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According to IUPAC nomen clature sodium nitroprusside is named as [2003]
  • a)
    Sodium pentacyanonitrosyl ferrate (III)
  • b)
    Sodium nitroferrocyanide
  • c)
    Sodium nitroferrocyanide I
  • d)
    Sodium pentacyanonitrosyl ferrate (II)
Correct answer is option 'A'. Can you explain this answer?
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According to IUPAC nomen clature sodium nitroprusside is named as [200...
IUPAC name of sodium nitroprusside
Na2[Fe(CN)5NO) is sodium pentacyanoni trosyl ferrate (III) because in it NO is neutral ligand and the oxidation number of Fe is +3. Which is calculated as

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According to IUPAC nomen clature sodium nitroprusside is named as [200...
IUPAC name of sodiumnitroprusside Na2[Fe(CN)5NO] is sodium pentacyanonitrosoyl ferrate (III) because in it NO is neutral ligand.
Hence 2×O.N. of Na + O.N. of Fe + 5×O.N. of CN       1×O.N. of NO = 02×(+1) + O.N. of Fe + 5 ×(–1) +1×0 = 0
O.N. of Fe = 5 – 2 = +3,  
Hence ferrate (III)
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According to IUPAC nomen clature sodium nitroprusside is named as [200...
Answer:
Sodium nitroprusside is a coordination compound that contains the following ions:
- Sodium ion (Na+)
- Nitroprusside ion (Fe(CN)5NO2-)

To name this compound according to IUPAC nomenclature, we need to follow certain rules:

1. Identify the central metal atom or ion:
In this case, the central metal atom is iron (Fe).

2. Determine the oxidation state of the central metal atom:
The oxidation state of iron in the nitroprusside ion is +3.

3. Write the name of the central metal atom with its oxidation state:
The name of the central metal atom is "ferrate (III)".

4. Identify the ligands attached to the central metal atom:
The ligands in sodium nitroprusside are:
- Cyanide ion (CN-)
- Nitrosyl group (NO)

5. Write the names of the ligands:
- Cyanide ion is named as "cyanido".
- Nitrosyl group is named as "nitrosyl".

6. Write the ligands in alphabetical order, except for prefixes:
The ligands in sodium nitroprusside, in alphabetical order, are:
- Cyanide ion
- Nitrosyl group

7. Write the ligands along with the central metal atom:
The ligands, along with the central metal atom, are:
- Cyanide ion: pentacyano
- Nitrosyl group: nitro

8. Combine the ligands with the central metal atom:
Combining the ligands with the central metal atom, we get:
- Cyanide ion: pentacyanoferrate (III)
- Nitrosyl group: nitroferrate (III)

9. Write the overall name of the compound:
The overall name of the compound is:
- Sodium pentacyanonitrosyl ferrate (III)

Therefore, according to IUPAC nomenclature, sodium nitroprusside is named as "Sodium pentacyanonitrosyl ferrate (III)".
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According to IUPAC nomen clature sodium nitroprusside is named as [2003]a)Sodium pentacyanonitrosyl ferrate (III)b)Sodium nitroferrocyanidec)Sodium nitroferrocyanide Id)Sodium pentacyanonitrosyl ferrate (II)Correct answer is option 'A'. Can you explain this answer?
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According to IUPAC nomen clature sodium nitroprusside is named as [2003]a)Sodium pentacyanonitrosyl ferrate (III)b)Sodium nitroferrocyanidec)Sodium nitroferrocyanide Id)Sodium pentacyanonitrosyl ferrate (II)Correct answer is option 'A'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about According to IUPAC nomen clature sodium nitroprusside is named as [2003]a)Sodium pentacyanonitrosyl ferrate (III)b)Sodium nitroferrocyanidec)Sodium nitroferrocyanide Id)Sodium pentacyanonitrosyl ferrate (II)Correct answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for According to IUPAC nomen clature sodium nitroprusside is named as [2003]a)Sodium pentacyanonitrosyl ferrate (III)b)Sodium nitroferrocyanidec)Sodium nitroferrocyanide Id)Sodium pentacyanonitrosyl ferrate (II)Correct answer is option 'A'. Can you explain this answer?.
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