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Why aldehyde is more reactive than ketone?
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Why aldehyde is more reactive than ketone?
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Aldehydes are more reactive towards nucleophillic addition reactions. Can be explained on the basis of 2 factors :

1.inductive effect : since carbonyl group of ketones is connected to alkyl groups,and alkyl group has electron donating inductive effect,it increases electron density on carbon of carbonyl group in ketones,making it less electrophilic. Therefore nucleophiles fail to attack ketones'carbonyl grp. And hence aldehydes are more reactive.
2. Steric effect: alkyl groups present on ketones provide steric hindrance to the attack of nucleophile. This is not the case with aldehydes.
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Why aldehyde is more reactive than ketone?
Reactivity of Aldehydes vs. Ketones
Aldehydes are generally more reactive than ketones due to several structural and electronic factors. Here’s a detailed breakdown of the reasons:
1. Electronic Effects
- Carbonyl Group Polarization: In aldehydes, the carbonyl carbon (C=O) is bonded to one alkyl group and a hydrogen atom. The presence of the electronegative oxygen creates a partial positive charge on the carbonyl carbon, making it more susceptible to nucleophilic attack.
- Steric Hindrance: Ketones have two alkyl groups attached to the carbonyl carbon, which results in greater steric hindrance. This bulkiness can impede the approach of nucleophiles, reducing the rate of reaction compared to aldehydes.
2. Stability of Intermediates
- Formation of Tetrahedral Intermediates: When nucleophiles attack the carbonyl carbon, they form a tetrahedral intermediate. In aldehydes, this intermediate is more stable due to less steric hindrance, facilitating further reactions.
- Less Stable Ketone Intermediates: Ketone intermediates are often less stable due to increased steric strain from two alkyl groups, making the reaction pathway slower.
3. Reactivity in Different Reactions
- Nucleophilic Addition: Aldehydes are more reactive in nucleophilic addition reactions compared to ketones due to the reasons stated above.
- Oxidation and Reduction: Aldehydes can be easily oxidized to carboxylic acids, while ketones are more resistant to oxidation, further illustrating the inherent reactivity difference.
In summary, the combination of electronic factors, steric hindrance, and stability of reaction intermediates makes aldehydes more reactive than ketones.
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Why aldehyde is more reactive than ketone?
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