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Assertion (A): Linear polymers are rigid at low temperatures but soft andmouldable at elevated temperatures.  
Reason (R): Linear polymers are thermo-setting.
  • a)
    Both A and R are individually true and R is the correct explanation of A
  • b)
    Both A and R are individually true but R is not the correct explanation of A
  • c)
    A is true but R is false
  • d)
    A is false but R is true
Correct answer is option 'C'. Can you explain this answer?
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Assertion (A): Linear polymers are rigid at low temperatures but soft ...
Ans. (c) A is true but R is false
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Assertion (A): Linear polymers are rigid at low temperatures but soft ...
Linear Polymers - Assertion and Reasoning

Assertion (A): Linear polymers are rigid at low temperatures but soft and mouldable at elevated temperatures.
Reason (R): Linear polymers are thermo-setting.

Explanation:

• Linear polymers are made up of long chains of repeating units called monomers.
• Linear polymers are flexible and rubbery at room temperature.
• When the temperature is increased, the kinetic energy of the polymer chains increases, and they start to move more freely and become soft and mouldable.
• At low temperatures, the polymer chains are held together by strong intermolecular forces, making the material rigid.
• Linear polymers are not thermo-setting, as they do not undergo irreversible chemical changes when heated.
• Thermo-setting polymers are those that undergo irreversible chemical changes when heated and become hard and rigid.
• Examples of thermo-setting polymers are Bakelite, melamine, and epoxy resins.
• Therefore, the assertion (A) is true, but the reason (R) is false.
• Hence, option (C) is the correct answer.

Conclusion:

• Linear polymers are flexible and rubbery at room temperature.
• They become soft and mouldable at elevated temperatures due to increased kinetic energy of the polymer chains.
• Linear polymers are not thermo-setting as they do not undergo irreversible chemical changes when heated.
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Assertion (A): Linear polymers are rigid at low temperatures but soft ...
C
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Assertion (A): Linear polymers are rigid at low temperatures but soft andmouldable at elevated temperatures.Reason (R): Linear polymers are thermo-setting.a)Both A and R are individually true and R is the correct explanation of Ab)Both A and R are individually true but R is not the correct explanation of Ac)A is true but R is falsed)A is false but R is trueCorrect answer is option 'C'. Can you explain this answer?
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