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The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (BD) is as follows.
(a) Show that the rate law is 
(b) The apparent first-order rate constant,    At the CB concentration of 1 × 10–5 mol dm–3, the value of kapp reaches 50% of its limiting value obtained at very high concentrations of CB. Evaluate the ratio
Correct answer is '(a) The rate of formation of BD is'. Can you explain this answer?
Most Upvoted Answer
The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (...

(a) The rate of formation of BD is
... (1)
Applying SSA on CB*,   

Therefore, (1) 
Hence proved.
(b) Given, ... (2)
At very high concentration of CB, k -1[CB] >> k 2
Therefore, (2) 
And at [CB] = 1 × 10–5,
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The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (BD) is as follows.(a) Show that the rate law is(b) The apparent first-order rate constant, At the CB concentration of 1 105 mol dm3, the value of kapp reaches 50% of its limiting value obtained at very high concentrations of CB. Evaluate the ratioCorrect answer is '(a) The rate of formation of BD is'. Can you explain this answer?
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The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (BD) is as follows.(a) Show that the rate law is(b) The apparent first-order rate constant, At the CB concentration of 1 105 mol dm3, the value of kapp reaches 50% of its limiting value obtained at very high concentrations of CB. Evaluate the ratioCorrect answer is '(a) The rate of formation of BD is'. Can you explain this answer? for IIT JAM 2024 is part of IIT JAM preparation. The Question and answers have been prepared according to the IIT JAM exam syllabus. Information about The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (BD) is as follows.(a) Show that the rate law is(b) The apparent first-order rate constant, At the CB concentration of 1 105 mol dm3, the value of kapp reaches 50% of its limiting value obtained at very high concentrations of CB. Evaluate the ratioCorrect answer is '(a) The rate of formation of BD is'. Can you explain this answer? covers all topics & solutions for IIT JAM 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The mechanism of isomerization of cyclobutene (CB) to 1, 3-butadiene (BD) is as follows.(a) Show that the rate law is(b) The apparent first-order rate constant, At the CB concentration of 1 105 mol dm3, the value of kapp reaches 50% of its limiting value obtained at very high concentrations of CB. Evaluate the ratioCorrect answer is '(a) The rate of formation of BD is'. Can you explain this answer?.
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