Transition elements having more tendency to form complex than represen...
Availability of d-orbitals for bonding:
Transition elements have d-orbitals available for bonding, which allows them to form complexes. In contrast, representative elements (s and p-block elements) do not have d-orbitals available for bonding. The d-orbitals in transition elements are at a higher energy level and have a greater spatial extent compared to the s and p-orbitals. This provides transition elements with more opportunities for bonding, as the d-orbitals can accommodate additional electrons and form complex structures.
Formation of complexes:
Complexes are compounds in which a central metal ion is surrounded by ligands (atoms, ions, or molecules) that donate electrons to the metal ion. The d-orbitals in transition elements can accept electron pairs from the ligands, forming coordinate bonds. These coordinate bonds result in the formation of complex structures.
Variable oxidation states:
Transition elements are known for their ability to exhibit multiple oxidation states. This is due to the availability of d-orbitals for bonding. The presence of d-orbitals allows transition elements to have a greater range of electron configurations, leading to different oxidation states. In contrast, representative elements have a more limited range of oxidation states due to the absence of d-orbitals.
F-orbitals not available for bonding:
The statement that f-orbitals are available for bonding is incorrect. F-orbitals are part of the inner transition elements, which are not involved in the formation of complexes. The inner transition elements, also known as the f-block elements, have their f-orbitals filled with electrons and do not participate in bonding to a significant extent.
In conclusion, the availability of d-orbitals for bonding is the main reason why transition elements have a greater tendency to form complexes compared to representative elements. The d-orbitals allow for the formation of coordinate bonds with ligands, resulting in the formation of complex structures. The variable oxidation states exhibited by transition elements are also a consequence of the availability of d-orbitals.