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Comprehension Type
Direction (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).
Passage I
In a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.
Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.
Q. 
In water, the order of nucleophilicity of halides is
  • a)
    I- < Br < Cl- < F-
  • b)
    F- < Cl- < Br- < I-
  • c)
    I- = Br- = Cl- = F-
  • d)
    F- = Cl- < Br- < I-
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 pa...
F- is most hydrated, least nucleophilic and I- is most polarisable, strongest nucleophile among halides in H2O.
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Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 pa...
Explanation:

Order of Nucleophilicity of Halides in Water:
- The order of nucleophilicity of halides in water is directly related to their basicity.
- The basicity of halides increases in the order I- < br-="" />< cl-="" />< />
- Therefore, the order of nucleophilicity of halides in water is F- < cl-="" />< br-="" />< />

Reasoning:
- Fluoride ion (F-) is the smallest halide ion and is the most solvated due to its high charge density.
- Iodide ion (I-) is the largest halide ion and is the least solvated due to its low charge density.
- As a result, the nucleophilicity of the halides in water follows the order F- < cl-="" />< br-="" />< />

Order of Nucleophilicity:
- F- < cl-="" />< br-="" />< />
Therefore, the correct answer to the question is option 'b) F- Cl- Br- I'.
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Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer?
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Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer?.
Solutions for Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
Here you can find the meaning of Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer?, a detailed solution for Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? has been provided alongside types of Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Comprehension TypeDirection (Q. Nos. 18-23) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).Passage IIn a SN2 reaction, solvent plays a very important role. Hydroxylic solvents like water, alcohols, carboxylic acids etc., solvate nucleophile, decreases its reactivity in the reaction.Size of donor atom of nucleophile also affect nucleophilicity. A larger donor atom is more easily polarised and less solvated, hence a stronger nucleophile. Therefore, in a given group of periodic table, nucleophilicity increases down the group. However solvation effect is more predominant than polarisability.Q.In water, the order of nucleophilicity of halides isa)I- < Br < Cl- < F-b)F-< Cl-< Br- < I-c)I-= Br-= Cl-= F-d)F-= Cl-< Br- < I-Correct answer is option 'B'. Can you explain this answer? tests, examples and also practice Class 12 tests.
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