Introduction:
Adsorption is the process in which molecules or atoms from a gas, liquid, or dissolved solid adhere to a surface. It involves the interaction between the adsorbate (the substance being adsorbed) and the adsorbent (the surface on which adsorption occurs). The bonding forces in adsorption can be classified into different categories based on their nature.

Explanation:
The nature of bonding forces in adsorption can be purely physical, purely chemical, or a combination of both chemical and physical forces. Let's discuss each of these options in detail:

a) Purely physical such as Van der Waals forces:
Van der Waals forces are weak intermolecular forces that exist between all molecules, regardless of their polarity. These forces arise from the fluctuating electron distribution in molecules, leading to temporary dipoles. These temporary dipoles induce dipoles in neighboring molecules, resulting in attractive forces between them. Van der Waals forces play a significant role in physical adsorption or physisorption. In physisorption, the adsorbate is held onto the surface of the adsorbent through weak Van der Waals forces.

b) Purely chemical:
Purely chemical bonding forces in adsorption involve the formation of chemical bonds between the adsorbate and the adsorbent. This type of adsorption is known as chemisorption. Chemisorption is a stronger and more specific form of adsorption compared to physisorption. It involves the sharing or transfer of electrons between the adsorbate and the adsorbent, resulting in the formation of stable chemical bonds. Chemisorption is typically observed when the adsorbate and adsorbent have a high affinity for each other and can undergo chemical reactions.

c) Both chemical and physical always:
The correct answer to the given question is option 'C', which states that the bonding forces in adsorption are both chemical and physical. This is because adsorption can involve a combination of Van der Waals forces and chemical bonding forces, depending on the specific adsorbate-adsorbent system and conditions. In many cases, physical adsorption may occur initially, followed by chemical adsorption as the adsorbate molecules get closer to the adsorbent surface. The physical forces facilitate the initial adsorption, while the chemical forces lead to stronger and more stable bonding.

Conclusion:
In conclusion, the bonding forces in adsorption can be both chemical and physical. Van der Waals forces play a role in physical adsorption, while chemisorption involves the formation of chemical bonds between the adsorbate and the adsorbent. The specific nature of the bonding forces depends on the interactions between the adsorbate and the adsorbent, and it can vary in different adsorption systems.