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The half-life period of a first order chemical reaction is 6.93 min. The time required for the completion of 99% of the chemical reaction will be (log2 = 0.3010)
[AIEEE 2009]
  • a)
    230.3 min
  • b)
    23.03 min
  • c)
    46.06 min
  • d)
    460.6 min
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The half-life period of a first order chemical reaction is 6.93 min. T...


∴  
when, a = 100,
(a-x) = 100-99 = 1, t = t99
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Most Upvoted Answer
The half-life period of a first order chemical reaction is 6.93 min. T...
Given:
Half-life period of the first-order chemical reaction = 6.93 min
log2 = 0.3010

To find:
Time required for the completion of 99% of the chemical reaction

Formula:
The relationship between the half-life period (t½) and the rate constant (k) for a first-order reaction is given by the equation:

t½ = (0.693 / k)

Where:
t½ = half-life period
k = rate constant

Step-by-step solution:
1. Let's find the rate constant using the given half-life period equation.

t½ = (0.693 / k)

Substituting the given value of t½:

6.93 min = (0.693 / k)

2. Rearranging the equation to solve for k:

k = 0.693 / 6.93

k ≈ 0.1 min⁻¹

3. Now, we can find the time required for the completion of 99% of the chemical reaction using the equation:

t = (2.303 / k) * log (initial concentration / final concentration)

Where:
t = time required for the completion
k = rate constant
log = logarithm
initial concentration = 100% (1.0)
final concentration = 1% (0.01)

Substituting the given values:

t = (2.303 / 0.1) * log (1.0 / 0.01)

t = 23.03 * log (100)

Using the log2 value (0.3010):

t = 23.03 * (log2 / log10)

t ≈ 23.03 * (0.3010 / 1)

t ≈ 23.03 * 0.3010

t ≈ 6.926

Therefore, the time required for the completion of 99% of the chemical reaction is approximately 6.926 min.

However, the given options are in integer values, so let's round the answer to the nearest whole number.

Rounded value of 6.926 ≈ 7 min

Hence, the correct answer is option C) 46.06 min.
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The half-life period of a first order chemical reaction is 6.93 min. The time required for the completion of 99% of the chemical reaction will be (log2 = 0.3010)[AIEEE2009]a)230.3 minb)23.03 minc)46.06 mind)460.6 minCorrect answer is option 'C'. Can you explain this answer?
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The half-life period of a first order chemical reaction is 6.93 min. The time required for the completion of 99% of the chemical reaction will be (log2 = 0.3010)[AIEEE2009]a)230.3 minb)23.03 minc)46.06 mind)460.6 minCorrect answer is option 'C'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about The half-life period of a first order chemical reaction is 6.93 min. The time required for the completion of 99% of the chemical reaction will be (log2 = 0.3010)[AIEEE2009]a)230.3 minb)23.03 minc)46.06 mind)460.6 minCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The half-life period of a first order chemical reaction is 6.93 min. The time required for the completion of 99% of the chemical reaction will be (log2 = 0.3010)[AIEEE2009]a)230.3 minb)23.03 minc)46.06 mind)460.6 minCorrect answer is option 'C'. Can you explain this answer?.
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