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Which of the following oxidation states is the most common among the lanthanoids? [2010]
  • a)
    3
  • b)
    4
  • c)
    2
  • d)
    5
Correct answer is option 'A'. Can you explain this answer?
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Which of the following oxidation states is the most common among the l...
Correct choice : (a)
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Which of the following oxidation states is the most common among the l...
The most common oxidation state among the lanthanoids is +3.

Explanation:

Lanthanoids, also known as lanthanides, are a group of 15 elements that include elements from lanthanum (La) to lutetium (Lu) in the periodic table. These elements are known for their similar electronic configurations, which result in similar chemical properties.

Key Point: Lanthanoids have a tendency to lose three electrons to achieve a stable electron configuration.

Reasoning:

1. Electronic Configuration:
The electronic configuration of lanthanoids is characterized by the filling of the 4f orbitals. The general electronic configuration for the lanthanoids is [Xe]4f^n6s^2, where n represents the number of electrons in the 4f orbital.

2. Stability:
The +3 oxidation state is the most stable oxidation state for lanthanoids due to the stability of the completely filled 4f orbitals. In the +3 oxidation state, the lanthanoids lose three electrons from their outermost 6s and 4f orbitals, resulting in a completely filled 4f orbital.

3. Atomic Size:
The lanthanoids have relatively similar atomic sizes, and as a result, they have similar tendencies to lose three electrons to achieve a stable electron configuration. This is because the loss of three electrons allows the lanthanoids to achieve a more stable electronic configuration and a lower energy state.

4. Ionic Radii:
The ionic radii of the lanthanoids decrease slightly across the series, but the change is not significant enough to affect the most common oxidation state. The trend in ionic radii is mainly due to the increasing nuclear charge and effective nuclear charge across the period.

Conclusion:

In conclusion, the most common oxidation state among the lanthanoids is +3. This is because the lanthanoids have a tendency to lose three electrons to achieve a stable electronic configuration, and the +3 oxidation state allows them to achieve this stability.
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Community Answer
Which of the following oxidation states is the most common among the l...
Because it is present in the 3rd group of the periodic table
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