Is there any trick or method to learn order of (+) and (-)inductive ef...
Tricks to Learn Order of ( ) and (-) Inductive Effect
Introduction
The order of ( ) and (-) inductive effect is essential to understand in organic chemistry. The inductive effect is an electronic effect that occurs due to differences in electronegativity between atoms. The (+) inductive effect is when an electron-donating group increases the electron density of a molecule, while the (-) inductive effect is when an electron-withdrawing group decreases the electron density of a molecule. In this article, we will discuss some tricks to learn the order of ( ) and (-) inductive effect.
Tricks to Learn the Order of (+) Inductive Effect
The order of (+) inductive effect can be remembered by using the following tricks:
- The order of (+) inductive effect is determined by the electronegativity of the attached substituent. The higher the electronegativity, the higher the (+) inductive effect.
- Another trick is to remember the acronym I > N > O > F > Cl > Br > S > C > H. This stands for the electronegativity of the common substituents found in organic chemistry. The order of (+) inductive effect follows this sequence.
- Lastly, the order of (+) inductive effect can be memorized by understanding the concept of hyperconjugation. The more the number of alpha hydrogens, the higher the (+) inductive effect.
Tricks to Learn the Order of (-) Inductive Effect
The order of (-) inductive effect can be remembered by using the following tricks:
- The order of (-) inductive effect is determined by the electronegativity of the attached substituent. The higher the electronegativity, the higher the (-) inductive effect.
- The order of (-) inductive effect can also be memorized by remembering the order of the halogens. The order is F > Cl > Br > I.
- Lastly, the order of (-) inductive effect can be memorized by understanding the concept of resonance. Resonance structures with a negative charge or pi bonds have a higher (-) inductive effect.
Conclusion
In conclusion, learning the order of ( ) and (-) inductive effect is crucial in organic chemistry. By using the tricks mentioned above, one can easily memorize the order and apply it in various organic chemistry problems. It is important to note that these tricks are not a substitute for understanding the concept of inductive effect. Therefore, it is essential to grasp the fundamental concepts before applying these tricks.
Is there any trick or method to learn order of (+) and (-)inductive ef...
More electronegative atoms like N,O,F and Halogens present in a group or in combination wirh a carbon atom ,then it shows -I effect.Remember, presence of -I group increases the acidic strength of the acid as it stabilises the conjugate base and a +I group decreases the acidity of the acid by destabilizing the conjugate base.