Which hydride has lowest boiling point (a) H2O (b) H2Se (c) H2Te (d) H...
The boiling point of a hydride depends on several factors such as molecular weight, intermolecular forces, and polarity. Let's analyze the given hydrides to determine which one has the lowest boiling point:
(a) H2O (Water):
- Molecular weight: 18 g/mol
- Intermolecular forces: Water molecules are polar due to the electronegativity difference between hydrogen and oxygen atoms. This polarity allows for hydrogen bonding, which is a strong intermolecular force.
- Boiling point: Due to the strong hydrogen bonding, water has a relatively high boiling point of 100°C.
(b) H2Se (Hydrogen Selenide):
- Molecular weight: 80 g/mol
- Intermolecular forces: Hydrogen selenide is a polar molecule, but it has weaker intermolecular forces compared to water. It forms dipole-dipole interactions.
- Boiling point: The boiling point of H2Se is around -41°C.
(c) H2Te (Hydrogen Telluride):
- Molecular weight: 130 g/mol
- Intermolecular forces: Hydrogen telluride is also a polar molecule with dipole-dipole interactions.
- Boiling point: The boiling point of H2Te is approximately -2.2°C.
(d) H2S (Hydrogen Sulfide):
- Molecular weight: 34 g/mol
- Intermolecular forces: Hydrogen sulfide is a polar molecule that can form dipole-dipole interactions.
- Boiling point: The boiling point of H2S is -60°C.
Based on the above information, we can conclude that H2S (Hydrogen Sulfide) has the lowest boiling point among the given hydrides, with a boiling point of -60°C. This is due to its relatively low molecular weight and weaker intermolecular forces compared to the other hydrides.
Which hydride has lowest boiling point (a) H2O (b) H2Se (c) H2Te (d) H...
Even though Sulphur is more electronegative than Se or Te (so you would expect a higher dipole moment and so higher attractive forces between molecules) the size of the molecules is a bigger factor in their interactions. More energy is needed simply because the molecules of the hydrides get bigger as you go down the Group.