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Low spin complex is formed by
  • a)
    sp3d2 hybridisation
  • b)
    sp3d hybridisation
  • c)
    d2sp3 hybridisation
  • d)
    sp3 hybridisation
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisati...
Low spin complex utilises (n−1) d-orbital for hybridisation and thus the low spin complex is formed with d2sp3 hybridisation. Inner d-orbital complex is formed.
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Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisati...
Explanation:
Low spin complexes are formed when ligands preferentially occupy the bonding orbitals before the anti-bonding orbitals. This typically occurs when the metal center has a high oxidation state and/or is a small, high charge density metal ion.

d2sp3 hybridisation:
- In low spin complexes, the d orbitals are involved in bonding with ligands.
- The d2sp3 hybridization involves mixing one 3d, two 4s, and three 4p atomic orbitals to form six equivalent sp3d2 hybrid orbitals.
- These hybrid orbitals are oriented in an octahedral arrangement around the metal center.
- The low spin complex formation occurs when the ligands preferentially occupy the lower energy d orbitals before the higher energy d orbitals. This results in a low spin configuration.
Therefore, in the formation of low spin complexes, d2sp3 hybridization is commonly observed due to the involvement of d orbitals in bonding with ligands and the preference for lower energy orbitals to be filled first.
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Low spin complex is formed bya)sp3d2 hybridisationb)sp3d hybridisationc)d2sp3 hybridisationd)sp3 hybridisationCorrect answer is option 'C'. Can you explain this answer?
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