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One desires to prepare a positively charged solution of silver iodide. This can be achieved by
  • a)
    Adding a little AgNO3 solution to KI solution in slight excess
  • b)
    Adding a little KI solution to AgNO3 solution in slight excess
  • c)
    Mixing equal volumes of equimolar solutions of AgNO3 and KI
  • d)
    None of these
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
One desires to prepare a positively charged solution of silver iodide....
KI + AgNO3 → AgI + KNO3
AgNO3 → Ag+ + NO3
AgI(s) + Ag+ → [AgI] + Ag+.
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Most Upvoted Answer
One desires to prepare a positively charged solution of silver iodide....
Answer:

To prepare a positively charged solution of silver iodide, we need to consider the solubility and dissociation of the compounds involved.

Solubility and Dissociation:
- AgNO3 (silver nitrate) is a soluble compound that dissociates into Ag+ and NO3- ions.
- KI (potassium iodide) is also a soluble compound that dissociates into K+ and I- ions.
- AgI (silver iodide) is a sparingly soluble compound that dissociates into Ag+ and I- ions.

Formation of Positively Charged Solution:
In order to prepare a positively charged solution of silver iodide, we need to have an excess of Ag+ ions in the solution. This can be achieved by adding a little KI solution to AgNO3 solution in slight excess.

Explanation of Options:
a) Adding a little AgNO3 solution to KI solution in slight excess:
- This option would result in the formation of AgI, but it would not ensure the presence of excess Ag+ ions. Therefore, it does not fulfill the requirement of preparing a positively charged solution of silver iodide.

b) Adding a little KI solution to AgNO3 solution in slight excess:
- This option is correct because the addition of KI solution to AgNO3 solution in slight excess ensures the presence of excess Ag+ ions. This excess of Ag+ ions will combine with the I- ions from KI to form AgI, resulting in a positively charged solution.

c) Mixing equal volumes of equimolar solutions of AgNO3 and KI:
- This option does not fulfill the requirement of having an excess of Ag+ ions. The equal volumes of equimolar solutions would result in the formation of AgI, but it would not provide the desired positively charged solution.

d) None of these:
- This option is incorrect as option B is the correct answer.

Therefore, the correct answer is option B: Adding a little KI solution to AgNO3 solution in slight excess. This method ensures the presence of excess Ag+ ions, leading to the formation of a positively charged solution of silver iodide.
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One desires to prepare a positively charged solution of silver iodide. This can be achieved bya)Adding a little AgNO3solution to KI solution in slight excessb)Adding a little KI solution to AgNO3solution in slight excessc)Mixing equal volumes of equimolar solutions of AgNO3and KId)None of theseCorrect answer is option 'B'. Can you explain this answer?
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