The low density of ice compared to water is due to[1997]a)hydrogen-bon...
We know that due to polar nature, water molecules are held together by intermolecular hydrogen bonds. The structure of ice is open with large number of vacant spaces, therfore the density of ice is less than water.
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The low density of ice compared to water is due to[1997]a)hydrogen-bon...
Explanation:
The low density of ice compared to water is indeed due to hydrogen-bonding interactions. This can be explained by considering the molecular structure and behavior of water molecules.
Hydrogen Bonding:
- Hydrogen bonding is a special type of intermolecular force that occurs between a hydrogen atom bonded to a highly electronegative atom (such as oxygen or nitrogen) and an electronegative atom in a neighboring molecule.
- In the case of water, each water molecule consists of two hydrogen atoms covalently bonded to one oxygen atom, forming a bent or V-shaped structure.
- The oxygen atom in water is highly electronegative, meaning it attracts electrons more strongly than the hydrogen atoms.
- As a result, the oxygen atom carries a partial negative charge (δ-) while the hydrogen atoms carry partial positive charges (δ+).
- These partial charges create an electrostatic attraction between neighboring water molecules, leading to hydrogen bonding.
Ice vs Water:
- In the liquid state, water molecules are in constant motion and have enough thermal energy to break and reform hydrogen bonds with neighboring molecules.
- However, as water is cooled below its freezing point (0°C), the thermal energy decreases, and water molecules start to arrange themselves in a more ordered and stable structure.
- In the solid state, such as ice, the water molecules form a lattice structure held together by hydrogen bonds.
- In this lattice, each water molecule is hydrogen bonded to four neighboring water molecules, resulting in an open and hexagonal arrangement.
- This arrangement creates empty spaces or voids between the water molecules, which gives ice its characteristic low density.
- The empty spaces in the lattice structure of ice allow it to expand and occupy a larger volume compared to water, even though the same number of water molecules are present.
Conclusion:
The low density of ice compared to water is due to the arrangement of water molecules in a lattice structure held together by hydrogen bonds. These hydrogen bonds create empty spaces or voids in the lattice, leading to ice having a lower density than liquid water.
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