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Can aqueous KOH give elimination reaction in any case ?
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Can aqueous KOH give elimination reaction in any case ?
Elimination reactions. Halogenoalkanes also undergo elimination reactions in the presence of sodium or potassium hydroxide. The 2-bromopropane has reacted to give an alkene - propene. Notice that a hydrogen atom has been removed from one of the end carbon atoms together with the bromine from the centre one.
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Can aqueous KOH give elimination reaction in any case ?
Can Aqueous KOH Give Elimination Reaction?
Elimination reactions are common in organic chemistry and can occur with aqueous KOH under certain conditions. Here's a detailed explanation:

Conditions for Elimination Reaction:
- Aqueous KOH can promote elimination reactions in certain cases where a suitable substrate is present.
- The substrate should have a leaving group capable of forming a stable anion.
- The reaction conditions, such as temperature and concentration, can also influence the occurrence of an elimination reaction.

Mechanism of Elimination Reaction:
- In the presence of aqueous KOH, the base (OH-) can abstract a proton from the substrate to form an alkoxide ion.
- The alkoxide ion can then undergo elimination by losing a leaving group to form a double bond, resulting in the elimination product.

Types of Elimination Reactions:
- The most common types of elimination reactions are E1 and E2 mechanisms, which depend on the nature of the substrate and reaction conditions.
- E1 reactions proceed via a carbocation intermediate, while E2 reactions occur in a concerted manner.

Factors Influencing Elimination Reactions:
- The nature of the substrate, leaving group, and base can all affect the outcome of an elimination reaction.
- Steric hindrance and solvent effects can also play a role in determining the mechanism and product formation.
In conclusion, while aqueous KOH can facilitate elimination reactions under suitable conditions, it is essential to consider the specific factors that influence the reaction outcome. Understanding the mechanism and types of elimination reactions can help predict and control the product formation in organic synthesis.
Community Answer
Can aqueous KOH give elimination reaction in any case ?
No. An alkaline medium along with KOH is definitely required to carry out elimination (For instance, ethanol + KOH) . Now if you wonder why elimination product cannot be obtained in aq KOH (since KOH is a base as well), the reason is that even if KOH manages to extract a H+ from the reactant (as what happens in an elimination reaction), the aquous medium will resupply that H+ to the reactant.
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There are many reactions which obey a first order rate equation although it reality they are bi- or ter-molecular. As an example of these may be taken the decomposition of Carbonyl sulfide in water, namely, COS + H20 002 + H2SAccording to the law of mass action this reaction should be second order with the rate dependent on the concentration of both the carbonyl sulfide and the water. Actually however, the rate is found to be first order with respect to the carbonyl sulfide and independent of the water Reactions exhibiting such behaviour are said to be pseudo-molecular.The pseudo-unimoecuar nature of this reaction is explainable by the fact that water is present in such excess that its concentration remains practically constant during the course of the reaction. Under these condition b x = b, and the rate equation becomesOn integration this leads towhich is the equation for a first order reaction. It is evident, however, that the now constant k is not independent of the concentration, as is the case with true first order constants, but may vary with b if the latter is changed appreciably, When such is the case, the true constant k2 can be obtained from k by dividing the latter by b. pseudo-molecular reactions are encountered whenever one or more of the reactants remain constants during the course of an experiment. This is the case with reactions conducted in solvents which are themselves one of the reactants, as in the decomposition of carbonyl sulfide in water, or in the esterification of acetic anhydride in alcohol(CH3C0)20 + 2C2H5OH 2CH3C00C2H5 + H20Again, this is also true of reactions subject to catalysis, in which case the concentration of the catalyst does not change. The decomposition of diacetone alcohol to acetone in aqueous solution is catalysed by hydroxyl ions, with the rate proportional to the concentration of the alcohol and that of the base. Since the concentration of the base does not change within any one experiment, however, the rate equation reduces to one of first order with respect to the alcohol. But the rateconstant k obtained for various concentrations of base are not identical, as may be seen from table. To obtain from these the true second order velocity constant, the ks must be divided by the hydroxyl ion concentration. When this is done excellent k2 values result, as column 3 indicatesTable : Decomposition of diacetone alcohol in water at 25C (Catalyst : NaOH)Q.By what factor does the rate of reaction of diacetone alcohol in water solution change if p0H is increased by 2 units other things remaining same ?

Can aqueous KOH give elimination reaction in any case ?
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