A white precipitate of sn(OH)4 is peptized with dilute HCl.the Sol par...
Precipitation of Sn(OH)4
When tin(IV) chloride (SnCl4) is mixed with sodium hydroxide (NaOH) solution, a white precipitate of tin(IV) hydroxide (Sn(OH)4) is formed. This precipitate is insoluble in water and exists as solid particles.
Peptization with Dilute HCl
To peptize the precipitate, dilute hydrochloric acid (HCl) is added. Peptization is the process of converting a precipitate into a colloidal suspension by breaking down the particles into smaller, dispersed particles called sol particles.
When dilute HCl is added to the white precipitate of Sn(OH)4, the following reaction occurs:
Sn(OH)4 + 2HCl → SnCl4 + 4H2O
The addition of HCl causes the precipitate to dissolve, forming tin(IV) chloride and water. As a result, the Sn(OH)4 particles are converted into tin(IV) chloride ions and hydroxide ions.
Charge on Sol Particles
The charge on the sol particles after peptization depends on the nature of the colloid and the pH of the medium. In the case of Sn(OH)4 peptized with dilute HCl, the sol particles will carry a positive charge.
The positive charge on the sol particles can be explained as follows:
1. Dissociation of HCl: Dilute HCl dissociates in water to form H+ ions and Cl- ions.
2. Formation of Tin(IV) Chloride Ions: The dissolved Sn(OH)4 reacts with the H+ ions from HCl to form tin(IV) chloride ions (SnCl4).
3. Formation of Hydroxide Ions: The hydroxide ions (OH-) from the dissociation of Sn(OH)4 combine with the excess H+ ions from HCl to form water.
As a result of these reactions, the sol particles become positively charged. The positive charge arises due to the presence of excess H+ ions surrounding the sol particles. This positive charge allows the sol particles to repel each other and remain dispersed in the medium, forming a colloidal suspension.
Conclusion
In conclusion, when a white precipitate of Sn(OH)4 is peptized with dilute HCl, the sol particles will carry a positive charge. The positive charge arises due to the presence of excess H+ ions, which allows the sol particles to remain dispersed in the medium.
A white precipitate of sn(OH)4 is peptized with dilute HCl.the Sol par...
Option a..positive charge