JEE Exam  >  JEE Questions  >  The reactivity of compound Z with different h... Start Learning for Free
The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)
The observed pattern of electrophilic substitution can be explained by
  • a)
    The steric effect of the halogen
  • b)
    The steric effect of the tert-butyl group
  • c)
    The electronic effect of the phenolic group
  • d)
    The electronic effect of the tert-butyl group
Correct answer is option 'A,B,C'. Can you explain this answer?
Verified Answer
The reactivity of compound Z with different halogens under appropriate...
—OH group is strongly activating and o, p-directing due to +M effect. Thus positions a, b and c are the sites for attack by an electrophile. However, sites b and c are not preferred by bulky electrophile due to steric crowding. Thus more bulky electrophile (like I2) can attack only site a, which is least sterically hindered, a bit smaller electrophile (Br2) can attack at sites a and also b (relatively less sterically hindered site) and the smallest electrophile (Cl2) can attack all the three sites, viz., a, b and c (most sterically hindered site).
View all questions of this test
Explore Courses for JEE exam

Similar JEE Doubts

Can you explain the answer of this question below:On the basis of aromaticity, there are three types of compounds i.e. aromatic, non-aromatic and antiaromatic.The increasing order of stability of these compounds are is under:Anti-aromatic compound non-aromatic compound aromatic compounds. Compounds to be aromaticfollow the following conditions (according to valence bond theory)(i) The compounds must be be cyclic in structure having (4n + 2) e, where n = Hckels number = 0, 1,2, 3 et.c(ii) The each atoms of the cyclic structure must have unhybridised p-orbital i.e. the atoms of thecompounds have unhybridised p-orbital i.e. usually have sp2 hybrid or planar.(iii) There must be a ring current of electrons in the ring or cyclic structure i.e. cyclic structure mustundergo resonance .Compounds to be anti-aromatic, it must have 4ne where n = 1, 2 and it must be planar and undergoresonance. Non-aromatic compounds the name itself spells that compounds must be non-planarirrespective of number of electrons. Either it has 4ne or (4n + 2) electrons it does not matter.The rate of reaction of any aromatic compounds depends upon the following factors:(i) Electron density(ii) stability of carbocation producedHigher the amount of electron density of the ring, higher will be its rate towards aromatic electrophilicsubstitution and vice-versa. Similarly, higher will be the stability of the produced carbocation after theattack of electrophile, higher will be its rate towards aromatic electrophilic substitution. There is a greateffect of kinetic labelling on the rate of aromatic electrophilic substitution. As we known that higher theatomic weight or, molecualr weight, higher will be the van der Waals force of attraction or, bond energy.Since there will be effect of kienetic labelling if the 2nd step of the reaction will be the slow step, (r.d.s.)otherwise there will be no effect of kinetic labelling.Q. Which of the following is correct order of the rate of reaction of C6H6, C6D6 and C6T6 towardsnitrations?A:C6H6 C6D6 C6T6B:C6H6 = C6D6 = C6T6C:C6H6 C6D6 = C6T6D:C6T6 C6D6 C6H6The answer is b.

On the basis of aromaticity, there are three types of compounds i.e. aromatic, non-aromatic and antiaromatic. The increasing order of stability of these compounds are is under: Anti-aromatic compound < non-aromatic compound < aromatic compounds. Compounds to be aromaticfollow the following conditions (according to valence bond theory)(i) The compounds must be be cyclic in structure having (4n + 2)π e–, where n = Hückel’s number = 0, 1, 2, 3 et.c(ii) The each atoms of the cyclic structure must have unhybridised p-orbital i.e. the atoms of the compounds have unhybridised p-orbital i.e. usually have sp2 hybrid or planar.(iii) There must be a ring current of π electrons in the ring or cyclic structure i.e. cyclic structure mustundergo resonance .Compounds to be anti-aromatic, it must have 4nπe– where n = 1, 2… and it must be planar and undergo resonance. Non-aromatic compounds the name itself spells that compounds must be non-planarirrespective of number of π electrons. Either it has 4nπe– or (4n + 2) π electrons it does not matter.The rate of reaction of any aromatic compounds depends upon the following factors:(i) Electron density(ii) stability of carbocation producedHigher the amount of electron density of the ring, higher will be its rate towards aromatic electrophilic substitution and vice-versa. Similarly, higher will be the stability of the produced carbocation after the attack of electrophile, higher will be its rate towards aromatic electrophilic substitution. There is a great effect of kinetic labelling on the rate of aromatic electrophilic substitution. As we known that higher the atomic weight or, molecualr weight, higher will be the van der Waal’s force of attraction or, bond energy. Since there will be effect of kienetic labelling if the 2nd step of the reaction will be the slow step, (r.d.s.) otherwise there will be no effect of kinetic labelling.Q. Which of the following is correct order of the rate of reaction of C6H6, C6D6 and C6T6 towardssulphonation?

The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer?
Question Description
The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer?.
Solutions for The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
Here you can find the meaning of The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer?, a detailed solution for The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? has been provided alongside types of The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice The reactivity of compound Z with different halogens under appropriate conditions is given below: (JEE Adv. 2014)The observed pattern of electrophilic substitution can be explained bya)The steric effect of the halogenb)The steric effect of the tert-butyl groupc)The electronic effect of the phenolic groupd)The electronic effect of the tert-butyl groupCorrect answer is option 'A,B,C'. Can you explain this answer? tests, examples and also practice JEE tests.
Explore Courses for JEE exam

Top Courses for JEE

Explore Courses
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev