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Metallic gold crystallises in a fee lattice. The length (a) of the cubic unit cell is 407 pm. Atomic mass of gold is 197 amu.
Q.
Closest distance between gold atoms is
  • a)
    287.8pm
  • b)
    407pm
  • c)
    203.5pm
  • d)
    235pm
Correct answer is option 'A'. Can you explain this answer?
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Metallic gold crystallises in a fee lattice. The length (a) of the cub...
(a)
Closest distance between two gold atoms is half of the diagonal.
Note There are total of 12 nearest neighbours (six along diagonal and six along the edges],
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Metallic gold crystallises in a fee lattice. The length (a) of the cub...
Given:
Length of edge of unit cell, a = 407 pm
Atomic mass of gold, M = 197 amu

Density of Gold:
Density of gold can be calculated using the formula:
Density = (mass of unit cell)/(volume of unit cell)

Mass of unit cell:
Mass of unit cell can be calculated as the product of the number of atoms in the unit cell and the mass of each atom.
The given crystal structure of gold is face-centered cubic (FCC). In FCC, there are 4 atoms per unit cell.
Therefore, mass of unit cell = 4 × atomic mass of gold

Mass of unit cell = 4 × 197 amu
Mass of unit cell = 788 amu

Volume of unit cell:
Volume of unit cell can be calculated using the formula:
Volume of unit cell = a^3
where a is the length of the edge of the unit cell.

Substituting the given values, we get:
Volume of unit cell = (407 pm)^3
Volume of unit cell = 68.06 × 10^-24 cm^3

Converting pm to cm, we get:
Volume of unit cell = 68.06 × 10^-24 cm^3

Substituting the values of mass and volume in the formula for density, we get:
Density = (mass of unit cell)/(volume of unit cell)

Density = 788 amu / 68.06 × 10^-24 cm^3

Converting amu to g and cm^3 to m^3, we get:
Density = (788 × 1.66 × 10^-27 kg) / (68.06 × 10^-24 m^3)
Density = 19.30 g/cm^3

Therefore, the density of gold is 19.30 g/cm^3.

Atomic Radius of Gold:
The atomic radius of gold can be calculated using the formula:
Volume of an atom = (4/3)πr^3

where r is the atomic radius.

Volume of an atom:
The volume of an atom in FCC can be calculated as:
Volume of an atom = (1/4) × (volume of unit cell/number of atoms in unit cell)

Substituting the given values, we get:
Volume of an atom = (1/4) × [(407 pm)^3 / 4]
Volume of an atom = 6.76 × 10^-23 cm^3

Converting pm to cm, we get:
Volume of an atom = 6.76 × 10^-23 cm^3

Substituting the value of volume in the formula for atomic radius, we get:
Volume of an atom = (4/3)πr^3

6.76 × 10^-23 cm^3 = (4/3) × π × r^3

Solving for r, we get:
r = [(3 × 6.76 × 10^-23 cm^3)/(4π)]^(1/3)

r = 1.439 Å
r = 143.9 pm

Therefore, the atomic radius of gold is 143.9 pm.
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Metallic gold crystallises in a fee lattice. The length (a) of the cubic unit cell is 407 pm. Atomic mass of gold is 197 amu.Q.Closest distance between gold atoms isa)287.8pmb)407pmc)203.5pmd)235pmCorrect answer is option 'A'. Can you explain this answer?
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Metallic gold crystallises in a fee lattice. The length (a) of the cubic unit cell is 407 pm. Atomic mass of gold is 197 amu.Q.Closest distance between gold atoms isa)287.8pmb)407pmc)203.5pmd)235pmCorrect answer is option 'A'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Metallic gold crystallises in a fee lattice. The length (a) of the cubic unit cell is 407 pm. Atomic mass of gold is 197 amu.Q.Closest distance between gold atoms isa)287.8pmb)407pmc)203.5pmd)235pmCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Metallic gold crystallises in a fee lattice. The length (a) of the cubic unit cell is 407 pm. Atomic mass of gold is 197 amu.Q.Closest distance between gold atoms isa)287.8pmb)407pmc)203.5pmd)235pmCorrect answer is option 'A'. Can you explain this answer?.
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