Page 1
1 | P a g e
KENDRIYA VIDYALAYA SANGATHAN
RAIPUR REGION
STUDY MODULES
CHEMISTRY
CLASS-XI 2016-17
NAME OF CHAPTERS
1. CHEMICAL BONDING & MOLECULAR STRUCTURE
2. THERMODYNAMICS
3. EQUILLIBRIUM
4. REDOX REACTIONS
5. S- BLOCK ELEMENTS
6. SOME P-BLOCK ELEMENTS
7. ORGANIC CHEMISTRY & BASIC PRINCIPLES
8. HYDROCARBONS
COORDINATOR- SHRI K. SASEENDRAN,
ASSISTANT COMMISSIONER, KVS-RO RAIPUR
SUBJECT EXPERTS-
MRS M. SHARDA RAO,PGT(CHEM.) K.V. SECL JHAGRAKHAND
MR. SANTOSH CHAINI,PGT (CHEM), KV DONGARGARH
Page 2
1 | P a g e
KENDRIYA VIDYALAYA SANGATHAN
RAIPUR REGION
STUDY MODULES
CHEMISTRY
CLASS-XI 2016-17
NAME OF CHAPTERS
1. CHEMICAL BONDING & MOLECULAR STRUCTURE
2. THERMODYNAMICS
3. EQUILLIBRIUM
4. REDOX REACTIONS
5. S- BLOCK ELEMENTS
6. SOME P-BLOCK ELEMENTS
7. ORGANIC CHEMISTRY & BASIC PRINCIPLES
8. HYDROCARBONS
COORDINATOR- SHRI K. SASEENDRAN,
ASSISTANT COMMISSIONER, KVS-RO RAIPUR
SUBJECT EXPERTS-
MRS M. SHARDA RAO,PGT(CHEM.) K.V. SECL JHAGRAKHAND
MR. SANTOSH CHAINI,PGT (CHEM), KV DONGARGARH
2 | P a g e
INDEX
S.N NAME OF THE UNIT PAGE NO.
FROM--- TO---
1 CHEMICAL BONDING & MOLECULAR STRUCTURE
Basic concepts and Practice Question with Answers
03--27
2 THERMODYNAMICS
Basic concepts and Practice Question with Answers
28-34
3 EQUILLIBRIUM
Basic concepts and Practice Question with Answers
35-40
4 REDOX REACTIONS
Basic concepts and Practice Question with Answers
36-46
5 S- BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
47-51
6 SOME P-BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
52-71
7 ORGANIC CHEMISTRY –
SOME BASIC PRINCIPLES AND TECHNIQUES
Basic concepts and Practice Question with Answers
72-85
8 HYDROCARBONS
Basic concepts and Practice Question with Answers
86-101
Page 3
1 | P a g e
KENDRIYA VIDYALAYA SANGATHAN
RAIPUR REGION
STUDY MODULES
CHEMISTRY
CLASS-XI 2016-17
NAME OF CHAPTERS
1. CHEMICAL BONDING & MOLECULAR STRUCTURE
2. THERMODYNAMICS
3. EQUILLIBRIUM
4. REDOX REACTIONS
5. S- BLOCK ELEMENTS
6. SOME P-BLOCK ELEMENTS
7. ORGANIC CHEMISTRY & BASIC PRINCIPLES
8. HYDROCARBONS
COORDINATOR- SHRI K. SASEENDRAN,
ASSISTANT COMMISSIONER, KVS-RO RAIPUR
SUBJECT EXPERTS-
MRS M. SHARDA RAO,PGT(CHEM.) K.V. SECL JHAGRAKHAND
MR. SANTOSH CHAINI,PGT (CHEM), KV DONGARGARH
2 | P a g e
INDEX
S.N NAME OF THE UNIT PAGE NO.
FROM--- TO---
1 CHEMICAL BONDING & MOLECULAR STRUCTURE
Basic concepts and Practice Question with Answers
03--27
2 THERMODYNAMICS
Basic concepts and Practice Question with Answers
28-34
3 EQUILLIBRIUM
Basic concepts and Practice Question with Answers
35-40
4 REDOX REACTIONS
Basic concepts and Practice Question with Answers
36-46
5 S- BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
47-51
6 SOME P-BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
52-71
7 ORGANIC CHEMISTRY –
SOME BASIC PRINCIPLES AND TECHNIQUES
Basic concepts and Practice Question with Answers
72-85
8 HYDROCARBONS
Basic concepts and Practice Question with Answers
86-101
3 | P a g e
CHAPTER-4
CHEMICAL BONDING AND MOLECULAR STRUCTURE
OCTET RULE- During a chemical reaction the atoms tend to adjust their electronic
arrangement in such a way that they achieve 8 e
-
in their outermost electron. This is called
octet rule.
CHEMICAL BOND- the chemical force which keeps the atoms in any molecule
together is called a chemical bond.
IONIC BOND- The columbic force of attraction which holds the appositively charged ions
together is called an ionic bond. An ionic bond is formed by the complete transfer of one or
more electrons from the atom of a metal to an atom of non- metal.
LATTICE ENTHALPY- The molar enthalpy change accompanying the complete separation of
the constituent particles that compose of the solids (such as ions for ionic solid, molecules for
molecular solids) under standard conditions is called lattice enthalpy (?
l
H
o
). The lattice enthalpy
is a positive quantity.
ELECTRO VALENCY: The number of electrons lost or gain by an atom of an element is
called as electrovalency.
The element which give up electrons to form positive ions are said to have positive valency,
while the elements which accept electrons to form negative ions are said to have negative
valency.
FORMATION OF AN IONIC BOND: It is favoured by, (i) the low ionisation enthalpy of
a metallic element which forms the cations, (ii) High electron gain enthalpy of non- metallic
element which forms the anions, (iii) Large lattice enthalpy i.e; the smaller size and the
higher charge of the atoms.
COVALENCY:The number of electrons which an atom contributes towards mutual sharing
during the formation of a chemical bond called its covalency in that compound.
SINGLE COVALENT BOND: A covalent bond formed by the mutual sharing of one pair of
electrons is called a single covalent bond, or simply a single bond. A single covalent bond is
represented by a small line (-) between the two atoms
DOUBLE COVALENT BOND: A covalent bond formed by the mutual sharing of two pair of
electrons is called a double covalent bond, or simply a double bond. A double covalent bond is
represented by two small horizontal lines (=) between the two atoms. E.g. O=O, O=C=O etc.
TRIPLE COVALENT BOND: A covalent bond formed by the mutual sharing of three pair of
electrons is called a triple covalent bond, or simply a triple bond. A triple covalent bond is
represented by three small horizontal lines (=) between the two atoms. E.g. N=N, H-C=C-H etc.
FORMATION OF A COVALENT BOND: Formation of a covalent bond is favoured by
(i) High ionisation enthalpy of the combining elements.
(ii) Nearly equal electron gain enthalpy and equal electro-negativities of combining elements.
(iii) High nuclear charge and small atomic size of the combining elements.
POLAR COVALENT BOND: The bond between two unlike atoms which differ in their
affinities for electrons is said to be polar covalent bond. E.g. H-Cl
COORDINATE BOND: The bond formed when one sided sharing of electrons take place is
called a coordinate bond. Such a bond is also known as dative bond. It is represented by an
arrow (?) pointing towards the acceptor atom. E.g. H
3N
?BF
3
Bond Length: Bond length is defined as the equilibrium distance between the nuclei of
two bonded atoms in a molecule
Bond Angle: It is defined as the angle between the orbitals containing bonding electron
pairs around the central atom in a molecule/complex ion.
Bond Enthalpy: It is defined as the amount of energy required to break one mole of bonds of
a particular type between two atoms in a gaseous state.
Page 4
1 | P a g e
KENDRIYA VIDYALAYA SANGATHAN
RAIPUR REGION
STUDY MODULES
CHEMISTRY
CLASS-XI 2016-17
NAME OF CHAPTERS
1. CHEMICAL BONDING & MOLECULAR STRUCTURE
2. THERMODYNAMICS
3. EQUILLIBRIUM
4. REDOX REACTIONS
5. S- BLOCK ELEMENTS
6. SOME P-BLOCK ELEMENTS
7. ORGANIC CHEMISTRY & BASIC PRINCIPLES
8. HYDROCARBONS
COORDINATOR- SHRI K. SASEENDRAN,
ASSISTANT COMMISSIONER, KVS-RO RAIPUR
SUBJECT EXPERTS-
MRS M. SHARDA RAO,PGT(CHEM.) K.V. SECL JHAGRAKHAND
MR. SANTOSH CHAINI,PGT (CHEM), KV DONGARGARH
2 | P a g e
INDEX
S.N NAME OF THE UNIT PAGE NO.
FROM--- TO---
1 CHEMICAL BONDING & MOLECULAR STRUCTURE
Basic concepts and Practice Question with Answers
03--27
2 THERMODYNAMICS
Basic concepts and Practice Question with Answers
28-34
3 EQUILLIBRIUM
Basic concepts and Practice Question with Answers
35-40
4 REDOX REACTIONS
Basic concepts and Practice Question with Answers
36-46
5 S- BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
47-51
6 SOME P-BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
52-71
7 ORGANIC CHEMISTRY –
SOME BASIC PRINCIPLES AND TECHNIQUES
Basic concepts and Practice Question with Answers
72-85
8 HYDROCARBONS
Basic concepts and Practice Question with Answers
86-101
3 | P a g e
CHAPTER-4
CHEMICAL BONDING AND MOLECULAR STRUCTURE
OCTET RULE- During a chemical reaction the atoms tend to adjust their electronic
arrangement in such a way that they achieve 8 e
-
in their outermost electron. This is called
octet rule.
CHEMICAL BOND- the chemical force which keeps the atoms in any molecule
together is called a chemical bond.
IONIC BOND- The columbic force of attraction which holds the appositively charged ions
together is called an ionic bond. An ionic bond is formed by the complete transfer of one or
more electrons from the atom of a metal to an atom of non- metal.
LATTICE ENTHALPY- The molar enthalpy change accompanying the complete separation of
the constituent particles that compose of the solids (such as ions for ionic solid, molecules for
molecular solids) under standard conditions is called lattice enthalpy (?
l
H
o
). The lattice enthalpy
is a positive quantity.
ELECTRO VALENCY: The number of electrons lost or gain by an atom of an element is
called as electrovalency.
The element which give up electrons to form positive ions are said to have positive valency,
while the elements which accept electrons to form negative ions are said to have negative
valency.
FORMATION OF AN IONIC BOND: It is favoured by, (i) the low ionisation enthalpy of
a metallic element which forms the cations, (ii) High electron gain enthalpy of non- metallic
element which forms the anions, (iii) Large lattice enthalpy i.e; the smaller size and the
higher charge of the atoms.
COVALENCY:The number of electrons which an atom contributes towards mutual sharing
during the formation of a chemical bond called its covalency in that compound.
SINGLE COVALENT BOND: A covalent bond formed by the mutual sharing of one pair of
electrons is called a single covalent bond, or simply a single bond. A single covalent bond is
represented by a small line (-) between the two atoms
DOUBLE COVALENT BOND: A covalent bond formed by the mutual sharing of two pair of
electrons is called a double covalent bond, or simply a double bond. A double covalent bond is
represented by two small horizontal lines (=) between the two atoms. E.g. O=O, O=C=O etc.
TRIPLE COVALENT BOND: A covalent bond formed by the mutual sharing of three pair of
electrons is called a triple covalent bond, or simply a triple bond. A triple covalent bond is
represented by three small horizontal lines (=) between the two atoms. E.g. N=N, H-C=C-H etc.
FORMATION OF A COVALENT BOND: Formation of a covalent bond is favoured by
(i) High ionisation enthalpy of the combining elements.
(ii) Nearly equal electron gain enthalpy and equal electro-negativities of combining elements.
(iii) High nuclear charge and small atomic size of the combining elements.
POLAR COVALENT BOND: The bond between two unlike atoms which differ in their
affinities for electrons is said to be polar covalent bond. E.g. H-Cl
COORDINATE BOND: The bond formed when one sided sharing of electrons take place is
called a coordinate bond. Such a bond is also known as dative bond. It is represented by an
arrow (?) pointing towards the acceptor atom. E.g. H
3N
?BF
3
Bond Length: Bond length is defined as the equilibrium distance between the nuclei of
two bonded atoms in a molecule
Bond Angle: It is defined as the angle between the orbitals containing bonding electron
pairs around the central atom in a molecule/complex ion.
Bond Enthalpy: It is defined as the amount of energy required to break one mole of bonds of
a particular type between two atoms in a gaseous state.
4 | P a g e
DOUBLE COVALENT BOND: A covalent bond formed by the mutual sharing
of two pair of electrons is called a double covalent bond, or simply a double bond.
A double covalent bond is represented by two small horizontal lines (=) between
the two atoms. E.g. O=O, O=C=O etc.
TRIPLE COVALENT BOND: A covalent bond formed by the mutual sharing
of three pair of electrons is called a triple covalent bond, or simply a triple bond.
A triple covalent bond is represented by three small horizontal lines (=) between
the two atoms. E.g. N=N, H-C=C-H etc.
FORMATION OF A COVALENT BOND: Formation of a covalent bond
is favoured by
(i) High ionisation enthalpy of the combining elements.
(ii) Nearly equal electron gain enthalpy and equal electro-negativities
of combining elements.
(iii) High nuclear charge and small atomic size of the combining elements.
POLAR COVALENT BOND: The bond between two unlike atoms which
differ in their affinities for electrons is said to be polar covalent bond. E.g. H-Cl
COORDINATE BOND: The bond formed when one sided sharing of electrons take
place is called a coordinate bond. Such a bond is also known as dative bond. It is
represented by an arrow (?) pointing towards the acceptor atom. E.g. H
3N
?BF
3
Bond Length: Bond length is defined as the equilibrium distance between
the nuclei of two bonded atoms in a molecule
Bond Angle: It is defined as the angle between the orbitals containing
bonding electron pairs around the central atom in a molecule/complex ion
Bond Enthalpy: It is defined as the amount of energy required to break one
mole of bonds of a particular type between two atoms in a gaseous state.
Bond Order: In the Lewis description of covalent bond, the Bond Order is given
by the number of bonds between the two atoms in a molecule
Resonance:whenever a single Lewis structure cannot describe a molecule
accurately, a number of structures with similar energy, positions of nuclei,
bonding and non-bonding pairs of electrons are taken as the canonical structures of
the hybrid which describes the molecule accurately
Dipole moment : The product of the magnitude of the charge and the distance between
the centres of positive and negative charge.It is a vector quantity and is represented by
an arrow with its tail at the positive centre and head pointing towards a negative centre.
Dipole moment ( µ) = charge (Q) × distance of separation (r)
Page 5
1 | P a g e
KENDRIYA VIDYALAYA SANGATHAN
RAIPUR REGION
STUDY MODULES
CHEMISTRY
CLASS-XI 2016-17
NAME OF CHAPTERS
1. CHEMICAL BONDING & MOLECULAR STRUCTURE
2. THERMODYNAMICS
3. EQUILLIBRIUM
4. REDOX REACTIONS
5. S- BLOCK ELEMENTS
6. SOME P-BLOCK ELEMENTS
7. ORGANIC CHEMISTRY & BASIC PRINCIPLES
8. HYDROCARBONS
COORDINATOR- SHRI K. SASEENDRAN,
ASSISTANT COMMISSIONER, KVS-RO RAIPUR
SUBJECT EXPERTS-
MRS M. SHARDA RAO,PGT(CHEM.) K.V. SECL JHAGRAKHAND
MR. SANTOSH CHAINI,PGT (CHEM), KV DONGARGARH
2 | P a g e
INDEX
S.N NAME OF THE UNIT PAGE NO.
FROM--- TO---
1 CHEMICAL BONDING & MOLECULAR STRUCTURE
Basic concepts and Practice Question with Answers
03--27
2 THERMODYNAMICS
Basic concepts and Practice Question with Answers
28-34
3 EQUILLIBRIUM
Basic concepts and Practice Question with Answers
35-40
4 REDOX REACTIONS
Basic concepts and Practice Question with Answers
36-46
5 S- BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
47-51
6 SOME P-BLOCK ELEMENTS
Basic concepts and Practice Question with Answers
52-71
7 ORGANIC CHEMISTRY –
SOME BASIC PRINCIPLES AND TECHNIQUES
Basic concepts and Practice Question with Answers
72-85
8 HYDROCARBONS
Basic concepts and Practice Question with Answers
86-101
3 | P a g e
CHAPTER-4
CHEMICAL BONDING AND MOLECULAR STRUCTURE
OCTET RULE- During a chemical reaction the atoms tend to adjust their electronic
arrangement in such a way that they achieve 8 e
-
in their outermost electron. This is called
octet rule.
CHEMICAL BOND- the chemical force which keeps the atoms in any molecule
together is called a chemical bond.
IONIC BOND- The columbic force of attraction which holds the appositively charged ions
together is called an ionic bond. An ionic bond is formed by the complete transfer of one or
more electrons from the atom of a metal to an atom of non- metal.
LATTICE ENTHALPY- The molar enthalpy change accompanying the complete separation of
the constituent particles that compose of the solids (such as ions for ionic solid, molecules for
molecular solids) under standard conditions is called lattice enthalpy (?
l
H
o
). The lattice enthalpy
is a positive quantity.
ELECTRO VALENCY: The number of electrons lost or gain by an atom of an element is
called as electrovalency.
The element which give up electrons to form positive ions are said to have positive valency,
while the elements which accept electrons to form negative ions are said to have negative
valency.
FORMATION OF AN IONIC BOND: It is favoured by, (i) the low ionisation enthalpy of
a metallic element which forms the cations, (ii) High electron gain enthalpy of non- metallic
element which forms the anions, (iii) Large lattice enthalpy i.e; the smaller size and the
higher charge of the atoms.
COVALENCY:The number of electrons which an atom contributes towards mutual sharing
during the formation of a chemical bond called its covalency in that compound.
SINGLE COVALENT BOND: A covalent bond formed by the mutual sharing of one pair of
electrons is called a single covalent bond, or simply a single bond. A single covalent bond is
represented by a small line (-) between the two atoms
DOUBLE COVALENT BOND: A covalent bond formed by the mutual sharing of two pair of
electrons is called a double covalent bond, or simply a double bond. A double covalent bond is
represented by two small horizontal lines (=) between the two atoms. E.g. O=O, O=C=O etc.
TRIPLE COVALENT BOND: A covalent bond formed by the mutual sharing of three pair of
electrons is called a triple covalent bond, or simply a triple bond. A triple covalent bond is
represented by three small horizontal lines (=) between the two atoms. E.g. N=N, H-C=C-H etc.
FORMATION OF A COVALENT BOND: Formation of a covalent bond is favoured by
(i) High ionisation enthalpy of the combining elements.
(ii) Nearly equal electron gain enthalpy and equal electro-negativities of combining elements.
(iii) High nuclear charge and small atomic size of the combining elements.
POLAR COVALENT BOND: The bond between two unlike atoms which differ in their
affinities for electrons is said to be polar covalent bond. E.g. H-Cl
COORDINATE BOND: The bond formed when one sided sharing of electrons take place is
called a coordinate bond. Such a bond is also known as dative bond. It is represented by an
arrow (?) pointing towards the acceptor atom. E.g. H
3N
?BF
3
Bond Length: Bond length is defined as the equilibrium distance between the nuclei of
two bonded atoms in a molecule
Bond Angle: It is defined as the angle between the orbitals containing bonding electron
pairs around the central atom in a molecule/complex ion.
Bond Enthalpy: It is defined as the amount of energy required to break one mole of bonds of
a particular type between two atoms in a gaseous state.
4 | P a g e
DOUBLE COVALENT BOND: A covalent bond formed by the mutual sharing
of two pair of electrons is called a double covalent bond, or simply a double bond.
A double covalent bond is represented by two small horizontal lines (=) between
the two atoms. E.g. O=O, O=C=O etc.
TRIPLE COVALENT BOND: A covalent bond formed by the mutual sharing
of three pair of electrons is called a triple covalent bond, or simply a triple bond.
A triple covalent bond is represented by three small horizontal lines (=) between
the two atoms. E.g. N=N, H-C=C-H etc.
FORMATION OF A COVALENT BOND: Formation of a covalent bond
is favoured by
(i) High ionisation enthalpy of the combining elements.
(ii) Nearly equal electron gain enthalpy and equal electro-negativities
of combining elements.
(iii) High nuclear charge and small atomic size of the combining elements.
POLAR COVALENT BOND: The bond between two unlike atoms which
differ in their affinities for electrons is said to be polar covalent bond. E.g. H-Cl
COORDINATE BOND: The bond formed when one sided sharing of electrons take
place is called a coordinate bond. Such a bond is also known as dative bond. It is
represented by an arrow (?) pointing towards the acceptor atom. E.g. H
3N
?BF
3
Bond Length: Bond length is defined as the equilibrium distance between
the nuclei of two bonded atoms in a molecule
Bond Angle: It is defined as the angle between the orbitals containing
bonding electron pairs around the central atom in a molecule/complex ion
Bond Enthalpy: It is defined as the amount of energy required to break one
mole of bonds of a particular type between two atoms in a gaseous state.
Bond Order: In the Lewis description of covalent bond, the Bond Order is given
by the number of bonds between the two atoms in a molecule
Resonance:whenever a single Lewis structure cannot describe a molecule
accurately, a number of structures with similar energy, positions of nuclei,
bonding and non-bonding pairs of electrons are taken as the canonical structures of
the hybrid which describes the molecule accurately
Dipole moment : The product of the magnitude of the charge and the distance between
the centres of positive and negative charge.It is a vector quantity and is represented by
an arrow with its tail at the positive centre and head pointing towards a negative centre.
Dipole moment ( µ) = charge (Q) × distance of separation (r)
5 | P a g e
SIGMA BOND: A covalent bond formed due to the overlapping of orbitals of
the two atoms along the line joining the two nuclei (orbital axis) is called sigma
(s) bond. For example, the bond formed due to s-s and s-p, p-p overlapping along
the orbital axis are sigma bonds.
Pi- BOND: A covalent bond formed by the side wise overlapping of p- or d-
orbitals of two atoms is called as pi (p) bond. For example, the bond formed due
to the sideways overlapping of the two p- orbitals is a pi- bond.
HYDROGEN BOND: The bond between the hydrogen atom of one molecule and
a more electro- negative element of same or another molecule is called as
hydrogen bond.
HYBRIDIZATION: The process of mixing of the atomic orbitals to form new
hybrid orbitals is called hybridization. All hybrid orbitals of a particular kind
have equal energy, identical shapes and are symmetrically oriented in shape.
The hybrid orbitals are designed according to the type and the atomic
orbitals merging together, e.g.,
Molecu
Electron
Examples
le Type
Shape arrangeme Geometry
nt
†
‡
AX
2
E
0
Linear
BeCl
2
, HgCl
2
, CO
2
AX
2
E
1
Bent
NO
2
-
, SO
2
, O
3
, CCl
2
AX
2
E
2
Bent
H
2
O, OF
2
AX
2
E
3
Linear
XeF
2
, I
3
-
, XeCl
2
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