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An acidified solution of potassium chromate was layered with an equal volume of amyl alcohol. When it was shaken after the addition of 1 mL of 3% H2O2, a blue alcohol layer was obtained. The blue color is due to the formation of a chromium (VI) compound 'X' . What is the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X?
    Correct answer is '4'. Can you explain this answer?
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    An acidified solution of potassium chromate was layered with an equal ...

    Here the structure of CrO5 is :-

    Here, single bonded O-atoms with Cr is = 04
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    An acidified solution of potassium chromate was layered with an equal ...
    Explanation:

    The blue color observed in the alcohol layer is due to the formation of a chromium (VI) compound, denoted as X. In order to determine the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X, we need to analyze the reaction and the structure of the compound.

    Reaction:

    The reaction involves the acidified solution of potassium chromate (K2CrO4) and amyl alcohol, followed by the addition of hydrogen peroxide (H2O2).

    Step 1: Acidification
    K2CrO4 + H+ → K+ + CrO42-

    In the presence of acid, the chromate ion (CrO42-) is converted to dichromate ion (Cr2O72-).

    Step 2: Layering with Amyl Alcohol
    The acidified potassium chromate solution is layered with an equal volume of amyl alcohol. Organic solvents like amyl alcohol are immiscible with water and can form a separate layer.

    Step 3: Addition of Hydrogen Peroxide
    1 mL of 3% hydrogen peroxide (H2O2) is added to the mixture. Hydrogen peroxide can oxidize the chromium ion from its +6 oxidation state to a higher oxidation state, resulting in the formation of a different compound.

    Formation of Chromium (VI) Compound X:

    The blue color observed in the alcohol layer indicates the formation of a chromium (VI) compound, denoted as X. The structure of X can be represented as follows:

    X: CrO5

    In the compound X, the chromium atom is bonded to five oxygen atoms. However, not all of these oxygen atoms are bonded to chromium through only single bonds.

    Determination of Oxygen Atoms Bonded to Chromium through Single Bonds:

    To determine the number of oxygen atoms bonded to chromium through only single bonds, we need to analyze the structure of compound X.

    From the structure, we can see that there are two oxygen atoms bonded to chromium through double bonds. These double bonds are represented by a double line in the structure.

    Therefore, the remaining oxygen atoms (total 5 - 2 = 3) are bonded to chromium through single bonds.

    Hence, the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X is 3.

    However, the correct answer specified in the question is '4'. This implies that there might be additional information or considerations that are not provided.
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    An acidified solution of potassium chromate was layered with an equal volume of amyl alcohol. When it was shaken after the addition of 1 mL of 3% H2O2, a blue alcohol layer was obtained. The blue color is due to the formation of a chromium (VI) compound X . What is the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X?Correct answer is '4'. Can you explain this answer?
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    An acidified solution of potassium chromate was layered with an equal volume of amyl alcohol. When it was shaken after the addition of 1 mL of 3% H2O2, a blue alcohol layer was obtained. The blue color is due to the formation of a chromium (VI) compound X . What is the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X?Correct answer is '4'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about An acidified solution of potassium chromate was layered with an equal volume of amyl alcohol. When it was shaken after the addition of 1 mL of 3% H2O2, a blue alcohol layer was obtained. The blue color is due to the formation of a chromium (VI) compound X . What is the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X?Correct answer is '4'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for An acidified solution of potassium chromate was layered with an equal volume of amyl alcohol. When it was shaken after the addition of 1 mL of 3% H2O2, a blue alcohol layer was obtained. The blue color is due to the formation of a chromium (VI) compound X . What is the number of oxygen atoms bonded to chromium through only single bonds in a molecule of X?Correct answer is '4'. Can you explain this answer?.
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