The coordination number and magnetic moment of the complex [Cr(C2O4)2(...
The coordination number and magnetic moment of the complex [Cr(C2O4)2(NH3)2]- can be determined by analyzing the structure and properties of the complex.
Coordination Number:
The coordination number refers to the number of ligands attached directly to the central metal ion in a complex. In the given complex [Cr(C2O4)2(NH3)2]-, we have to identify the ligands that bind to the central chromium (Cr) ion.
- The ligands attached to the central chromium ion are C2O4 (oxalate) and NH3 (ammonia).
- The formula [Cr(C2O4)2(NH3)2]- indicates that there are two C2O4 ligands and two NH3 ligands.
- Each C2O4 ligand has two oxygen atoms that can coordinate with the central chromium ion, and each NH3 ligand has one nitrogen atom.
- Therefore, the total number of ligands directly attached to the central chromium ion is four.
Hence, the coordination number of the complex [Cr(C2O4)2(NH3)2]- is 4.
Magnetic Moment:
The magnetic moment of a complex is related to the number of unpaired electrons present in the complex. To determine the magnetic moment of [Cr(C2O4)2(NH3)2]-, we need to consider the electronic configuration of the central chromium ion.
- Chromium (Cr) has an atomic number of 24, and its electronic configuration is [Ar] 3d5 4s1.
- In the given complex, the oxidation state of chromium is not specified, so we assume it to be +3 for the sake of calculation.
- When Cr3+ forms a complex, it loses three electrons from its 3d orbital, resulting in a configuration of [Ar] 3d3.
- In the 3d3 configuration, there are three unpaired electrons present.
- Each unpaired electron contributes one Bohr magneton (μB) to the magnetic moment.
- Therefore, the magnetic moment of the complex [Cr(C2O4)2(NH3)2]- is 3 μB.
In summary, the coordination number of the complex [Cr(C2O4)2(NH3)2]- is 4, and its magnetic moment is 3 μB, based on the number of ligands directly attached to the central chromium ion and the electronic configuration of the chromium ion, respectively.
The coordination number and magnetic moment of the complex [Cr(C2O4)2(...
Coordination no. 6 and magnetic moment is 3.46BM
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