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50 ml of a solution containing 10-3 mol of Ag+ is mixed with 50 ml of a 0.1 M HCl solution. Howmuch [Ag+] remains in solution? Given: Ksp of AgCl = 10-10
  • a)
    2.5 X10-9M
  • b)
    2.5 X10-7M
  • c)
    2.5 X10-8M
  • d)
    2.5 X10-10M
Correct answer is option 'A'. Can you explain this answer?
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Solution:

Given, volume of solution = 50 ml

Moles of Ag in 50 ml solution = 10^-3 mol

Volume of HCl solution = 50 ml

Concentration of HCl solution = 0.1 M

AgCl(s) ⇌ Ag+ (aq) + Cl- (aq)

Initial concentration of Ag+ = 10^-3 mol/100 ml = 10^-5 M

Initial concentration of Cl- = 0.1 M/100 ml = 10^-3 M

The reaction between Ag+ and Cl- ions leads to the formation of AgCl(s), therefore, the concentration of Ag+ will decrease and Cl- will increase.

Let the concentration of Ag+ at equilibrium be x.

Ksp = [Ag+][Cl-] = 1.0 × 10^-10

10^-5 - x x

10^-3 + x x

10^-10 = x^2

x = 2.5 × 10^-6 M

Therefore, [Ag+] at equilibrium = 2.5 × 10^-6 M

The amount of Ag+ remaining in solution can be calculated as follows:

Amount of Ag+ remaining = Initial amount of Ag+ - Amount of Ag+ consumed

Initial amount of Ag+ = 10^-5 M × 50 ml = 5 × 10^-4 mol

Amount of Ag+ consumed = 2.5 × 10^-6 M × 50 ml = 1.25 × 10^-7 mol

Amount of Ag+ remaining = (5 × 10^-4 - 1.25 × 10^-7) mol = 4.99875 × 10^-4 mol

Concentration of Ag+ remaining = 4.99875 × 10^-4 mol/50 ml = 9.9975 × 10^-6 M

Therefore, [Ag+] remaining in solution = 9.9975 × 10^-6 M

Hence, the correct answer is option 'A' i.e 2.5 × 10^-9 M.
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