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A physician wishes to prepare a buffer solution of pH = 3.58 that efficiently resists a change in pH yet contains only small concentrations of the buffering agents. Which one of the following weak acids together with its sodium salt would be the best to use ? [1997]
  • a)
    m-chlorobenzoic acid (pKa = 3.98)
  • b)
    p-chlorocinnamic acid (pKa = 4.41)
  • c)
    2, 5-dihydroxy benzoic acid (pKa =  2.97)
  • d)
    Acetoacetic acid (pKa = 3.58)
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
A physician wishes to prepare a buffer solution of pH = 3.58 that effi...
For small concentration of buffering agent and for maximum buffer capacity
∴ pH = pKa
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Most Upvoted Answer
A physician wishes to prepare a buffer solution of pH = 3.58 that effi...
To prepare a buffer solution of pH 3.58, the physician needs to choose a weak acid and its sodium salt that can efficiently resist changes in pH. The best choice for this buffer solution is acetoacetic acid (pKa = 3.58).

Explanation:
1. Understanding buffer solutions:
- A buffer solution consists of a weak acid and its conjugate base (salt) or a weak base and its conjugate acid.
- Buffers are able to resist changes in pH when small amounts of acid or base are added to the solution.
- The pH of a buffer solution is determined by the pKa of the weak acid and its salt.

2. Choosing the best weak acid-salt pair:
- The pH of the buffer solution should be close to the desired pH of 3.58.
- The pKa of the weak acid should be close to the desired pH for effective buffering.
- The weak acid and its salt should be present in small concentrations to minimize the effect on the overall pH of the solution.

3. Analyzing the options:
a) m-chlorobenzoic acid (pKa = 3.98):
- The pKa is higher than the desired pH, indicating that it may not be an efficient buffer at pH 3.58.
- It is not the best choice for this buffer solution.

b) p-chlorocinnamic acid (pKa = 4.41):
- The pKa is higher than the desired pH, suggesting that it may not be an effective buffer at pH 3.58.
- It is not the best choice for this buffer solution.

c) 2, 5-dihydroxy benzoic acid (pKa = 2.97):
- The pKa is lower than the desired pH, indicating that it may not be an efficient buffer at pH 3.58.
- It is not the best choice for this buffer solution.

d) Acetoacetic acid (pKa = 3.58):
- The pKa is equal to the desired pH, indicating that it has the potential to be an effective buffer at pH 3.58.
- It is the best choice for this buffer solution.

Conclusion:
Based on the analysis, acetoacetic acid (pKa = 3.58) and its sodium salt would be the best choice for preparing a buffer solution of pH 3.58 that efficiently resists changes in pH while containing only small concentrations of the buffering agents.
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A physician wishes to prepare a buffer solution of pH = 3.58 that efficiently resists a change in pH yet contains only small concentrations of the buffering agents. Which one of the following weak acids together with its sodium salt would be the best to use ? [1997]a)m-chlorobenzoic acid (pKa = 3.98)b)p-chlorocinnamic acid (pKa = 4.41)c)2, 5-dihydroxy benzoic acid (pKa = 2.97)d)Acetoacetic acid (pKa = 3.58)Correct answer is option 'D'. Can you explain this answer?
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