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Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.


Assertion : Acetanilide is less basic than aniline.


Reason : Acetylation of aniline results in decrease of electron density on nitrogen.

  • a)
    If both the Assertion and Reason are incorrect.

  • b)
    If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.

  • c)
    If the Assertion is correct but Reason is incorrect.

  • d)
    If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.

Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Directions: These questions consist of two statements, each printed as...
Assertion: Acetanilide is less basic than aniline.
Reason: Acetylation of aniline results in a decrease in electron density on nitrogen.

Explanation:

Assertion: Acetanilide is less basic than aniline.
The assertion states that acetanilide is less basic than aniline. Basicity refers to the ability of a molecule or ion to accept a proton (H+) or donate a pair of electrons. In this case, we are comparing the basicity of acetanilide and aniline.

Reason: Acetylation of aniline results in a decrease in electron density on nitrogen.
The reason provided is that the acetylation of aniline leads to a decrease in electron density on nitrogen. Acetylation refers to the process of introducing an acetyl group (CH3CO-) into a molecule. In this case, aniline (C6H5NH2) is acetylated to form acetanilide (C6H5NHCOCH3).

Explanation:
The reason provided is a correct explanation of the assertion. Let's break down the explanation into key points:

1. Aniline is a primary aromatic amine, consisting of a benzene ring attached to an amino group (-NH2). It can act as a weak base because the lone pair of electrons on the nitrogen atom can accept a proton.

2. Acetylation of aniline involves the substitution of the amino group with an acetyl group (-COCH3), resulting in the formation of acetanilide. This reaction is carried out using acetic anhydride (or acetyl chloride) as an acetylating agent.

3. The acetylation reaction leads to the formation of a new bond between the nitrogen atom of aniline and the carbon atom of the acetyl group. This bond formation causes a decrease in the electron density on the nitrogen atom.

4. The decrease in electron density on the nitrogen atom reduces its ability to accept a proton, thereby decreasing the basicity of the molecule. Acetanilide is therefore less basic than aniline.

In conclusion, the reason provided is a correct explanation of the assertion. Acetylation of aniline results in a decrease in electron density on nitrogen, which in turn reduces the basicity of the molecule, making acetanilide less basic than aniline. Hence, the correct answer is option 'b'.
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Directions: These questions consist of two statements, each printed as...
Acetylation of aniline results in decrease of electron density on nitrogen hence acetanilide is less basic than aniline.
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Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.Assertion : Acetanilide is less basic than aniline.Reason : Acetylation of aniline results in decrease of electron density on nitrogen.a)If both the Assertion and Reason are incorrect.b)If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.c)If the Assertion is correct but Reason is incorrect.d)If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.Correct answer is option 'D'. Can you explain this answer?
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Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.Assertion : Acetanilide is less basic than aniline.Reason : Acetylation of aniline results in decrease of electron density on nitrogen.a)If both the Assertion and Reason are incorrect.b)If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.c)If the Assertion is correct but Reason is incorrect.d)If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.Correct answer is option 'D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.Assertion : Acetanilide is less basic than aniline.Reason : Acetylation of aniline results in decrease of electron density on nitrogen.a)If both the Assertion and Reason are incorrect.b)If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.c)If the Assertion is correct but Reason is incorrect.d)If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Directions: These questions consist of two statements, each printed as Assertion and Reason. While answering these questions, you are required to choose any one of the following four responses.Assertion : Acetanilide is less basic than aniline.Reason : Acetylation of aniline results in decrease of electron density on nitrogen.a)If both the Assertion and Reason are incorrect.b)If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.c)If the Assertion is correct but Reason is incorrect.d)If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.Correct answer is option 'D'. Can you explain this answer?.
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