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The conversion of propan-1-ol to n-butylamine involves the sequential addition of reagents. The correct sequential order of reagents is
  • a)
    (i) SOCl2 (ii) KCN (iii) H2/Ni, Na(Hg)/C2H5OH
  • b)
    (i) HCl (ii) H2/Ni, Na(Hg)/C2H5OH
  • c)
    (i) SOCl2 (ii) KCN (iii) CH3NH2
  • d)
    (i) HCl (ii) CH3NH2
Correct answer is option 'A'. Can you explain this answer?
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The conversion of propan-1-ol to n-butylamine involves the sequential addition of reagents. The correct sequential order of reagents is:

(i) SOCl2
(ii) KCN
(iii) H2/Ni, Na(Hg)/C2H5OH

Let's understand the process step by step:

(i) Conversion of propan-1-ol to propanoyl chloride (propanoyl chloride is formed by the reaction of propan-1-ol with thionyl chloride, SOCl2)
- Propan-1-ol reacts with thionyl chloride (SOCl2) to form propanoyl chloride. This reaction is an example of the conversion of an alcohol to an acyl chloride. The hydroxyl group (-OH) of the alcohol is replaced by a chlorine atom (-Cl) from the thionyl chloride.
- The reaction can be represented as follows:
Propan-1-ol + SOCl2 -> Propanoyl chloride + HCl

(ii) Conversion of propanoyl chloride to nitrile (propanoyl chloride reacts with potassium cyanide, KCN to form propanonitrile)
- Propanoyl chloride reacts with potassium cyanide (KCN) to form propanonitrile. This reaction is an example of the conversion of an acyl chloride to a nitrile. The chlorine atom (-Cl) of the acyl chloride is replaced by a cyano group (-CN) from the potassium cyanide.
- The reaction can be represented as follows:
Propanoyl chloride + KCN -> Propanonitrile + KCl

(iii) Reduction of propanonitrile to n-butylamine (propanonitrile reacts with hydrogen gas in the presence of a catalyst such as nickel or sodium amalgam/ethyl alcohol to form n-butylamine)
- Propanonitrile is reduced to n-butylamine by reacting it with hydrogen gas (H2) in the presence of a catalyst such as nickel (Ni) or sodium amalgam (Na(Hg))/ethyl alcohol (C2H5OH). This reduction reaction converts the nitrile group (-CN) to an amine group (-NH2).
- The reaction can be represented as follows:
Propanonitrile + H2/Ni, Na(Hg)/C2H5OH -> n-Butylamine

Hence, the correct sequential order of reagents for the conversion of propan-1-ol to n-butylamine is (i) SOCl2, (ii) KCN, and (iii) H2/Ni, Na(Hg)/C2H5OH.
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The conversion of propan-1-ol to n-butylamine involves the sequential addition of reagents. The correct sequential order of reagents isa)(i) SOCl2 (ii) KCN (iii) H2/Ni, Na(Hg)/C2H5OHb)(i) HCl (ii) H2/Ni, Na(Hg)/C2H5OHc)(i) SOCl2 (ii) KCN (iii) CH3NH2d)(i) HCl (ii) CH3NH2Correct answer is option 'A'. Can you explain this answer?
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