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There are four complexes of Ni. Select the complex(es) which will be attracted by magnetic field.
I. [Ni(CN)4]2- II.[NiCl4]2- III.Ni(CO)4 IV. [Ni(H2O)6]2+
  • a)
    Only I
  • b)
    Only II
  • c)
    I, II and IV
  • d)
    II and IV
Correct answer is option 'D'. Can you explain this answer?
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There are four complexes of Ni. Select the complex(es) which will be a...
Diamagnetic complexes are [Ni(CN)4]2- and Ni(CO)4.
Paramagnetic complexes are
[NiCI4]2- and [Ni(H2O)6]2+ (attracted)
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There are four complexes of Ni. Select the complex(es) which will be a...
The magnetic properties of a complex depend on the presence of unpaired electrons. If a complex has unpaired electrons, it will be attracted by a magnetic field. Let's analyze each complex individually to determine which ones have unpaired electrons and will be attracted by a magnetic field.

I. [Ni(CN)4]2-
This complex has a coordination number of 4, meaning that it forms four bonds with the central Ni atom. The cyanide ligands (CN-) are strong-field ligands that cause pairing of the electrons in the 3d orbitals of Ni. As a result, this complex does not have any unpaired electrons and will not be attracted by a magnetic field.

II. [NiCl4]2-
Similar to the first complex, this complex also has a coordination number of 4. The chloride ligands (Cl-) are weak-field ligands that do not cause significant pairing of the electrons in the 3d orbitals of Ni. Therefore, this complex has unpaired electrons and will be attracted by a magnetic field.

III. Ni(CO)4
This complex has a coordination number of 4 and consists of four carbon monoxide (CO) ligands. CO is a strong-field ligand that causes pairing of the electrons in the 3d orbitals of Ni. Consequently, this complex does not have any unpaired electrons and will not be attracted by a magnetic field.

IV. [Ni(H2O)6]2
This complex has a coordination number of 6 and consists of six water (H2O) ligands. Water is a weak-field ligand that does not cause significant pairing of the electrons in the 3d orbitals of Ni. Therefore, this complex has unpaired electrons and will be attracted by a magnetic field.

Based on the analysis above, complexes II and IV have unpaired electrons and will be attracted by a magnetic field. Hence, the correct answer is option 'D' - II and IV.
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Read the following text and answer the following questions on the basis of the same:Super magnet The term super magnet is a broad term and encompasses several families of rare-earth magnets that include seventeen elements in the periodic table; namely scandium, yttrium, and the fifteen lanthanides. These elements can be magnetized, but have Curie temperatures below room temperature. This means that in their pure form, their magnetism only appears at low temperatures. However, when they form compounds with transition metals such as iron, nickel, cobalt, etc. Curie temperature rises well above room temperature and they can be used effectively at higher temperatures as well. The main advantage they have over conventional magnets is that their greater strength allows for smaller, lighter magnets to be used. Super magnets are of two categories: (i) Neodymium magnet: These are made from an alloy of neodymium, iron, and boron. This material is currently the strongest known type of permanent magnet. It is typically used in the construction of head actuators in computer hard drives and has many electronic applications, such as electric motors, appliances, and magnetic resonance imaging (MRI). (ii) Samarium-cobalt magnet: These are made from an alloy of samarium and cobalt. This second strongest type of rare Earth magnet is also used in electronic motors, turbo-machinery, and because of its high temperature range tolerance may also have many applications for space travel, such as cryogenics and heat resistant machinery. Rare-earth magnets are extremely brittle and also vulnerable to corrosion, so they are usually plated or coated to protect them from breaking, chipping, or crumbling into powder. Since super magnets are about 10 times stronger than ordinary magnets, safe distance should be maintained otherwise these may damage mechanical watch, CRT monitor, pacemaker, credit cards, magnetically stored media etc. These types of magnets are hazardous for health also. The greater force exerted by rare-earth magnets creates hazards that are not seen with other types of magnet. Magnets larger than a few centimeters are strong enough to cause injuries to body parts pinched between two magnets or a magnet and a metal surface, even causing broken bones. Neodymium permanent magnets lose their magnetism 5% every 100 years. So, in the truest sense Neodymium magnets may be considered as a permanent magnet.Super magnets are about _____ time stronger than ordinary magnets.

Read the following text and answer the following questions on the basis of the same:Super magnetThe term super magnet is a broad term and encompasses several families of rare-earth magnets that include seventeen elements in the periodic table; namely scandium, yttrium, and the fifteen lanthanides. These elements can be magnetized, but have Curie temperatures below room temperature. This means that in their pure form, their magnetism only appears at low temperatures. However, when they form compounds with transition metals such as iron, nickel, cobalt, etc. Curie temperature rises well above room temperature and they can be used effectively at higher temperatures as well. The main advantage they have over conventional magnets is that their greater strength allows for smaller, lighter magnets to be used. Super magnets are of two categories: (i) N eodymium magnet: These are made from an alloy of neodymium, iron, and boron. This material is currently the strongest known type of permanent magnet. It is typically used in the construction of head actuators in computer hard drives and has many electronic applications, such as electric motors, appliances, and magnetic resonance imaging (MRI). (ii) Samarium-cobalt magnet: These are made from an alloy of samarium and cobalt. This second strongest type of rare Earth magnet is also used in electronic motors, turbo-machinery, and because of its high temperature range tolerance may also have many applications for space travel, such as cryogenics and heat resistant machinery. Rare-earth magnets are extremely brittle and also vulnerable to corrosion, so they are usually plated or coated to protect them from breaking, chipping, or crumbling into powder. Since super magnets are about 10 times stronger than ordinary magnets, safe distance should be maintained otherwise these may damage mechanical watch, CRT monitor, pacemaker, credit cards, magnetically stored media etc.These types of magnets are hazardous for health also. The greater force exerted by rare-earth magnets creates hazards that are not seen with other types of magnet. Magnets larger than a few centimeters are strong enough to cause injuries to body parts pinched between two magnets or a magnet and a metal surface, even causing broken bones. Neodymium permanent magnets lose their magnetism 5% every 100 years. So, in the truest sense Neodymium magnets may be considered as a permanent magnet.Curie point of pure rare Earth elements is

There are four complexes of Ni. Select the complex(es) which will be attracted by magnetic field.I.[Ni(CN)4]2- II.[NiCl4]2- III.Ni(CO)4IV.[Ni(H2O)6]2+a)Only Ib)Only IIc)I, II and IVd)II and IVCorrect answer is option 'D'. Can you explain this answer?
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