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Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0 kg of water, then how many grams of ethylene glycol (C2H602) must you add to get the freezing point of the solution lowered to -2.8oc ?
(AIEEE 2012)
  • a)
    72 g
  • b)
    93 g
  • c)
    39 g
  • d)
    27 g
Correct answer is option 'B'. Can you explain this answer?
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Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0...
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Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0...
Given data:
Kf for water (Kf) = 1.86 K kg mol⁻¹
Mass of water (m1) = 1.0 kg
Freezing point depression (ΔTf) = -2.8 °C
Molar mass of ethylene glycol (M2) = 62 g mol⁻¹

To find: Mass of ethylene glycol (m2) required to lower the freezing point of water to -2.8 °C

Formula used:
ΔTf = Kf x molality
Molality (m) = moles of solute (n2) / mass of solvent (m1)
Moles of solute (n2) = m2 / M2

Calculation:
From the formula, ΔTf = Kf x molality
molality (m) = n2 / m1

Substitute the given values, we get
-2.8 = 1.86 x (n2 / 1.0)
n2 = (2.8 / 1.86) = 1.50 mol

Molar mass of ethylene glycol (M2) = 62 g mol⁻¹
Mass of ethylene glycol (m2) = n2 x M2
= 1.50 x 62
= 93 g

Therefore, 93 g of ethylene glycol must be added to 1.0 kg of water to lower the freezing point to -2.8 °C. Hence, the correct answer is option (b).
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Kf for water is 1.86 K kg mol-1. If your automobile radiator holds 1.0 kg of water, then how many grams of ethylene glycol (C2H602) must you add to get the freezing point of the solution lowered to -2.8oc ?(AIEEE 2012)a)72 gb)93 gc)39 gd)27 gCorrect answer is option 'B'. Can you explain this answer?
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