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Which statement is/are correct in the following statements? (A) Allyl bromide gives S_(N) 1reaction but vinyl chloride does not. (B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction.This depends on the structure of the substrate and nature of solvent. (C) CH_(3)-CH-=CH-CH_(2) Clreacts with KCN to give mixture of two isomeric products. (D) CH_(3)-CH_(2)-O-CH_(2) Bris less reactive than tert.Butyl bromide for S_(N) 1reaction.?
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Which statement is/are correct in the following statements? (A) Allyl ...
Correctness of Statements

(A) Allyl bromide gives S_(N)1reaction but vinyl chloride does not. - This statement is correct.

(B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction. This depends on the structure of the substrate and nature of solvent. - This statement is correct.

(C) CH3-CH=CH-CH2Cl reacts with KCN to give a mixture of two isomeric products. - This statement is correct.

(D) CH3-CH2-O-CH2Br is less reactive than tert-Butyl bromide for S_(N)1 reaction. - This statement is incorrect.

Explanation

(A) Allyl bromide gives S_(N)1 reaction but vinyl chloride does not. - This is because the allyl carbocation formed during the reaction is resonance stabilized, while vinyl carbocation is not. Therefore, allyl bromide can undergo S_(N)1 reaction, while vinyl chloride cannot.

(B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction. This depends on the structure of the substrate and nature of solvent. - The reaction mechanism depends on the structure of the substrate and nature of solvent. In polar protic solvents, S_(N)1 reaction predominates, while in polar aprotic solvents, S_(N)2 reaction predominates.

(C) CH3-CH=CH-CH2Cl reacts with KCN to give a mixture of two isomeric products. - This is because the reaction can proceed through both S_(N)1 and S_(N)2 mechanisms, resulting in the formation of two isomeric products.

(D) CH3-CH2-O-CH2Br is less reactive than tert-Butyl bromide for S_(N)1 reaction. - This statement is incorrect. The tert-butyl carbocation formed during the reaction is highly stable due to steric hindrance, while the carbocation formed during the reaction of CH3-CH2-O-CH2Br is less stable. Therefore, CH3-CH2-O-CH2Br is more reactive than tert-butyl bromide for S_(N)1 reaction.
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Which statement is/are correct in the following statements? (A) Allyl bromide gives S_(N) 1reaction but vinyl chloride does not. (B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction.This depends on the structure of the substrate and nature of solvent. (C) CH_(3)-CH-=CH-CH_(2) Clreacts with KCN to give mixture of two isomeric products. (D) CH_(3)-CH_(2)-O-CH_(2) Bris less reactive than tert.Butyl bromide for S_(N) 1reaction.?
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Which statement is/are correct in the following statements? (A) Allyl bromide gives S_(N) 1reaction but vinyl chloride does not. (B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction.This depends on the structure of the substrate and nature of solvent. (C) CH_(3)-CH-=CH-CH_(2) Clreacts with KCN to give mixture of two isomeric products. (D) CH_(3)-CH_(2)-O-CH_(2) Bris less reactive than tert.Butyl bromide for S_(N) 1reaction.? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which statement is/are correct in the following statements? (A) Allyl bromide gives S_(N) 1reaction but vinyl chloride does not. (B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction.This depends on the structure of the substrate and nature of solvent. (C) CH_(3)-CH-=CH-CH_(2) Clreacts with KCN to give mixture of two isomeric products. (D) CH_(3)-CH_(2)-O-CH_(2) Bris less reactive than tert.Butyl bromide for S_(N) 1reaction.? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which statement is/are correct in the following statements? (A) Allyl bromide gives S_(N) 1reaction but vinyl chloride does not. (B) Primary alkyl halides can give S_(N)1 or S_(N)2 reaction.This depends on the structure of the substrate and nature of solvent. (C) CH_(3)-CH-=CH-CH_(2) Clreacts with KCN to give mixture of two isomeric products. (D) CH_(3)-CH_(2)-O-CH_(2) Bris less reactive than tert.Butyl bromide for S_(N) 1reaction.?.
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