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Observe the following reaction

Which of the following statement is true regarding solvent of the above reaction
  • a)
    In water the product is almost all benzyl naphthol
  • b)
    In DMSO (dimethyl sulfoxide) the product is almost all benzyl napthol
  • c)
    In CCl4 ether is major product
  • d)
    It cannot be decided
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Observe the following reactionWhich of the following statement is true...
In water the product is almost all benzyl naphthol. However, in DMSO (dimethyl sulfoxide) the
major product is the ether. In water the oxyanion is heavily solvated through hydrogen bonds to
water molecules and the electrophile cannot push them aside to get close to O– (this is an entropy
effect). DMSO cannot form hydrogen bonds as it has no OH bonds and does not solvate the oxyanion, which is free to attack the electrophile.
DMSO Solvent:

Water Solvent:

Hence option (a) is correct.
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Observe the following reactionWhich of the following statement is true regarding solvent of the above reactiona)In water the product is almost all benzyl naphtholb)In DMSO (dimethyl sulfoxide) the product is almost all benzyl naptholc)In CCl4 ether is major productd)It cannot be decidedCorrect answer is option 'A'. Can you explain this answer?
Question Description
Observe the following reactionWhich of the following statement is true regarding solvent of the above reactiona)In water the product is almost all benzyl naphtholb)In DMSO (dimethyl sulfoxide) the product is almost all benzyl naptholc)In CCl4 ether is major productd)It cannot be decidedCorrect answer is option 'A'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Observe the following reactionWhich of the following statement is true regarding solvent of the above reactiona)In water the product is almost all benzyl naphtholb)In DMSO (dimethyl sulfoxide) the product is almost all benzyl naptholc)In CCl4 ether is major productd)It cannot be decidedCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Observe the following reactionWhich of the following statement is true regarding solvent of the above reactiona)In water the product is almost all benzyl naphtholb)In DMSO (dimethyl sulfoxide) the product is almost all benzyl naptholc)In CCl4 ether is major productd)It cannot be decidedCorrect answer is option 'A'. Can you explain this answer?.
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