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Why oxalic acid is more acidic than acetic acid?
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Why oxalic acid is more acidic than acetic acid?
Oxalic Acid vs Acetic Acid: A Comparison of Acidity

Introduction:
Oxalic acid (C2H2O4) and acetic acid (CH3COOH) are both organic acids, but oxalic acid is known to be more acidic than acetic acid. This can be explained by several factors, including the structure and stability of the acid molecules.

1. Molecular Structure:
One of the primary reasons for the difference in acidity between oxalic acid and acetic acid lies in their molecular structures.

Oxalic Acid:
- Oxalic acid contains two carboxylic acid groups (-COOH) in its structure.
- These two acidic groups can easily release hydrogen ions (H+) into the solution, making it a strong acid.

Acetic Acid:
- Acetic acid, on the other hand, has only one carboxylic acid group in its structure.
- It can release hydrogen ions, but not as easily as oxalic acid due to the presence of fewer acidic groups.

2. Stability of Acid Conjugate Base:
Another factor affecting the acidity of these acids is the stability of their respective conjugate bases.

Oxalic Acid:
- When oxalic acid donates a hydrogen ion, it forms the oxalate ion (C2O42-).
- The oxalate ion is highly stable due to resonance stabilization, where the negative charge is delocalized over the two oxygen atoms.
- This stability of the conjugate base allows oxalic acid to more readily donate hydrogen ions, leading to higher acidity.

Acetic Acid:
- Acetic acid donates a hydrogen ion to form the acetate ion (CH3COO-).
- The acetate ion is also stabilized, but not to the same extent as the oxalate ion.
- The stability of the conjugate base is relatively lower, resulting in lower acidity compared to oxalic acid.

3. pKa Values:
The acidity of an acid can be quantitatively measured using the pKa value. A lower pKa value indicates a stronger acid.

Oxalic Acid:
- The pKa value of the first dissociation of oxalic acid is around 1.25, which is very low.
- This indicates that oxalic acid readily donates its first hydrogen ion, making it a strong acid.

Acetic Acid:
- Acetic acid has a pKa value of around 4.76, which is higher than that of oxalic acid.
- This suggests that acetic acid is a weaker acid compared to oxalic acid.

Conclusion:
In summary, oxalic acid is more acidic than acetic acid due to its molecular structure, which contains two carboxylic acid groups, and the stability of its conjugate base. The presence of two acidic groups in oxalic acid allows for the easy release of hydrogen ions, resulting in higher acidity. Additionally, the conjugate base of oxalic acid, the oxalate ion, is highly stable due to resonance stabilization, further enhancing its acidity. On the other hand, acetic acid has only one acidic group and a less stable conjugate base, leading to lower acidity compared to oxalic acid.
Community Answer
Why oxalic acid is more acidic than acetic acid?
It has 2 carboxylic acid groups and if one H is donated being acidic, the formed carboxylate ion will be stabilized through resonance with one another electron withdrawing carboxylic acid group beside. where as in acetic acid, though it gets resonance stabilization, it has one methyl group which is electron releasing. So comparitively, oxalic acid is more acidic comparing to acetic acid
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Why oxalic acid is more acidic than acetic acid?
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