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A 5% solution of cane sugar (molar mass = 342 g mol-1) is isotonic with 1 % of a solution of an unknown non-electrolyte solute at 300 K. The molar mass of unknown solute is (in g mol-1)
[Aieee 2011]
  • a)
     136.2
  • b)
    171.2
  • c)
    68.4
  • d)
    34.2
Correct answer is option 'C'. Can you explain this answer?
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Isotonic Solutions and Colligative Properties:

An isotonic solution is a solution that has the same osmotic pressure as another solution. In other words, it is a solution in which the concentration of solute particles is the same as that of another solution. The osmotic pressure of a solution depends on the number of solute particles, rather than their chemical nature. This property is known as a colligative property.

The formula to calculate the osmotic pressure of a solution is:

π = (n/V)RT

Where:
π is the osmotic pressure
n/V is the concentration of solute particles in moles per liter (mol/L)
R is the ideal gas constant (0.0821 L·atm/(mol·K))
T is the temperature in Kelvin (K)

Isotonicity between Cane Sugar and Unknown Solute:

Given that the 5% cane sugar solution is isotonic with a 1% solution of the unknown solute, we can assume that the osmotic pressure of both solutions is the same. Therefore, we can equate the osmotic pressure equations for both solutions:

For the cane sugar solution:
π1 = (n1/V1)RT

For the unknown solute solution:
π2 = (n2/V2)RT

Since the osmotic pressures are the same, we can write:

(n1/V1)RT = (n2/V2)RT

Simplifying, we get:

(n1/V1) = (n2/V2)

Since the molar mass of cane sugar (M1) is given as 342 g/mol, and the concentration of the cane sugar solution is 5%, we can write:

(n1/V1) = (0.05/M1)

Similarly, for the unknown solute, let the molar mass be M2. The concentration of the unknown solute solution is given as 1%, so we can write:

(n2/V2) = (0.01/M2)

Equating these expressions, we have:

(0.05/M1) = (0.01/M2)

Solving for M2, we get:

M2 = (0.01/M1) * (M2/0.05)

M2 = (0.01/0.05) * M1

M2 = 0.2 * M1

Substituting the molar mass of cane sugar (M1 = 342 g/mol), we get:

M2 = 0.2 * 342

M2 = 68.4 g/mol

Therefore, the molar mass of the unknown solute is 68.4 g/mol, which corresponds to option 'C'.
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A 5% solution of cane sugar (molar mass = 342 g mol-1) is isotonic with 1 % of a solution of an unknown non-electrolyte solute at 300 K. The molar mass of unknown solute is (in g mol-1)[Aieee 2011]a)136.2b)171.2c)68.4d)34.2Correct answer is option 'C'. Can you explain this answer?
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