NH4Cl (s) is heated in test tube. Vapours are brought in contact with ...
Explanation:
When NH4Cl (ammonium chloride) is heated, it undergoes sublimation, which means it directly changes from a solid to a gas without forming a liquid intermediate. The chemical equation for this reaction is as follows:
NH4Cl (s) → NH3 (g) + HCl (g)
The vapors produced consist of ammonia gas (NH3) and hydrogen chloride gas (HCl). When these vapors come in contact with red litmus paper, it undergoes the following color changes:
1. Change to blue: The red litmus paper turns blue when it comes in contact with the ammonia gas (NH3). This is because ammonia is a basic substance and reacts with the water present in the litmus paper to form ammonium hydroxide (NH4OH), which is alkaline in nature. This alkaline nature turns the red litmus paper blue.
2. Change back to red: After some time, the blue litmus paper turns back to red. This is because the hydrogen chloride gas (HCl) also present in the vapors reacts with the ammonium hydroxide (NH4OH) formed in the previous step. The reaction between HCl and NH4OH is as follows:
NH4OH (aq) + HCl (g) → NH4Cl (aq) + H2O (l)
The reaction between ammonium hydroxide and hydrogen chloride produces ammonium chloride (NH4Cl) and water (H2O). Ammonium chloride is acidic in nature, and it turns the blue litmus paper back to red.
Conclusion:
The change in color of the red litmus paper to blue and then back to red indicates the presence of ammonia gas (NH3) and hydrogen chloride gas (HCl) in the vapors. The initial change to blue is due to the formation of ammonium hydroxide (NH4OH) from ammonia, and the subsequent change back to red is due to the formation of ammonium chloride (NH4Cl) from the reaction between ammonium hydroxide and hydrogen chloride. The greater diffusion of ammonia gas (NH3) compared to hydrogen chloride gas (HCl) is responsible for the blue color change being observed before the red color change. Therefore, option C, "Greater diffusion of NH3 than HCl," is the correct answer.
NH4Cl (s) is heated in test tube. Vapours are brought in contact with ...
As NH3 has low molecular mass than HCl so it will diffuse faster than HCl so 1st red litmus changes to blue and then blue changes to red colour.