although the Carnot cycle is theoretically the most efficient it is in no way a practical device. Also the energy transfers would be far too slow for any real benefits to be realised. Internal combustion engines work on non cyclic processes because the fuel-air mix enters the system and products of combustion exit the system. . However theoretical cycles based on the hypothesis that air is the working fluid in a closed system receiving an rejecting energy to external sinks allows provide very crude estimations on the theoretical efficiencies possible internal combustion engines. For the purpose of the air standard cycles the suction and exhaust strokes are not considered.T The Otto Cycle or constant volume cycle has been proposed to provide an approximation of the 4 stroke Internal combustion cycle designed by Otto. The diesel cycle is used to approximate a cycle with heat being added at constant pressure.. Otto Cycle The Otto cycle is comprised of four reversible processes of air in a closed system: ? a -> c adiabatic compression, THERMODYNAMICS - THEORY Reversible and Irreversible Process Examples of Reversible and Irreversible Processes Click to View Movie (52 kB) A process is reversible if, after it has been carried out, it is possible to restore both the system and its entire surroundings to exactly the same states they were in before the process. If the system and its surroundings cannot return to their initial states at the end of the reversed process, this process is an irreversible process. A system can be restored to its initial state following a process, regardless if the process is reversible or not. If the surroundings can also be restored to its initial state, the process is reversible. Otherwise, the process is irreversible. Reversible process does not occur in nature. It is the idealization of actual process and serves as an idealized model to which actual process can be compared. The factors that cause a process to be irreversible are called irreversibilities. They include: ? heat transfers through a finite temperature difference ? unrestrained expansion of a gas ? mixing of two gases ? friction ? electric current flow through a resistance ? inelastic deformation ? chemical reactions The process is irreversible if any of these effects present. Internally and Externally Reversible Processes When a process is carried out, irreversibilities can be found within the system as well as in the system's surroundings. A process is called internally reversible if the system can be restored through exactly the same equilibrium states which the system goes through. No irreversibilities occur within the boundaries of the system as it goes through the process. If no irreversibilities occur outside the system boundaries during the process, the process is called externally reversible. A process is called totally reversible, or reversible, if it is both internally and externally reversible. The Carnot Cycle The Carnot Cycle (1-2): Reversible Isothermal Expansion Click to View Movie (36 kB) The Carnot Cycle (2-3): Reversible Adiabatic Expansion Click to View Movie (40 kB) The Carnot Cycle (3-4): Reversible Isothermal Compression Click to View Movie (40 kB) Heat engine operates on a cycle. The efficiency of heat engine depends on how the individual processes are executed. The most efficient cycles are reversible cycles, that is, the processes that make up the cycle are all reversible processes. Reversible cycles cannot be achieved in practice. However, they provide the upper limits on the performance of real cycles. Carnot cycle is one of the best-known reversible cycles. The Carnot cycle is composed of four reversible processes. Consider an adiabaticpiston- cylinder device that contains gas. The four reversible processes that make up the Carnot cycle are as follows: ? Reversible Isothermal Expansion (process 1- 2): Heat transfer between the heat source and the cylinder occurs with an infinitesimal temperature difference. Hence, it is a reversible heat transfer process. Gas in the cylinder expands slowly, does work to its surroundings, and remains at a constant temperature TH. The total amount of heat transferred to the gas during this process is QH. ? Reversible adiabatic expansion (process 2-3): The heat source is removed, and the gas expands in an adiabatic manner. Gas in the cylinder continues to expand slowly, do work to its surroundings till the temperature of the gas drops from TH to TL. Assuming the piston moves frictionless and the process to be quasi-equilibrium, the process is reversible as well as adiabatic. ? Reversible isothermal compression (process 3-4): The cylinder is brought into contact with a heat sink at temperature TL. The piston is pushed by an external force and which does work on the gas. During the compression, the gas temperature maintains at TL and the process is a reversible heat transfer process. The total amount of heat rejected to the heatRead More
1. What is a thermodynamic cycle? | ![]() |
2. What are the main types of thermodynamic cycles? | ![]() |
3. How does a thermodynamic cycle work? | ![]() |
4. What is the purpose of a thermodynamic cycle? | ![]() |
5. What are some real-life applications of thermodynamic cycles? | ![]() |