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Low spin complex is formed by
- a)sp3d2 hybridisation
- b)sp3d hybridisation
- c)d2sp3 hybridisation
- d)sp3 hybridisation
Correct answer is option 'C'. Can you explain this answer?
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Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisati...
Low spin complex utilises (n−1) d-orbital for hybridisation and thus the low spin complex is formed with d2sp3 hybridisation. Inner d-orbital complex is formed.
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Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisati...
Explanation:
Low spin complexes are formed when ligands preferentially occupy the bonding orbitals before the anti-bonding orbitals. This typically occurs when the metal center has a high oxidation state and/or is a small, high charge density metal ion.
d2sp3 hybridisation:
- In low spin complexes, the d orbitals are involved in bonding with ligands.
- The d2sp3 hybridization involves mixing one 3d, two 4s, and three 4p atomic orbitals to form six equivalent sp3d2 hybrid orbitals.
- These hybrid orbitals are oriented in an octahedral arrangement around the metal center.
- The low spin complex formation occurs when the ligands preferentially occupy the lower energy d orbitals before the higher energy d orbitals. This results in a low spin configuration.
Therefore, in the formation of low spin complexes, d2sp3 hybridization is commonly observed due to the involvement of d orbitals in bonding with ligands and the preference for lower energy orbitals to be filled first.
Low spin complexes are formed when ligands preferentially occupy the bonding orbitals before the anti-bonding orbitals. This typically occurs when the metal center has a high oxidation state and/or is a small, high charge density metal ion.
d2sp3 hybridisation:
- In low spin complexes, the d orbitals are involved in bonding with ligands.
- The d2sp3 hybridization involves mixing one 3d, two 4s, and three 4p atomic orbitals to form six equivalent sp3d2 hybrid orbitals.
- These hybrid orbitals are oriented in an octahedral arrangement around the metal center.
- The low spin complex formation occurs when the ligands preferentially occupy the lower energy d orbitals before the higher energy d orbitals. This results in a low spin configuration.
Therefore, in the formation of low spin complexes, d2sp3 hybridization is commonly observed due to the involvement of d orbitals in bonding with ligands and the preference for lower energy orbitals to be filled first.
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Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisationc)d2sp3 hybridisationd)sp3 hybridisationCorrect answer is option 'C'. Can you explain this answer?
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